IP Library › Granted Patent US 10,662,311
Granted Patent B2
US 10,662,311 · App. 14/989,592 · Granted May 26, 2020

Thermoplastic films having asymmetric properties

Inventors: Steven Sargeant (Elizabethtown, KY); Sudhir Naik (Noida, IN); J. K. Sharma (Noida, IN); Pramod Sirsamkar (Noida, IN)
Assignee: FLEX FILMS (USA) INC.
C08K3/36B29C48/0018B29C48/0021B29C55/023B29D7/01B32B27/08B32B27/20B32B27/36C08J5/18C08J7/0427B29C55/143B29K2067/003B32B2038/0028B32B2255/10B32B2255/26B32B2264/102B32B2270/00B32B2307/518B32B2307/54B32B2307/5825B32B2307/702B32B2307/704B32B2307/732B32B2367/00C08J2367/02C08J2433/00C08J2475/04
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Quick Facts
Patent No.
US 10,662,311
App. No.
14/989,592
Granted
May 26, 2020
Kind
B2
Abstract

A thermoplastic film is provided that includes a biaxially-oriented polyethylene terephthalate (PET) layer, a tensile strength in the longitudinal and transverse directions of about 2000 kg/cm 2 or 3000 kg/cm 2 or more, and a tear force in the longitudinal direction that is about 1.5 times as large as a tear force in the transverse direction. Such a film can include two or more layers. Processes for producing the thermoplastic film are also provided.

Claims (34)

1. A thermoplastic film, comprising:

a biaxially-oriented polyethylene terephthalate (PET) layer;

an acrylic primer layer on at least one side of the film, wherein the acrylic primer layer comprises cross-linking agents;

a tensile strength in the longitudinal direction of about 2000 kg/cm 2 or more;

a tensile strength in the transverse direction of about 3000 kg/cm 2 or more;

a crystallinity in the transverse direction that is reduced as compared to a crystallinity in the longitudinal direction; and

a tear force in the longitudinal direction that is about 1.5 times as large as a tear force in the transverse direction;

wherein the polyethylene terephthalate layer comprises a polyethylene terephthalate homopolymer.

2. The film of claim 1 , wherein the polyethylene terephthalate layer further comprises a polyethylene terephthalate copolymer.

3. The film of claim 1 , further comprising a coating on at least one side of the film, the coating selected from the group consisting of an acrylic coating, a polyurethane coating, a polysulphonester coating, and a quaternary ammonium-based coating.

4. The film of claim 1 , wherein the film comprises two or more layers.

5. The film of claim 4 , wherein the film consists essentially of three layers.

6. The film of claim 4 , wherein one or more of the layers includes silica.

7. The film of claim 6 , wherein the one or more layers that include silica have a dynamic coefficient of friction to steel of about 0.45 or less.

8. The film of claim 6 , wherein the layer that includes silica is comprised of polyethylene terephthalate.

9. The film of claim 6 , wherein the layer that includes silica is interposed between layers that do not include silica.

10. The film of claim 6 , wherein the film comprises, from top to bottom, a first polyethylene terephthalate layer, a polyethylene terephthalate-silica layer, and a second polyethylene terephthalate layer.

11. The film of claim 1 , wherein the one or more layers that include silica have a dynamic coefficient of friction to steel of about 0.45 or less when heated to 150° C.

12. The film of claim 1 , wherein the film has a total thickness of about 50 μm or less.

13. The film of claim 1 , wherein the film has a total thickness of about 30 μm or less.

14. The film of claim 1 , wherein the film has a total thickness of about 5 μm to about 15 μm.

15. A process for producing the thermoplastic film of claim 6 , comprising:

producing a biaxially-oriented polyethylene terephthalate (PET) layer which comprises a polyethylene terephthalate homopolymer;

producing a biaxially-oriented polyethylene terephthalate layer that includes silica (PET-silica);

laminating the polyethylene terephthalate layer on one or both sides of the polyethylene terephthalate-silica layer to produce a multilayer film;

applying an acrylic primer layer on at least one side of the film;

stretching the multilayer film in a longitudinal direction; and

stretching the multilayer film in a transverse direction.

16. The process of claim 15 , wherein the step of stretching the multilayer film in the longitudinal direction includes stretching the multilayer film by a factor of about 2 to about 4.

17. The process of claim 15 , wherein the step of stretching the multilayer film in the transverse direction includes stretching the multilayer film by a factor of about 3 to about 4.5.

18. The process of claim 15 , wherein the step of stretching the multilayer film in the transverse direction is performed at a temperature of about 80° C. to about 140° C.

19. The process of claim 15 , further comprising coating at least one side of the multilayer film after the step of stretching the multilayer film in a longitudinal direction and prior to the step of stretching the multilayer film in the transverse direction.

20. The process of claim 19 , wherein coating the multilayer film comprises inline coating the multilayer film.

21. A thermoplastic film produced by the process according to claim 15 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 7, 2016
From: SARGEANT, STEVEN; NAIK, SUDHIR; SHARMA, J. K.; SIRSAMKAR, PRAMOD
To: FLEX FILMS (USA) INC.
Reel/Frame 037428/0184 →
Continuity (2)
Provisional Application 62100197 · Jan 6, 2015
Related Publication 20160193821A1 · Jul 7, 2016