Gypsum wallboard slurry and method for making the same
A slurry for manufacturing gypsum board is disclosed. The slurry comprises calcined gypsum, water, a foaming agent, and a thickening agent. The thickening agent of the present disclosure acts to improve the cohesiveness of the slurry without adversely affecting the setting time of the slurry, the paper-to-core bond (wet and dry), or the head of the slurry by acting as a defoaming agent or coalescing agent. Examples of suitable thickening agents include cellulose ether and co-polymers containing varying degrees of polyacrylamide and acrylic acid. A gypsum board and method of forming the slurry and the gypsum board are also disclosed. The gypsum board comprises a gypsum layer formed from the slurry.
1. A gypsum board comprising:
a gypsum layer comprising a reaction product of a gypsum slurry having a composition comprising
calcined gypsum in an amount of from 548 to 1180 lbs/msf for a ½ inch gypsum board or 1785 to 2040 lbs/msf for a ⅝ inch gypsum board;
water;
an aqueous foam; and
a thickening agent comprising a nonionic cellulose ether comprising an ethyl hydroxyl ethyl cellulose, a methyl hydroxyethyl cellulose, or a combination thereof, wherein the nonionic cellulose ether is present in the slurry in an amount of from 0.02 to 1.0 lbs/msf.
2. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a degree of substitution (DS) of hydroxyl groups between about 0.5 to about 1.0.
3. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a molar degree of substitution (MS) of hydroxyl groups of about 1.9.
4. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a degree of substitution (DS) of hydroxyl groups of about 0.9 and a molar degree of substitution (MS) of hydroxyl groups of about 1.9.
5. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a viscosity between about 3500 mPas to about 6500 mPas, when measured as a 2% solution.
6. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a viscosity between about 4250 mPas to about 6000 mPas, when measured as a 2% solution.
7. The gypsum board of claim 1 , wherein the cellulose ether is a methyl hydroxyethyl cellulose having a viscosity of between 28000 mPas and 34000 mPas, when measured as a 2% solution.
8. The gypsum board of claim 1 , wherein the cellulose ether is present in an amount of from about 0.05 lbs/msf to about 0.8 lbs/msf.
9. The gypsum board of claim 1 , wherein the cellulose ether is present in an amount of from about 0.1 lbs/msf to about 0.5 lbs/msf.
10. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a surface tension that is about the surface tension of the aqueous foam.
11. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a surface tension of about 72 Dynes/cm, when measured as a 2% solution.
12. The gypsum board of claim 1 , wherein the cellulose ether is an ethyl hydroxyl ethyl cellulose having a surface tension of about 65 Dynes/cm, when measured as a 2% solution.
13. The gypsum board of claim 1 , wherein the composition further comprises a secondary thickening agent.
14. The gypsum board of claim 13 , wherein the secondary thickening agent comprises a pre-gelled starch or clay.
15. The gypsum board of claim 1 , wherein the aqueous foam comprises an alkylsulfate compound, water and air.
16. A gypsum board comprising:
a gypsum layer comprising a reaction product of a gypsum slurry having a composition comprising
calcined gypsum in an amount of from 548 to 1180 lbs/msf for a ½ inch gypsum board or 1785 to 2040 lbs/msf for a ⅝ inch gypsum board;
water;
an aqueous foam comprising a foaming agent, water and air;
a coalescing agent; and
a thickening agent comprising a nonionic cellulose ether comprising an ethyl hydroxyl ethyl cellulose, a methyl hydroxyethyl cellulose, or a combination thereof, wherein the nonionic cellulose ether is present in the slurry in an amount of from 0.02 to 1.0 lbs/msf;
wherein the composition undergoes an exothermic reaction and has an initial temperature and a peak temperature when the composition is reacted, the coalescing agent having a cloud point between the initial temperature and the peak temperature.
17. The gypsum board of claim 16 , wherein the coalescing agent has a cloud point of from about 16° C. to about 60° C.
18. The gypsum board of claim 17 , wherein the coalescing agent is an EO/PO reverse block copolymer.
19. The gypsum board of claim 16 , wherein the weight ratio of the foaming agent to coalescing agent is in a range from about 10:0.5 to about 5:1.5.
20. The gypsum board of claim 16 , wherein the weight ratio of the foaming agent to coalescing agent is in a range from about 7.5:1 to about 5:1.
21. The gypsum board of claim 16 , wherein the weight ratio of the foaming agent to coalescing agent is in a range from about 7:1 to about 6:1.
22. The gypsum board of claim 1 , wherein the calcined gypsum is present in an amount of from 674 to 1180 lbs/msf for a ½ inch gypsum board.
23. The gypsum board of claim 16 , wherein the calcined gypsum is present in an amount of from 674 to 1180 lbs/msf for a ½ inch gypsum board.