Concentrated electrolyte solution
The present invention provides a single-phase or homogeneous solution comprising a high concentration of a salt, in particular a lithium salt, in an organic solvent. Such a high salt content in organic solvent is useful in a variety of applications including, but not limited to, in electrical energy storage devices as well as other devices that can benefit from a low-volatility liquid electrolyte.
1. A concentrated single-phase organic electrolyte solution consisting essentially of lithium bis(fluorosulfonyl)imide (LiFSI) in one or more organic solvents, wherein the LiFSI has a concentration in said concentrated single-phase organic electrolyte solution of more than 40% by weight.
2. The concentrated single-phase organic electrolyte solution of claim 1 , wherein the LiFSI concentration in said concentrated single-phase organic electrolyte solution is at least 50% by weight.
3. The concentrated single-phase organic electrolyte solution of claim 1 , wherein said concentrated single-phase organic electrolyte solution further comprises an ionic liquid.
4. The concentrated single-phase organic electrolyte solution of claim 1 , wherein said one or more organic solvents is selected from the group consisting of: acetonitrile, y-butyrolactone, diethyl carbonate, 1,2-dimethoxyethane, dimethyl carbonate, 1,3-dioxolane, ethyl acetate, ethylene carbonate, ethyl methyl carbonate, propylene carbonate, tetrahydrofuran, fluorinated carbonates, and a mixture thereof.
5. The concentrated single-phase organic electrolyte solution of claim 1 , wherein said one or more organic solvents comprises ethylene carbonate.
6. The concentrated single-phase organic electrolyte solution of claim 1 , wherein said concentrated single-phase organic electrolyte solution is in the liquid state at 10° C.
7. The concentrated single-phase organic electrolyte solution of claim 1 , wherein said concentrated single-phase organic electrolyte solution is in the liquid state at 0° C.