Infiltrant for dental application

1. An infiltrant for dental application, comprising crosslinking monomers, which has a penetration coefficient PC>100 cm/s, and the crosslinking monomers, based on the total mass of monomers, comprise:

i) 90% to 50% by weight of crosslinking monomers having two polymerizable groups; and

ii) 10% to 50% by weight of crosslinking monomers having at least three polymerizable groups, wherein the crosslinking monomers having at least three polymerizable groups have a distance between crosslinking points of 11 to 21 bond lengths;

wherein said infiltrant contains no solvent.

2. The infiltrant of claim 1 , wherein the fraction of crosslinking monomers having at least three polymerizable groups is 10% to 30% by weight.

3. The infiltrant of claim 1 , wherein the fraction of crosslinking monomers having two polymerizable groups is 90% to 70% by weight.

4. The infiltrant of claim 1 , wherein the crosslinking monomers having two polymerizable groups are esters of acrylic or methacrylic acid.

5. The infiltrant of claim 1 , wherein the crosslinking monomers having at least three polymerizable groups have the formula below

R 1 [X k R 2 1 Y m ] n

having the following definitions:

R 1 is a linear or branched hydrocarbon having 3-24 C atoms, comprising alkyl, cycloalkyl or aryl;

R 2 is a linear or branched hydrocarbon having 1-16 C atoms, comprising ether groups or polyether groups;

X is a linking group identically or differently selected from an ether group, carbonyl group, ester group, amide group, urethane group or urea group;

Y is a group identically or differently containing a polymerizable double bond and/or a ring-openingly polymerizable group and/or a thiol group; preferably vinyl, (meth)acrylate, (meth)acrylamide or epoxide groups;

k is 0 or 1;

l is 1;

m is at least 1;

n is at least 1; and

m×n is at least 3.

6. The infiltrant of claim 1 , wherein the crosslinking monomers having at least three polymerizable groups are selected from the group consisting of propoxylated glyceryl tri(meth)acrylate; ethoxylated trimethylolpropane trimethacrylate, ethoxylated trimethylolpropane triacrylate, propoxylated trimethylolpropane trimethacrylate, propoxylated trimethylolpropane triacrylate, ethoxylated pentaerythritol trimethacrylate, ethoxylated pentaerythritol triacrylate, ethoxylated pentaerythritol tetramethacrylate, ethoxylated pentaerythritol tetraacrylate, ethoxylated dipentaerythritol trimethacrylate, ethoxylated dipentaerythritol tetramethacrylate, ethoxylated dipentaerythritol pentamethacrylate, ethoxylated dipentaerythritol hexamethacrylate, ethoxylated dipentaerythritol triacrylate, ethoxylated dipentaerythritol tetraacrylate, ethoxylated dipentaerythritol pentaacrylate, ethoxylated dipentaerythritol hexaacrylate, propoxylated pentaerythritol trimethacrylate, propoxylated pentaerythritol triacrylate, propoxylated pentaerythritol tetramethacrylate, propoxylated pentaerythritol tetraacrylate, propoxylated dipentaerythritol trimethacrylate, propoxylated dipentaerythritol tetramethacrylate, propoxylated dipentaerythritol pentamethacrylate, propoxylated dipentaerythritol hexamethacrylate, propoxylated dipentaerythritol triacrylate, propoxylated dipentaerythritol tetraacrylate, propoxylated dipentaerythritol pentaacrylate and propoxylated dipentaerythritol hexaacrylate.

7. The infiltrant of claim 1 , further comprising monomers having only one polymerizable group.

8. The infiltrant of claim 1 , having a dynamic viscosity of 50 mPas or less.

9. A kit for preparing an infiltrant as claimed in claim 1 , wherein the kit comprises a first component with monomers and chemically activable initiators and a second component with activators.

10. A kit for preparing an infiltrant as claimed in claim 1 , wherein the kit further comprises etching agents and/or drying agents.

11. A method, comprising providing the infiltrant as claimed in claim 1 , and using said infiltrant to treat and/or prevent carious enamel lesions.

