Water soluble film, packets employing the film, and methods of making and using same
A water-soluble film including a polyvinyl alcohol copolymer resin, a plasticizer, an anti-block filler, and a release modifier is disclosed herein. Also disclosed are related packets incorporating the film, and related methods of making and using the film and packets.
1. A water-soluble film comprising a mixture of a water-soluble polyvinyl alcohol and a plasticizer blend comprising glycerol, sorbitol, and 2-methyl-1,3-propanediol, wherein
(i) the plasticizer blend is present in an amount in a range of 25 PHR to about 30 PHR; or
(ii) the plasticizer blend is present in an amount of at least 25 PHR and the individual components are
6.0PHR<glycerol<13.5PHR;
1.0PHR<sorbitol<5.0PHR; and
10.0PHR<2-methyl-1,3-propanediol<15.0PHR,
wherein the water-soluble polyvinyl alcohol comprises an anionic group modified polyvinyl alcohol, and the mixture further comprises propylene glycol, a modified starch filler, an antioxidant, a surfactant, a defoamer, a SiO 2 anti-block filler, and a stearic acid release modifier.
2. The water-soluble film of claim 1 , wherein the water-soluble polyvinyl alcohol comprises a monomethyl maleate co-polymer.
3. The water-soluble film of claim 1 , wherein the rate of anionic group modification is in a range of 1 to 10 mole %.
4. The water-soluble film of claim 1 , wherein (ii) the plasticizer blend is present in an amount of at least 25 PHR and the individual components are
6.0PHR<glycerol<13.5PHR;
1.0PHR<sorbitol<5.0PHR; and
10.0PHR<2-methyl-1,3-propanediol<15.0PHR,
and further wherein the plasticizer blend is present in an amount up to about 40 wt %.
5. The water-soluble film of claim 1 , wherein (i) the plasticizer blend is present in an amount in a range of 25 PHR to about 30 PHR and the individual components are
5.0PHR<glycerol<11.3PHR;
1.25PHR<sorbitol<7.5PHR; and
12.5PHR<2-methyl-1,3-propanediol<18.8PHR.
6. The water-soluble film of claim 1 , wherein (i) the plasticizer blend is present in an amount of about 30 PHR and the individual components are
6.0PHR<glycerol<13.5PHR;
1.5PHR<sorbitol<9.0PHR; and
15PHR<2-methyl-1,3-propanediol<22.5PHR.
7. The water-soluble film of claim 6 , wherein (i) the plasticizer blend is present in an amount of about 30 PHR and the individual components are
7.6PHR<glycerol<11.8PHR;
2.2PHR<sorbitol<7.3PHR; and
15PHR<2-methyl-1,3-propanediol<18.5PHR.
8. The water-soluble film of claim 1 , wherein the polyvinyl alcohol is a maleate polyvinyl alcohol copolymer having a carboxyl pendant group modification degree in a range of 6 mol % to 10 mol %, and a viscosity in a range of 10.5 cP to 22.5 cP, and a degree of hydrolysis in a range of about 80% to 99%.
9. The water-soluble film of claim 1 , wherein the polyvinyl alcohol is a methyl acrylate polyvinyl alcohol copolymer having a degree of modification of about 4.0 mol % to about 6.0 mol %, and a viscosity of about 10 cP to 30 cP, and a degree of hydrolysis of about 98.0% to about 99.8%.
10. The water-soluble film of claim 1 , wherein the SiO 2 anti-block filler is an untreated synthetic amorphous silica.
11. The water-soluble film of claim 10 , wherein the SiO 2 anti-block filler has a median particle size in a range of about 3 to about 11 microns.
12. The water-soluble film of claim 1 , wherein the mixture further comprises another release modifier selected from the group consisting of fatty acids other than stearic acid, fatty acid esters, fatty acid amides, linear or branched versions of any of the foregoing, saturated or unsaturated versions of any of the foregoing, substituted or unsubstituted versions of any of the foregoing and mixtures thereof.
13. The water-soluble film of claim 12 , wherein the other release modifier is a fatty acid other than stearic acid.
14. The water-soluble film of claim 1 , wherein the release modifier has a melting point of about 90° C. or less.
15. The water-soluble film of claim 14 , wherein the release modifier has a melting point of about 40° C. or greater.
16. The water-soluble film of claim 1 , wherein the SiO 2 anti-block filler and release modifier are present at a ratio in a range of 1:3 to 3:1.
17. The water-soluble film of claim 1 , wherein the SiO 2 anti-block filler is present in an amount of at least 0.1 PHR.
18. The water-soluble film of claim 1 , wherein the release modifier is present in an amount of at least 0.1 PHR.
19. The water-soluble film of claim 1 , wherein the SiO 2 anti-block filler and release modifier are collectively present in an amount of less than 4 PHR.
20. The water-soluble film of claim 1 , wherein the film has a static coefficient of friction of 4 or less.
21. The water-soluble film of claim 1 , wherein the film has a tear strength of at least 1000 g/mil.
22. A container comprising the film of claim 1 .
23. The container of claim 22 further comprising a liquid detergent therein, wherein the container, when immersed into bulk water at 20° C., does not release the liquid detergent for at least 30 seconds.
24. A water-soluble film comprising a mixture of a water-soluble polyvinyl alcohol and a plasticizer blend comprising glycerol, sorbitol, and trimethylolpropane, wherein the plasticizer blend is present in an amount of about 37.5 PHR to 45 PHR;
wherein the water-soluble polyvinyl alcohol comprises an anionic group modified polyvinyl alcohol, and the mixture further comprises propylene glycol, a modified starch filler, an antioxidant, a surfactant, a defoamer, a SiO 2 anti-block filler, and a stearic acid release modifier.