Manufacturing method of composite oxide and manufacturing method of power storage device
An object is to reduce variation in shape of crystals that are to be formed. Solutions containing respective raw materials are made in an environment where an oxygen concentration is lower than that in air, the solutions containing the respective raw materials are mixed in an environment where an oxygen concentration is lower than that in air to form a mixture solution, and with use of the mixture solution, a composite oxide is formed by a hydrothermal method.
1. A power storage device comprising:
a positive electrode comprising a positive electrode current collector and a positive electrode active material layer on the positive electrode current collector,
wherein the positive electrode active material layer comprises graphene and a plurality of crystals of composite oxide which is represented by a general formula LiMPO 4,
wherein M denotes a transition metal selected from the group consisting of Fe, Co, Ni, and Mn,
wherein the plurality of crystals is covered with the graphene, and
wherein each of the plurality of crystals has a crystal shape of a rectangular solid.
2. The power storage device according to claim 1 , wherein each of the plurality of crystals has an olivine structure.
3. The power storage device according to claim 1 , wherein the graphene functions as a conductive auxiliary agent and a binder in the positive electrode active material layer.
4. The power storage device according to claim 1 , wherein proportion of an element other than carbon in the graphene is 30 at % or less.
5. The power storage device according to claim 1 , wherein proportion of an element other than carbon and hydrogen the graphene contains to account for 15 at % or less.
6. The power storage device according to claim 1 , further comprising a negative electrode facing the positive electrode,
wherein the negative electrode comprises a negative electrode current collector and a negative electrode active material layer on the negative electrode current collector.
7. The power storage device according to claim 6 , wherein the negative electrode active material layer comprises graphene.
8. A display device comprising:
the power storage device according to claim 1 ;
a display portion electrically connected to the power storage device; and
a speaker electrically connected to the power storage device.
9. An electronic equipment comprising the power storage device according to claim 1 ,
wherein the electronic equipment is configured to receive electric power stored in the power storage device.
10. A power storage device comprising:
a positive electrode comprising a positive electrode current collector and a positive electrode active material layer on the positive electrode current collector,
wherein the positive electrode active material layer comprises graphene and a plurality of crystals of composite oxide which is represented by a general formula LiMPO 4,
wherein M denotes a transition metal selected from the group consisting of Fe, Co, Ni, and Mn,
wherein the graphene is multilayer graphene including 2 to 100 graphene sheets,
wherein the plurality of crystals are provided between the graphene sheets, and
wherein each of the plurality of crystals has a crystal shape of a rectangular solid.
11. The power storage device according to claim 10 , wherein each of the plurality of crystals has an olivine structure.
12. The power storage device according to claim 10 , wherein the graphene functions as a conductive auxiliary agent and a binder in the positive electrode active material layer.
13. The power storage device according to claim 10 , wherein proportion of an element other than carbon in the graphene is 30 at % or less.
14. The power storage device according to claim 10 , wherein proportion of an element other than carbon and hydrogen the graphene contains to account for 15 at. % or less.
15. The power storage device according to claim 10 , further comprising a negative electrode facing the positive electrode,
wherein the negative electrode comprises a negative electrode current collector and a negative electrode active material layer on the negative electrode current collector.
16. The power storage device according to claim 15 , wherein the negative electrode active material layer comprises graphene.
17. A display device comprising:
the power storage device according to claim 10 ;
a display portion electrically connected to the power storage device; and
a speaker electrically connected to the power storage device.
18. An electronic equipment comprising the power storage device according to claim 10 ,
wherein the electronic equipment is configured to receive electric power stored in the power storage device.