Quantum rod layer, method of fabricating the same and display device including the same
An example of the present invention provides a quantum rod layer including: a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and a quantum rod aligned along the first direction.
1. A liquid crystal display device, comprising:
a light source part emitting a blue colored light;
a quantum rod layer over the light source part, the quantum rod layer emitting a white colored light of a polarized state having a peak at wavelengths corresponding to red, green and blue colors using the blue colored light;
first and second substrates over the light source part, the first and second substrates facing each other and spaced apart from each other;
a liquid crystal layer between the first and second substrates;
a lower alignment layer on an inner surface of the first substrate;
an upper alignment layer on an inner surface of the second substrate; and
an upper polarizing plate on an outer surface of the second substrate,
wherein the lower and upper alignment layers determine an initial alignment state of the liquid crystal layer,
wherein the quantum rod layer comprises:
a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and
a quantum rod aligned along the first direction,
wherein the quantum rod is mixed with the photo-induced polymer to constitute a single layer with the photo-induced polymer,
wherein the quantum rod is uniformly aligned to the first direction by a reaction of the photo-induced polymer,
wherein the light source part has an edge type including a light source and a light guide plate at a side of the light source,
wherein the quantum rod layer directly contacts the light guide plate and the lower polarizing plate,
wherein the photo-reactive group is chemically combined to a main chain and/or a side chain of the base polymer and includes a material having a photo-isomerization reaction; and
wherein the photo-reactive group having the photo-isomerization reaction includes one selected from the group consisting of an azobenzene reacting to a light or a heat according to a following chemical reaction formula 1 and a moiety of a stilbene group reacting to a light or a heat according to a following chemical reaction formula 2:
2. The liquid crystal display device according to claim 1 , wherein the base polymer includes one selected from the group consisting of polyethylene (PE), polyethylene terephthalate (PET), polyimide (PI), polyacrylate (PA) and polyester.
3. The liquid crystal display device according to claim 1 , wherein the photo-induced polymer includes a first photo-induced polymer aligned along the first direction and a second photo-induced polymer aligned along the first direction due to modification and re-modification by a UV ray and a heat, and
wherein the quantum rod layer further comprises a modified polymer whose structure is changed by the UV ray.
4. The liquid crystal display device according to claim 1 , wherein a film including the quantum rod layer and at least one selected from the group consisting of a base layer, an adhesive layer, a moisture blocking layer, a contamination preventing layer and an optical compensating layer on or under the quantum rod layer is formed on one selected from the group consisting of the light source part and the first substrate.
5. A liquid crystal display device, comprising:
a light source part emitting a blue colored light;
a quantum rod layer over the light source part, the quantum rod layer emitting a white colored light of a polarized state having a peak at wavelengths corresponding to red, green and blue colors using the blue colored light;
first and second substrates over the light source part, the first and second substrates facing each other and spaced apart from each other;
a liquid crystal layer between the first and second substrates;
a lower alignment layer on an inner surface of the first substrate;
an upper alignment layer on an inner surface of the second substrate; and
an upper polarizing plate on an outer surface of the second substrate,
wherein the lower and upper alignment layers determine an initial alignment state of the liquid crystal layer,
wherein the quantum rod layer comprises:
a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and
a quantum rod aligned along the first direction,
wherein the quantum rod layer is disposed directly on and directly contacts an outer surface of the first substrate to function as a lower polarizing plate,
wherein the photo-reactive group is chemically combined to a main chain and/or a side chain of the base polymer and includes a material having a photo-isomerization reaction; and
wherein the photo-reactive group having the photo-isomerization reaction includes one selected from the group consisting of an azobenzene reacting to a light or a heat according to a following chemical reaction formula 1 and a moiety of a stilbene group reacting to a light or a heat according to a following chemical reaction formula 2:
6. A liquid crystal display device, comprising:
a light source part emitting a blue colored light;
a quantum rod layer over the light source part, the quantum rod layer emitting a white colored light of a polarized state having a peak at wavelengths corresponding to red, green and blue colors using the blue colored light;
first and second substrates over the light source part, the first and second substrates facing each other and spaced apart from each other;
a liquid crystal layer between the first and second substrates;
an upper alignment layer on an inner surface of the second substrate; and
an upper polarizing plate on an outer surface of the second substrate,
wherein the quantum rod layer and the upper alignment layer determine an initial alignment state of the liquid crystal layer,
wherein the quantum rod layer comprises:
a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and
a quantum rod aligned along the first direction,
wherein the quantum rod layer is disposed between the first substrate and the liquid crystal layer, and
wherein the quantum rod layer directly contacts an inner surface of the first substrate and the liquid crystal layer to function as a lower polarizing plate and a lower alignment layer,
wherein the photo-reactive group is chemically combined to a main chain and/or a side chain of the base polymer and includes a material having a photo-isomerization reaction; and
wherein the photo-reactive group having the photo-isomerization reaction includes one selected from the group consisting of an azobenzene reacting to a light or a heat according to a following chemical reaction formula 1 and a moiety of a stilbene group reacting to a light or a heat according to a following chemical reaction formula 2:
7. The liquid crystal display device according to claim 6 , further comprising a lower polarizing plate on an outer surface of the first substrate.