Valve seat
The valve seat includes an iron-based sintered alloy subjected to oxidation treatment, which is obtained by subjecting an iron-based sintered alloy including: 4 mass % to 15 mass % of Co particles; and hard particles each containing at least one compound of an intermetallic compound, a carbide, a silicide, a nitride, or a boride that has one or more kinds of elements selected from group 4a to 6a elements in a periodic table, and having a hardness of from 600 HV to 1,600 HV to oxidation treatment, and which has an oxide mainly including triiron tetraoxide (Fe 3 O 4 ) and cobalt oxide (CoO) formed on a surface and in an interior of the iron-based sintered alloy. The iron-based sintered alloy subjected to oxidation treatment has an area ratio of the oxide of from 5% to 25% in a cross section thereof in a state prior to installation on the cylinder head.
1. A valve seat to be installed on a cylinder head of an internal combustion engine,
the valve seat comprising an iron-based sintered alloy subjected to oxidation treatment, which is obtained by subjecting an iron-based sintered alloy comprising: 4 mass % to 15 mass % of Co particles; and hard particles each containing at least one compound of an intermetallic compound, a carbide, a silicide, a nitride, or a boride that has one or more kinds of elements selected from group 4a to 6a elements in a periodic table, and having a hardness of from 600 HV to 1,600 HV to oxidation treatment, and which has an oxide mainly comprising triiron tetraoxide (Fe 3 O 4 ) and cobalt oxide (CoO) formed on a surface and in an interior of the iron-based sintered alloy,
wherein the iron-based sintered alloy subjected to oxidation treatment has an area ratio of the oxide of from 5% to 25% in a cross section thereof in a state prior to installation on the cylinder head, and
wherein the hard particles comprise Co-based alloy particles each containing 28 mass % to 38 mass % of Co, and the carbide.
2. A valve seat according to claim 1 , wherein the Co particles have an average particle size of from 10 μm to 40 μm.
3. A valve seat according to claim 1 , wherein the iron-based sintered alloy has an area ratio of the hard particles of from 5% to 45% in a cross section thereof.
4. A valve seat according to claim 1 , wherein the iron-based sintered alloy further comprises a solid lubricant.
5. A valve seat according to claim 4 , wherein the solid lubricant has an average particle size of from 1 μm to 10 μm.