12. The infiltrant of claim 4 , wherein the crosslinking monomers having two polymerizable groups are selected from the group consisting of 1,10-decanediol dimethacrylate (DDDMA); polyethylene glycol 400 diacrylate (PEG400DA); polyethylene glycol 400 dimethacrylate (PEG400DMA); polyethylene glycol 300 diacrylate (PEG300DA); polyethylene glycol 300 dimethacrylate (PEG300DMA); ethoxylated (10) bisphenyl A dimethacrylate (BPA(EO)10DMA); ethoxylated (30) bisphenol A dimethacrylate (BPA(EO)30DMA); polyethylene glycol 200 diacrylate (PEG200DA); polyethylene glycol 600 diacrylate (PEG600DA); propoxylated (2) neopentylglycol diacrylate (NPG(PO)2DA); ethoxylated (4) bisphenol A diacrylate (BPA(EO)2DA); propoxylated (2) bisphenol A dimethacrylate (BPA(PO)2DMA), bis-GMA, 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane; 1,6-bis(methacryloyloxy-2-ethoxycarbonylamino)-2,4,4-trimethylhexane (UDMA); ethylene glycol dimethacrylate (EGDMA); triethylene glycol dimethacrylate (3EGDMA or TEDMA); tetraethylene glycol dimethacrylate (4EGDMA); 1,3-butylene glycol dimethacrylate(BDMA); 1,6-hexanediol dimethacrylate; 1,4-butylenediol diacrylate; tetraethylene glycol diacrylate (4EDA); 1,9-nonanediol diacrylate (NDDA); diethylene glycol dimethacrylate (DEGDMA); 1,5-pentanediol dimethacrylate (PDDMA); 1,4-butanediol dimethacrylate (BDDMA); 1,3-propanediol dimethacrylate (PRDMA); and dimethyloltricyclo[5.2.1.0]decane dimethacrylate (DMTCDDA).

13. The infiltrant of claim 7 , wherein the monomers having only one polymerizable group are selected from the group consisting of methyl methacrylate (MMA); ethyl methacrylate (EMA); n-butyl methacrylate (n-BMA); isobutyl methacrylate (IBMA); tert-butyl methacrylate (t-BMA); 2-ethylhexyl methacrylate (EHMA); lauryl methacrylate (LMA); tridecyl methacrylate (TDMA); stearyl methacrylate (SMA); cyclohexyl methacrylate (CHMA); benzyl methacrylate (BZMA), isobornyl methacrylates (IBXMA); methacrylic acid (MAA); 2-hydroxyethyl methacrylate (HEMA); 2-hydroxypropyl methacrylate (HPMA); dimethylaminoethyl methacrylate (DMMA); diethylaminoethyl methacrylate (DEMA); glycidyl methacrylate (GMA); tetrahydrofurfuryl methacrylate (THFMA); allyl methacrylate (AMA); ethoxyethyl methacrylate (ETMA); trifluoroethyl methacrylate (3FM); octafluoropentyl methacrylate (8FM); isobutyl acrylate (AIB); tert-butyl acrylate (TBA); lauryl acrylate (LA); cetyl acrylate (CEA); stearyl acrylate (STA); cyclohexyl acrylate (CHA); benzyl acrylate (BZA); isobornyl acrylate (IBXA); 2-methoxyethyl acrylate (2-MTA); 2-ethoxyethyl acrylate (ETA); ethoxyethoxyethyl acrylate (EETA); 2-phenoxyethyl acrylate (PEA); tetrahydrofurfuryl acrylate (THFA); 2-hydroxyethyl acrylate (HEA); 2-hydroxypropyl acrylate (HPA); 4-hydroxybutyl acrylate (4HBA); dimethylaminoethyl acrylate (DMA); trifluoroethyl acrylate (3F); heptadecafluorodecyl acrylate (17F); 2-phenoxyethyl acrylate (2-PEA); 4-tert-butylcyclohexyl acrylate (TBCH); dihydrodicyclopentadienyl acrylate (DCPA); 2-ethylhexyl acrylate (EHA); and triethylene glycol monomethacrylate (3EGMA).

14. The infiltrant of claim 8 , having a dynamic viscosity of 30 mPas or less.

15. The infiltrant of claim 13 , having a dynamic viscosity of 15 mPas or less.

16. The infiltrant of claim 5 , wherein R 1 contains O, N, Si, S, P as heteroatoms.

17. The infiltrant of claim 16 , wherein R 1 contains siloxane and/or cyclosiloxane and/or carbosilane and/or cyclocarbosilane and/or ether groups or polyether groups, polyester groups, polysiloxane groups or polycarbosilane groups.

18. The infiltrant of claim 5 , wherein R 1 is substituted by hydroxyl and/or carbonyl and/or halogen and/or ammonium-alkylene groups and/or siloxane and/or cyclosiloxane and/or carbosilane and/or cyclo-carbosilane.

19. The infiltrant of claim 18 , wherein R 1 is substituted by fluorine.