Transparent electrode and method for producing same
View Patent ↗Provided are a transparent electrode and a production method thereof, the transparent electrode using metal nanowires and/or metal nanotubes as conductive components, and showing favorable surface flatness, conductivity, and light transmittance. A transparent conductive ink is prepared by dispersing metal nanowires and/or metal nanotubes in a solution formed by dissolving a thermoset or thermoplastic binder resin having no fluidity within the range of 5 to 40° C. to a solvent, the content of the binder resin being 100 to 2500 parts by mass relative to 100 parts by mass of the metal nanowires and/or metal nanotubes. An electrode pattern having a desired shape is printed on a substrate with the transparent conductive ink, and pulsed light is irradiated to the printed electrode pattern, to thereby obtain a transparent electrode having a surface resistance of 0.1 to 500Ω/□ and a surface arithmetic average roughness Ra satisfying Ra≦5 nm.
1. A method for producing transparent electrode comprising:
a step of printing an electrode pattern having a desired shape on a substrate with a transparent conductive ink having a viscosity of 300 mPa·s to 2×10 5 mPa·s at 25° C., the transparent conductive ink being prepared by dispersing metal nanowires and/or metal nanotubes in a solution formed by dissolving a thermoset or thermoplastic binder resin having no fluidity within the range of 5 to 40° C. to a solvent, and the content of the binder resin being 100 to 2500 parts by mass relative to 100 parts by mass of the metal nanowires and/or metal nanotubes; and
a step of irradiating pulsed light to the printed electrode pattern,
wherein the transparent electrode has a surface arithmetic average roughness Ra satisfying Ra≦5 nm.
2. The method for producing transparent electrode according to claim 1 , wherein the solvent contains an organic solvent.
3. The transparent conductive ink according to claim 2 , wherein the organic solvent has a boiling point of 50° C. or more and 200° C. or less.
4. The transparent conductive ink according to claim 2 , wherein the organic solvent has a boiling point of 120° C. or more and 360° C. or less.
5. The method for producing transparent electrode according to claim 1 , wherein the step of printing is performed by gravure printing and the transparent conductive ink having a viscosity of 300 to 5000 mPa·s at 25° C.
6. The transparent conductive ink according to claim 5 , wherein the organic solvent has a boiling point of 50° C. or more and 200° C. or less.
7. The method for producing transparent electrode according to claim 1 , wherein the step of printing is performed by screen printing and the transparent conductive ink having a viscosity of 1×10 3 to 5×10 4 mPa·s at 25° C.
8. The transparent conductive ink according to claim 7 , wherein the organic solvent has a boiling point of 120° C. or more and 360° C. or less.
9. A transparent conductive ink for forming a transparent electrode comprising metal nanowires and/or metal nanotubes, a solvent, and a thermoset or thermoplastic binder resin having no fluidity within the range of 5 to 40° C. and to be dissolved in the solvent, the content of the binder resin being 100 to 2500 parts by mass relative to 100 parts by mass of the metal nanowires and/or metal nanotubes,
wherein the transparent conductive ink has a viscosity of 300 mPa·s to 2×10 5 mPa·s at 25° C.
10. The transparent conductive ink according to claim 9 , wherein the solvent contains an organic solvent.
11. The transparent conductive ink according to claim 10 , wherein the organic solvent has a boiling point of 50° C. or more and 200° C. or less.
12. The transparent conductive ink according to claim 10 , wherein the organic solvent has a boiling point of 120° C. or more and 360° C. or less.
13. The transparent conductive ink according to claim 9 , wherein the content of the binder resin is 300 to 2500 parts by mass relative to 100 parts by mass of the metal nanowires and/or metal nanotubes.