Processes for recovering rare earth elements from aluminum-bearing materials
The present disclosure relates to processes for recovering rare earth elements from an aluminum-bearing material. The processes can comprise leaching the aluminum-bearing material with an acid so as to obtain a leachate comprising at least one aluminum ion, at least one iron ion, at least one rare earth element, and a solid, and separating the leachate from the solid. The processes can also comprise substantially selectively removing at least one of the at least one aluminum ion and the at least one iron ion from the leachate and optionally obtaining a precipitate. The processes can also comprise substantially selectively removing the at least one rare earth element from the leachate and/or the precipitate.
1. A process for recovering at least one rare earth element and/or at least one rare metal from an aluminum-bearing material, said process comprising:
leaching said aluminum-bearing material with an acid so as to obtain a leachate comprising at least one aluminum ion, at least one iron ion, said at least one rare earth element and/or said at least one rare metal, and a solid, and separating said leachate from said solid;
substantially selectively removing said at least one aluminum ion from said leachate by carrying out a precipitation, by carrying out a liquid-liquid extraction, by using a hollow-fiber membrane, by using an extracting agent and/or by using an ion exchange resin, thereby obtaining a composition comprising said at least one iron ion, and said at least one rare earth element and/or said at least one rare metal;
substantially selectively at least partially removing said at least one iron ion from said composition by carrying out a precipitation, by carrying out a liquid-liquid extraction, by using a hollow-fiber membrane, by using an extracting agent, by carrying out a hydrolysis and/or by using an ion exchange resin, thereby obtaining a liquor comprising said at least one rare earth element and/or said at least one rare metal; and
substantially selectively removing said at least one rare earth element and/or said at least one rare metal from said liquor by carrying out a precipitation, by carrying out a liquid-liquid extraction, by using an adsorption technique, by using an extracting agent, by carrying out an electrowinning process and/or by using an ion exchange resin.
2. The process of claim 1 , wherein said at least one aluminum ion is substantially selectively removed from said leachate by substantially selectively precipitating it from said leachate and removing it therefrom by carrying out a solid-liquid separation.
3. The process of claim 1 , wherein said at least one aluminum ion is substantially selectively removed from said leachate by substantially selectively crystallizing it in the form of AlCl 3 .6H 2 O and removing it therefrom by carrying out a solid-liquid separation.
4. The process of claim 2 , wherein said at least one iron ion is substantially selectively removed from said composition by carrying out an hydrolysis.
5. The process of claim 3 , wherein said at least one iron ion is substantially selectively removed from said composition by carrying out an hydrolysis to convert said at least one iron ion into Fe 2 O 3 and removing said Fe 2 O 3 from said composition by carrying out a solid-liquid separation, thereby obtaining said liquor comprising said at least one rare earth element and/or said at least one rare metal.
6. The process of claim 1 , wherein said at least one rare earth element and/or said at least one rare metal is substantially selectively removed from said liquor by carrying out a precipitation.
7. The process of claim 1 , wherein said at least one rare earth element and/or said at least one rare metal is substantially selectively removed from said liquor by means of an ion exchange resin.
8. The process of claim 1 , wherein said at least one rare earth element and/or said at least one rare metal is substantially selectively removed from said liquor by using an extracting agent.
9. The process of claim 5 , wherein said at least one rare earth element and/or said at least one rare is substantially selectively removed from said liquor by using an extracting agent.
10. The process of claim 5 , wherein said at least one rare earth element and/or said at least one rare metal is substantially selectively precipitated, extracted and/or isolated from said liquor by means of a liquid-liquid extraction.
11. The process of claim 10 , wherein said liquor comprises said at least one rare earth element in the form of a chloride and said at least one rare metal in the form of a chloride, and wherein said liquor is reacted with an extracting agent in order to substantially selectively extract gallium therefrom, thereby obtaining a Ga-free solution and an extracted gallium solution, and separating said solutions from one another.
12. The process of claim 1 , wherein said process comprises:
leaching said aluminum-bearing material with said acid to obtain a leachate and a solid residue, and separating said leachate from said solid residue;
at least partially removing said at least one aluminum ion from said leachate by substantially selectively precipitating said at least one aluminum to obtain an iron-rich aqueous composition comprising said at least one rare earth element and/or said at least one rare metal and a precipitate, and removing said precipitate from said composition;
substantially selectively precipitating said at least one iron ion from said iron-rich aqueous composition, and removing said precipitate therefrom, thereby obtaining thereby obtaining an iron-depleted aqueous composition comprising said at least one rare earth element and/or said at least one rare metal; and
substantially selectively extracting said at least one rare earth element and/or said at least one rare metal from said iron-depleted aqueous composition.
13. The process of claim 12 , wherein said at least one aluminum ion is precipitated in the form of AlCl 3 in a crystallizer by sparging gaseous HCl.
