IP Library Granted Patent US 9,816,020
Granted Patent B2
US 9,816,020 · App. 15/015,390 · Granted Nov 14, 2017

Sintered shaped abrasive grains on basis of alumiunum oxide comprising mineralogical phases consisting of mullite, tialite and/or armalcolite, and baddeleyite and/or srilankite and a method for their production

Inventors: Jean-Andre Alary (L'Isle sur la Sorgue, FR); Alexander Hirsch (Villach, AT)
Assignee: Center for Abrasives and Refractories Research and Development C.A.R.R.D. GmbH
C09K3/1409C04B35/4885C04B2111/00129C04B2235/3217C04B2235/3232C04B2235/6021
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Quick Facts
Patent No.
US 9,816,020
App. No.
15/015,390
Granted
Nov 14, 2017
Kind
B2
Abstract

The present invention relates to sintered shaped abrasive grains on basis of aluminum oxide. Sintered shaped abrasive grains consistent with the disclosure include mineralogical phases made of mullite, tialite and/or armalcolite, and baddeleyite and/or srilankite. Methods for producing sintered shaped abrasive grains using alumina, ilmenite and zircon sand as raw materials are also provided.

Claims (31)

1. A method for producing sintered abrasive grains, comprising the steps:

preparing a homogeneous dry mixture of 85%-95% by weight alumina (Al 2 O 3 ), 1.0%-10% by weight zircon sand (ZrSiO 4 ), and 0.5%-8.0% by weight ilmenite (FeTiO 3 ), whereby raw-material-based impurities are less than 2% by weight;

adding at least one binder and at least one solvent together with one or more additives selected from the group comprising dispersants, lubricants and plasticizers for obtaining an extrudable mass;

extruding the mass;

cutting the extruded product to shaped abrasive grain precursors; and

sintering the shaped abrasive grain precursors in a temperature range between 1450° C. and 1650° C. to obtain sintered abrasive grains comprising corundum (Al 2 O 3 ), mullite (3Al 2 O 3 *2SiO 2 ), tialite and/or armalcolite (Al 2 TiO 5 /AlFeTiO 5 ) and baddeleyite and/or srilankite (ZrO 2 /Ti 0.75 Zr 0.25 O 2 ), wherein the sintered abrasive grains comprise a weight content of:

Al 2 O 3 between 85% and 95% by weight;

titanium compounds, expressed as TiO 2 , between 0.5% and 5.0% by weight;

silicon compounds, expressed as SiO 2 , between 0.3% and 4.0% by weight;

iron compounds, expressed as Fe 2 O 3 , between 0.4% and 9.0% by weight;

zirconium compounds, expressed as ZrO 2 , between 1.0% und 9.0% by weight; and

raw-material-based impurities of less than 2% by weight.

2. The method according to claim 1 , whereby the ratio by weight percent of zircon sand to ilmenite is from 1:6 to 6:1.

3. Sintered abrasive grains comprising corundum (Al2O3), mullite (3Al2O3*2 SiO2), tialite and/or armalcolite (Al2TiO5/AlFeTiO5) and baddeleyite and/or srilankite (ZrO2/Ti0.75Zr0.25O2), wherein the sintered abrasive grains comprise a weight content of

Al 2 O 3 between 85% and 95% by weight;

titanium compounds, expressed as TiO 2 , between 0.5% und 5.0% by weight;

silicon compounds, expressed as SiO 2 , between 0.3% and 4.0% by weight;

iron compounds, expressed as Fe 2 O 3 , between 0.4% and 9.0% by weight;

zirconium compounds, expressed as ZrO 2 , between 1.0% und 9.0% by weight; and

raw-material-based impurities of less than 2% by weight.

4. Sintered abrasive grains according to claim 3 , whereby the ratio by weight percent of mullite to tialite and/or armalcolite is from 6:1 to 1:6.

5. Sintered abrasive grains according to claim 3 having a density of ≧3.6 g/cm 3 and a hardness HV between 14 and 18 GPa.

6. Sintered abrasive grains according to claim 3 having a MKZ-value of ≦2.0%.

7. Sintered abrasive grains according to claim 6 having a MKZ-value of ≦1.2%.

8. Sintered abrasive grains according to claim 3 , whereby the sintered abrasive grains are rod shaped bodies having a diameter between 0.5 and 5 mm and a length between 1 and 10 mm, wherein the ratio of diameter to length is between 0.2:1.0 and 1.0:1.0.

9. Sintered abrasive grains according to claim 3 , wherein the sintered abrasive grains are manufactured by a method comprising the following steps:

preparing a homogeneous dry mixture of 85%-95% by weight alumina (Al 2 O 3 ), 1.0%-10% by weight zircon sand (ZrSiO 4 ), and 0.5%-8.0% by weight ilmenite (FeTiO 3 ), whereby raw-material-based impurities are less than 2% by weight;

adding at least one binder and at least one solvent together with one or more additives selected from the group comprising dispersants, lubricants and plasticizers for obtaining an extrudable mass;

extruding the mass;

cutting the extruded product to shaped abrasive grain precursors; and

sintering the shaped abrasive grain precursors in a temperature range between 1450° C. and 1650° C.

Assignments (3)
CHANGE OF NAME Recorded Feb 25, 2019
From: CENTER FOR ABRASIVES AND REFRACTORIES RESEARCH & DEVELOPMENT C.A.R.R.D. GMBH
To: IMERYS TECHNOLOGY CENTER AUSTRIA GMBH
Reel/Frame 048419/0532 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2019
From: IMERYS TECHNOLOGY CENTER AUSTRIA GMBH
To: IMERTECH SAS
Reel/Frame 048420/0322 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 30, 2016
From: ALARY, JEAN-ANDRÉ; HIRSCH, ALEXANDER
To: CENTER FOR ABRASIVES AND REFRACTORIES RESEARCH AND DEVELOPMENT C.A.R.R.D. GMBH
Reel/Frame 038133/0976 →
Priority Claims (2)
DE 10 2015 101 709 · Feb 6, 2015 · national
DE 10 2016 100 196 · Jan 6, 2016 · national
Continuity (1)
Related Publication 20160230058A1 · Aug 11, 2016