IP Library › Granted Patent US 10,054,864
Granted Patent B2
US 10,054,864 · App. 14/986,943 · Granted Aug 21, 2018

Toner, toner stored unit, and image forming apparatus

Inventors: Tomoki Murayama (Kanagawa, JP); Ryota Inoue (Shizuoka, JP); Masana Shiba (Shizuoka, JP); Daisuke Inoue (Shizuoka, JP); Junichi Awamura (Shizuoka, JP); Yoshitsugu Kimura (Kanagawa, JP); Rintaro Takahashi (Kanagawa, JP)
Assignee: Ricoh Company, Ltd.
G03G9/08755G03G15/00G03G15/0126
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Quick Facts
Patent No.
US 10,054,864
App. No.
14/986,943
Granted
Aug 21, 2018
Kind
B2
Abstract

A toner including a binder resin, wherein a toner extract obtained by drying an extraction liquid obtained through Soxhlet extraction of the toner with tetrahydrofuran (THF) has glass transition temperature Tg in a range of from 35° C. through 55° C., and a moisture-content change rate of the toner extract before and after leaving the toner extract to stand for 3 days in an environment of 40° C. and 70% RH is 0.5% or less, and wherein a specific-surface-area change rate of the toner before and after leaving the toner to stand for 3 days in an environment of 40° C. and 70% RH is in a range of from 15% through 50%.

Claims (21)

1. A toner comprising:

a binder resin comprising a crystalline polyester resin and an amorphous polyester resin, the amorphous polyester resin having a terminal group blocked with benzoic acid, wherein:

the toner has an endothermic peak in a range of from 40° C. through 70° C. at a first heating, and an endothermic peak in a range of from 20° C. through 50° C. at a second heating, as measured by differential scanning calorimetry (DSC),

a toner extract obtained by drying an extraction liquid obtained through Soxhlet extraction of the toner with tetrahydrofuran (THF) has glass transition temperature Tg in a range of from 35° C. through 55° C., and a moisture-content change rate of the toner extract before and after leaving the toner extract to stand for 3 days in an environment of 40° C. and 70% RH calculated as:

moisture-content change rate (%)=((weight after leaving to stand-weight before leaving to stand)/weight before leaving to stand)×100

is 0.5% or less, and

a specific-surface-area change rate of the toner before and after leaving the toner to stand for 3 days in an environment of 40° C. and 70% RH calculated as:

toner specific surface area change rate (%)=((BET specific surface area before storage-BET specific surface area after storage)/BET specific surface area before storage)×100

is in a range of from 15% through 50%.

2. A toner stored unit comprising:

a toner stored in the toner stored unit,

wherein the toner is the toner of claim 1 .

3. The toner according to claim 1 , wherein the binder resin further comprises a urea-modified polyester resin.

4. The toner according to claim 1 , wherein a ratio (Dw/Dn) of a weight average particle diameter (Dw) of the toner to a number average particle diameter (Dn) of the toner is 1.00-1.20.

5. An image forming apparatus comprising:

an electrostatic latent image bearer;

an electrostatic latent image forming unit configured to form an electrostatic latent image on the electrostatic latent image bearer;

a developing unit containing a toner and configured to develop the electrostatic latent image with the toner to form a visible image;

a transferring unit configured to transfer the visible image onto a recording medium to form a transferred image; and

a fixing unit configured to fix the transferred image on the recording medium,

wherein the toner is the toner of claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 4, 2016
From: MURAYAMA, TOMOKI; INOUE, RYOTA; SHIBA, MASANA; INOUE, DAISUKE; AWAMURA, JUNICHI; KIMURA, YOSHITSUGU; TAKAHASHI, RINTARO
To: RICOH COMPANY, LTD.
Reel/Frame 037400/0290 →
Priority Claims (2)
JP 2015-000400 · Jan 5, 2015 · national
JP 2015-232980 · Nov 30, 2015 · national
Continuity (1)
Related Publication 20160195827A1 · Jul 7, 2016