Pavement marking method and composition

1. A method of depositing a structured paint material on a surface comprising:

introducing an initiator to a paint composition comprising methyl methacrylate (MMA) and a first retroreflective element to produce a liquid mixture;

depositing the liquid mixture on a surface of a substrate to produce a layer of structured paint material; and

depositing a layer of a second retroreflective element onto at least a portion of an upper surface of the deposited layer of structured paint material, wherein the first and the second retroreflective elements comprise a plurality of glass beads and the glass beads of the layer of the second retroreflective element are deposited such that each bead is embedded to a depth of at least 60% of a diameter of each bead and a coefficient of retroreflected luminance of the layer of structured paint material is initially at least 1400 mcd/m 2 /lux.

2. The method of claim 1 , wherein introducing the initiator to the paint composition comprises:

supplying the paint composition and the initiator under pressurized conditions to a first end of a nozzle;

randomly distributing the initiator and the paint composition within the nozzle.

3. The method of claim 1 , wherein the coefficient of retroreflected luminance of the layer of structured paint material is initially at least 1800 mcd/m 2 /lux.

4. The method of claim 1 , wherein coverage of the surface of the substrate by the layer of structured paint material is about 80%, and the layer of structured paint material has a thickness in a range of about 0.0 inches to about 0.250 inches.

5. The method of claim 1 , wherein the layer of structured paint material has an average thickness in a range of about 0.09 inches to about 0.125 inches.

6. The method of claim 1 , wherein the paint composition comprises at least 5% by weight MMA.

7. The method of claim 6 , wherein the initiator is a peroxide.

8. The method of claim 7 , wherein the weight ratio of peroxide to paint composition in the liquid mixture is in a range from 99-80:1-20.

9. The method of claim 1 , further comprising depositing the liquid mixture at a temperature below about 0° C.

10. The method of claim 1 , wherein depositing the liquid mixture creates a three-dimensional (3D) topography on a surface of the layer of structured paint material formed at least in part by at least one of the first and the second retroreflective elements.

11. The method of claim 1 , wherein the cure time for the deposited liquid mixture is about 15 minutes.

12. The method of claim 1 , wherein the layer of structured paint material is deposited to form a pavement marking.

13. A pavement marking formed from a layer of structured paint material comprising methyl methacrylate (MMA) and having a three-dimensional topography created by a plurality of glass beads embedded to a depth of at least 60% of a diameter of each bead in the layer of structured paint material, the layer of structured paint material deposited such that the pavement marking exhibits an initial coefficient of retroreflected luminance of at least 1400 mcd/m 2 /lux.

14. The pavement marking of claim 13 , wherein the layer of structured paint material comprises a paint composition and an initiator, the paint composition comprising at least 5% by weight of the MMA and at least 30% by weight glass beads.

15. The pavement marking of claim 13 , having a shore D hardness of at least 40.

16. The pavement marking of claim 13 , having a life expectancy of at least three years.

17. The deposition layer of claim 13 , wherein the pavement marking exhibits an initial coefficient of retroreflected luminance of at least 1800 mcd/m2/lux.

18. The pavement marking of claim 13 , wherein the pavement marking is hydrophobic.

19. The pavement marking of claim 13 , wherein the glass beads are constructed from quartz, soda lime, borosilicate, phosphosilcate, aluminosilicate, and aluminoborate glasses or non-vitreous ceramic materials.