Separator for rechargeable battery and rechargeable battery including the same
A separator for a rechargeable battery includes a substrate and a coating layer on at least one surface of the substrate, wherein the coating layer includes a binder including an acrylic resin, the binder including the acrylic resin includes a carboxyl group-containing acrylic monomer and an acrylic acid derivative monomer, and the carboxyl group-containing acrylic monomer and the acrylic acid derivative monomer are present in a mole ratio of about 20:80 to about 80:20. The binder for a rechargeable battery has high heat resistance and strong adherence, and improves the cycling characteristics of the battery.
1. A separator for a rechargeable battery, comprising:
a substrate and a coating layer on at least one surface of the substrate,
wherein:
the coating layer comprises a binder including an acrylic resin,
the binder including the acrylic resin is a copolymerization acrylic resin in which a carboxyl group-containing acrylic monomer and an acrylic acid derivative monomer are copolymerized,
the carboxyl group-containing acrylic monomer comprises an alkali metal salt or an ammonium salt,
the acrylic resin comprises the alkali metal salt or the ammonium salt,
the acrylic acid derivative monomer is at least one selected from acrylonitrile, methacrylonitrile, 2-cyanoethylacrylate, 2-cyanoethylmethacrylate, isobornyl acrylate, 2,2,2-trifluoroethylacrylate, methyl (meth)acrylate, butyl (meth)acrylate, ethyl (meth)acrylate, 2-ethylhexyl(meth)acrylic acid, hydroxyethyl acrylate, 1H,1H-pentafluoropropyl acrylate, 2,2,3,3-tetrafluoropropyl acrylate, polyadamantyl acrylate, and acrylamide, and
the carboxyl group-containing acrylic monomer and the acrylic acid derivative monomer are present in a mole ratio of about 20:80 to about 80:20.
2. The separator of claim 1 , wherein the carboxyl group-containing acrylic monomer comprises at least one selected from acrylic acid, methacrylic acid, maleic acid, mono methyl maleic acid, 2-carboxylethyl acrylate, and 2-carboxylethyl methacrylate.
3. The separator of claim 1 , wherein the coating layer further comprises a non-water-soluble resin.
4. The separator of claim 3 , wherein the non-water-soluble resin comprises polyvinylidene fluoride, a non-water-soluble acrylic resin, or a combination thereof.
5. The separator of claim 1 , wherein the coating layer further comprises polyvinyl alcohol.
6. The separator of claim 1 , wherein the coating layer further comprises inorganic particles.
7. The separator of claim 6 , wherein the inorganic particles comprise alumina, boehmite, or a combination thereof.
8. A rechargeable battery comprising the separator of claim 1 .
9. The rechargeable battery of claim 8 , wherein the carboxyl group-containing acrylic monomer comprises at least one selected from acrylic acid, methacrylic acid, maleic acid, mono methyl maleic acid, 2-carboxylethyl acrylate, and 2-carboxylethyl methacrylate.
10. The rechargeable battery of claim 8 , wherein the coating layer further comprises a non-water-soluble resin.
11. The rechargeable battery of claim 10 , wherein the non-water-soluble resin comprises polyvinylidene fluoride, a non-water-soluble acrylic resin, or a combination thereof.
12. The rechargeable battery of claim 8 , wherein the coating layer further comprises polyvinyl alcohol.
13. The rechargeable battery of claim 8 , wherein the coating layer further comprises inorganic particles.
14. The rechargeable battery of claim 13 , wherein the inorganic particles comprise alumina, boehmite, or a combination thereof.