Method of manufacturing high volumetric density electrodes from self-aligning fiber powders
An electrode and a related method of manufacture are provided. The electrode includes a self-aligning active material having short fiber powders with a cylindrical morphology to increase the packing density from 0.74 to nearly 0.91. The short fiber powders self-align during a slurring coating process as a result of shear forces between a die and a foil. The resulting coating includes parallel short fibers in a closed packed arrangement, providing an increased volumetric capacity of at least approximately 17%.
1. A method of making an electrode comprising the steps of:
forming a carbon fiber mat by melt blowing fibers onto a substrate, oxidatively stabilizing the melt blown fibers by heating the fibers to 250° C. at a rate of between 0.01° C./min and 1.0° C./min, and carbonizing the fibers in an annealing temperature of at least 1000° C. in an inert gas;
grinding the carbon fiber mat into powders having a cylindrical morphology with an average particle diameter of 1-100 μm and an aspect ratio of 1:20 to 1:85 inclusive;
preparing a slurry containing at least the powders and a polymeric binder;
depositing the slurry onto a substrate to form a coating while applying a shear force to the coating to substantially align the powders within the coating; and
further processing the coated substrate to produce an electrode, wherein the powders have a packing density of at least 0.75.
2. The method according to claim 1 wherein the slurry includes a solvent, the method further including removing the solvent from the slurry to achieve a dry coating and calendaring the dry coating.
3. The method according to claim 1 wherein further processing the coated substrate includes incorporating the coated substrate into a lithium-ion battery as an anode.
4. The method according to claim 1 wherein applying a shear force to the coating includes drawing a die, a blade, or a roller along the coating.
5. The method according to claim 1 wherein the carbon fiber mat includes lignin-based carbon fibers or silicon-carbon fibers.
6. The method according to claim 1 wherein the polymeric binder includes poly(vinylidene difluoride).
7. The method according to claim 2 wherein the solvent includes ahhydrous N-methyl pyrrolidinone.
8. A method of making an electrode comprising the steps of:
forming a carbon fiber mat by melt blowing fibers onto a substrate, oxidatively stabilizing the melt blown fibers by heating the fibers to 250° C. at a rate of between 0.01° C./min and 1.0° C./min, and carbonizing the fibers in an annealing temperature of at least 1000° C. in an inert gas;
grinding the carbon fiber mat into fiber powders having a cylindrical morphology with an average particle diameter of 1-100 μm and an aspect ratio of 1:20 to 1:85 inclusive;
preparing a slurry including the fiber powders, a binder, and a solvent;
applying the slurry to a substrate to form a wet coating and drawing a shear element along the wet coating to substantially align the fiber powders therein; and
curing the wet coating to form a dry coating on the substrate, the dry coating having a fiber powder packing density of between 0.75 and 0.91.
9. The method according to claim 8 wherein the polymeric binder includes poly(vinylidene difluoride).
10. The method according to claim 8 wherein the solvent includes ahhydrous N-methyl pyrrolidinone.
11. The method according to claim 8 further including calendaring the dry coating to achieve a thickness of between 10 μm to 150 μm.
12. The method according to claim 8 wherein curing the wet coating removes residual adsorbed moisture therefrom.