Curable silicone composition, cured product thereof, and optical semiconductor device
View Patent ↗The present invention relates to a curable silicone composition comprising: (A) an organopolysiloxane represented by the average unit formula: (R 1 3 SiO 1/2 ) a (R 1 2 SiO 2/2 ) b (R 2 SiO 3/2 ) c (R 3 SiO 3/2 ) d , wherein, R 1 are the same or different alkyl groups having from 1 to 12 carbons, alkenyl groups having from 2 to 12 carbons, aryl groups having from 6 to 20 carbons, or aralkyl groups having from 7 to 20 carbons, provided that at least two R 1 in a molecule are the alkenyl groups; R 2 is an aryl group having from 6 to 20 carbons or an aralkyl group having from 7 to 20 carbons; R 3 is an alkyl group having from 1 to 12 carbons; and a, b, c, and d are respectively numbers satisfying: 0.01≦a≦0.5, 0≦b≦0.7, 0.01≦c<0.7, 0.1≦d<0.9, and a+b+c+d=1; (B) a linear organopolysiloxane having at least two silicon-bonded alkenyl groups and at least one silicon-bonded aryl group in a molecule; (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule; (D) a hydrosilylation-reaction catalyst. The curable silicone composition has excellent handling/workability and forming a cured product with a high refractive index and low gas permeability when cured.
1. A curable silicone composition comprising:
(A) an organopolysiloxane represented by the average unit formula:
(R 1 3 SiO 1/2 ) a (R 2 SiO 3/2 ) c (R 3 SiO 3/2 ) d
wherein, R 1 are the same or different alkyl groups having from 1to 12carbons, alkenyl groups having from 2to 12carbons, aryl groups having from 6to 20carbons, or aralkyl groups having from 7to 20carbons, provided that at least two R l in a molecule are the alkenyl groups; R 2 is an aryl group having from 6to 20carbons or an aralkyl group having from 7to 20carbons; R 3 is an alkyl group having from 1to 12carbons; and a, c, and d are respectively numbers satisfying: 0.01≦a≦0.5, 0.01≦c<0.7, 0.1≦d<0.9, and a+c+d=1;
(B) a linear organopolysiloxane having at least two silicon-bonded alkenyl groups and at least one silicon-bonded aryl group in a molecule, in an amount of 0.1 to 150 parts by mass per 100 parts by mass of component (A);
(C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, in an amount so that the amount of silicon-bonded hydrogen atoms in component (C) is from 0.1 to 5 mol per 1mol of total alkenyl groups in components (A) and (B); and
(D) a hydrosilylation-reaction catalyst in an amount that accelerates curing of the present composition.
2. The curable silicone composition according to claim 1 , wherein R 2 in component (A) is a phenyl group.
3. The curable silicone composition according to claim 1 , wherein R 3 in component (A) is a methyl group.
4. The curable silicone composition according to claim 1 , wherein component (B) is an organopolysiloxane represented by the general formula:
wherein, R l to R 3 are the same as the groups described above; m is an integer from 0 to 800, n is an integer from 0 to 300, and o is an integer from 0 to 300, provided that m, n, and o satisfy: m≧n and 5≦m+n+o≦1,000.
5. The curable silicone composition according to claim 1 , further comprising (E) a hydrosilylation-reaction inhibitor in an amount of 0.01 to 3 parts by mass per 100 parts total mass of components (A) to (C).
6. The curable silicone composition according to claim 1 , further comprising (F) an adhesion promoter in an amount of 0.1 to 3 parts by mass per 100 parts total mass of components (A) to (C).
7. A cured product produced by curing the curable silicone composition described in claim 1 .
8. An optical semiconductor device comprising an optical semiconductor element sealed with a cured product of the curable silicone composition described in claim 1 .
9. The curable silicone composition according to claim 2 , wherein R 3 in component (A) is a methyl group.
10. The curable silicone composition according to claim 9 , wherein component (B) is an organopolysiloxane represented by the general formula:
wherein, R l to R 3 are the same as the groups described above; m is an integer from 0 to 800, n is an integer from 0 to 300, and o is an integer from 0 to 300, provided that m, n, and o satisfy: m≧n and 5≦m+n+o≦1,000.
11. The curable silicone composition according to claim 2 , wherein component (B) is an organopolysiloxane represented by the general formula:
wherein, R l to R 3 are the same as the groups described above; m is an integer from 0 to 800, n is an integer from 0 to 300, and o is an integer from 0 to 300, provided that m, n, and o satisfy: m≧n and 5≦m+n+o≦1,000.
12. The curable silicone composition according to claim 3 , wherein component (B) is an organopolysiloxane represented by the general formula:
wherein, R l to R 3 are the same as the groups described above; m is an integer from 0 to 800, n is an integer from 0 to 300, and o is an integer from 0 to 300, provided that m, n, and o satisfy: m≧n and 5≦m+n+o≦1,000.
13. The curable silicone composition according to claim 4 , wherein R 2 in component (B) is a phenyl group and R 3 in component (B) is a methyl group.
14. The curable silicone composition according to claim 10 , wherein R 2 in component (B) is a phenyl group and R 3 in component (B) is a methyl group.