IP Library Granted Patent US 9,573,249
Granted Patent B2
US 9,573,249 · App. 14/946,606 · Granted Feb 21, 2017

Boron nitride composites

Inventors: Joshua D. Kuntz (Livermore, CA); German F. Ellsworth (Livermore, CA); Fritz J. Swenson (Tracy, CA); Patrick G. Allen (Pleasanton, CA)
Assignee: Lawrence Livermore National Security, LLC
B24D3/04B24D3/00B24D18/0009
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Quick Facts
Patent No.
US 9,573,249
App. No.
14/946,606
Granted
Feb 21, 2017
Kind
B2
Abstract

According to one embodiment, a composite product includes: a matrix material including hexagonal boron nitride and one or more borate binders; and a plurality of cubic boron nitride particles dispersed in the matrix material. According to another embodiment, a composite product includes: a matrix material including hexagonal boron nitride and amorphous boron nitride; and a plurality of cubic boron nitride particles dispersed in the matrix material.

Claims (28)

1. A composite product, comprising:

a matrix material comprising hexagonal boron nitride (hBN) and one or more borate binders; and

a plurality of cubic boron nitride (cBN) particles dispersed in the matrix material.

2. The composite product of claim 1 , wherein the borate binders are each independently selected from the group consisting of: calcium borate, potassium borate, magnesium borate, lithium tetraborate, and combinations thereof.

3. The composite product of claim 1 , wherein a total amount of the cBN particles is in a range from about 15 to about 90 vol. %.

4. The composite product of claim 1 , wherein a total amount of the borate binders is in a range from about 2 to about 95 vol. %.

5. The composite product of claim 1 , wherein an average particle size of the cBN particles is about 0.5 nm to about 250 microns.

6. The composite product of claim 1 , wherein one or more of the cBN particles comprise a first average particle size and one or more of the cBN particles comprises a second average particle size, wherein the second average particle size is smaller than the first average particle size.

7. The composite product of claim 6 , wherein a ratio of a volume percent of the cBN particles having the first average particle size to the cBN particles having the second average particle size is about 1:1 to about 10:1.

8. The composite product of claim 1 , wherein each of the cBN particles is a single crystal of cBN.

9. A method of making the composite product of claim 1 , comprising

forming a mixture including the cBN particles, the hBN and the one or more borate binders;

consolidating the mixture by employing a consolidation technique selected from a group consisting of: high pressure sintering, spark plasma sintering and hot pressing.

10. A medium for at least one of cutting, grinding, polishing, and drilling, the medium comprising the composite product of claim 1 .

11. A tool comprising the medium of claim 10 .

12. A composite product, comprising:

a matrix material comprising hexagonal boron nitride (hBN) and amorphous boron nitride; and

a plurality of cubic boron nitride (cBN) particles dispersed in the matrix material.

13. The composite product of claim 12 , a total amount of the cBN particles is in a range from about 15 to about 90 vol. %.

14. The composite product of claim 12 , wherein the matrix material comprises one or more borate binders in an amount ranging from about 2 to about 95 vol. %.

15. The composite product of claim 14 , wherein the borate binders are each independently selected from a group consisting of calcium borate, potassium borate, magnesium borate, lithium tetraborate.

16. The composite product of claim 12 , wherein the cBN particles comprise a first average particle size and a second average particle size, wherein the second average particle size is smaller than the first average particle size.

17. A composite product, comprising:

a matrix material comprising hexagonal boron nitride (hBN) and one or more borate binders, wherein at least one of the borate binders is present in a crystalline phase and at least one of the borate binders is present in an amorphous phase; and

a plurality of cubic boron nitride (cBN) particles dispersed in the matrix material.

18. The composite product of claim 17 , a total amount of the cBN particles is in a range from about 15 to about 90 vol. %.

19. The composite product of claim 17 , wherein each of the cBN particles is a single crystal of cBN.

20. The composite product of claim 17 , wherein a total amount of the borate binders is in a range from about 2 to about 95 vol. %.

Assignments (2)
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Sep 21, 2020
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 053837/0219 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2015
From: KUNTZ, JOSHUA D.; ELLSWORTH, GERMAN F.; SWENSON, FRITZ J.; ALLEN, PATRICK G.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 037094/0335 →
Continuity (2)
Continuation 14010423 · Aug 26, 2013
Related Publication 20160074997A1 · Mar 17, 2016