14. A process for recovering at least one rare earth element and/or at least one rare metal from an aluminum-bearing material, said process comprising:
leaching said aluminum-bearing material with said acid so as to obtain a leachate comprising at least one aluminum ion, at least one iron ion, and said at least one rare earth element and/or said at least one rare metal, and a solid and separating said leachate from said solid;
substantially selectively removing said at least one iron ion from said leachate by carrying out a precipitation, by carrying out a liquid-liquid extraction, by using a hollow-fiber membrane, by using an extracting agent, by carrying out a hydrolysis and/or by using an ion exchange resin, thereby obtaining a composition comprising said at least one aluminum ion, and said at least one rare earth element and/or said at least one rare metal; and
substantially selectively at least partially removing said at least one aluminum ion from said composition by carrying a precipitation, by carrying out a liquid-liquid extraction, by using a hollow-fiber membrane, by using an extracting agent and/or by using an ion exchange resin, thereby obtaining a liquor comprising said at least one rare earth element and/or said at least one rare metal; and
substantially selectively removing said at least one rare earth element and/or said at least one rare metal from said liquor by carrying out at least one of precipitation, liquid-liquid extraction, adsorption, extracting agent, electrowinning and ion exchange resin.
15. The process of claim 14 , further comprising at least one of
at least partially removing said at least one iron ion from said leachate by substantially complexing said at least one iron ion with an extracting agent;
selectively precipitating said at least one iron ion;
selectively precipitating said at least one aluminum ion; and
at least partially removing said at least one aluminum ion from said leachate by substantially complexing said at least one aluminum ion with another extracting agent.
16. The process of claim 14 , wherein said process comprises:
leaching said aluminum-bearing material with an acid so as to obtain a leachate and a solid residue, and separating said leachate from said solid residue;
at least partially removing said at least one iron ion from said leachate by substantially selectively precipitating said at least one iron ion by reacting said leachate with a base so as to obtain an Al-rich aqueous composition comprising said at least one rare earth element and/or said at least one rare metal and a precipitate, and removing said precipitate from said composition;
purifying said Al-rich aqueous composition by substantially selectively precipitating said at least one aluminum ion, thereby obtaining another composition comprising said at least one rare earth element and/or said at least one rare metal and another precipitate, removing said precipitate from said composition; and
substantially selectively extracting said at least one rare earth element and/or said at least one rare metal from said another composition.
17. The process of claim 14 , wherein said process comprises:
leaching said aluminum-bearing material with said acid to obtain a leachate and a solid residue, and separating said leachate from said solid residue,
at least partially removing said at least one iron ion from said leachate by substantially selectively precipitating said at least one iron ion by reacting said leachate with a base so as to obtain an Al-rich aqueous composition comprising said at least one rare earth element and/or said at least one rare metal and a precipitate, and removing said precipitate from said composition;
substantially selectively extracting said at least one aluminum ion from said Al-rich aqueous composition by means of a hollow fiber membrane, or by a liquid-liquid extraction, and removing said extracted at least one aluminum ion, thereby obtaining an Al-depleted aqueous composition comprising said at least one rare earth element and/or said at least one rare metal; and
substantially selectively extracting said at least one rare earth element and/or said at least one rare metal from said Al-depleted aqueous composition.
18. The process of claim 14 , wherein said process comprises:
leaching said aluminum-bearing material with said acid so as to obtain a leachate and a solid residue, and separating said leachate from said solid residue;
at least partially removing said at least one iron ion from said leachate by substantially selectively complexing said at least one iron ion with an extracting agent so as to obtain an Al-rich aqueous composition comprising said at least one rare earth element and/or said at least one rare metal;
purifying said Al-rich aqueous composition by substantially selectively precipitating said at least one aluminum ion, thereby obtaining another composition comprising said at least one rare earth element and/or said at least one rare metal and another precipitate, removing said precipitate from said composition; and
substantially selectively extracting said at least one rare earth element and/or said at least one rare metal from said another composition.
19. The process of claim 14 , wherein said process comprises:
leaching said aluminum-bearing material with said acid so as to obtain a leachate and a solid residue, and separating said leachate from said solid residue;
at least partially removing said at least one iron ion from said leachate by substantially selectively complexing said at least one iron ion with an extracting agent so as to obtain an Al-rich aqueous composition comprising said at least one rare earth element and/or said at least one rare metal;
substantially selectively extracting said at least one aluminum ion from said Al-rich aqueous composition by means of a hollow fiber membrane, or by a liquid-liquid extraction, and removing said extracted at least one aluminum ion, thereby obtaining an Al-depleted aqueous composition comprising said at least one rare earth element and/or said at least one rare metal; and
substantially selectively extracting said at least one rare earth element and/or said at least one rare metal from said Al-depleted aqueous composition.
20. The process of claim 14 , wherein said at least one iron ion is substantially selectively removed from said composition by carrying out an hydrolysis or by carrying out a precipitation.