Curable composition for printed wiring board, and cured coating and printed wiring board using same
Provided is a curable composition for a printed wiring board, which composition exhibits high physical strength as a coating film in terms of solder heat resistance, pencil hardness and the like and in which the components contained therein are not likely to precipitate in long-term storage even when the composition is configured to have a low viscosity and thereby made applicable to ink-jet printing, spin-coating and the like. The curable composition for a printed wiring board is characterized by comprising (A) a filler having a specific gravity of 3 or less, (B) a hydroxyl group-containing (meth)acrylate compound and (C) a photopolymerization initiator. The (A) filler having a specific gravity of 3 or less is preferably an inorganic filler.
1. A curable composition for a printed wiring board, comprising:
a filler having a specific gravity of 3 or less;
a bifiinctional (meth)acrylate compound;
a hydroxyl group-containing (meth)acrylate compound; and
a photopolymerization initiator,
wherein the hydroxyl group-containing (meth)acrylate compound is in an amount of 5 to 50 parts by mass with respect to 100 parts by mass of the curable composition.
2. The curable composition for a printed wiring board according to claim 1 , wherein the filler is an inorganic filler.
3. The curable composition for a printed wiring board according to claim 1 , wherein the filler is particles having a maximum particle size in a range of 0.1 to 5 μm.
4. The curable composition for a printed wiring board according to claim 1 , wherein the bifunctional (meth)acrylate compound has a viscosity of 5 to 50 mPa·s at 25° C.
5. The curable composition for a printed wiring board according to claim 2 , wherein the bifunctional (meth)acrylate compound has a viscosity of 5 to 50 mPa·s at 25° C.
6. The curable composition for a printed wiring board according to claim 1 , further comprising a thermosetting component.
7. The curable composition for a printed wiring board according to claim 1 , wherein the curable composition has a viscosity in a range of 5 to 50 mPa·s at 50° C.
8. A cured coating film obtained by photoirradiating the curable composition of claim 1 .
9. A printed wiring board, comprising:
a substrate; and
a pattern-cured coating film obtained by printing the curable composition of claim 1 on the substrate and subsequently photoirradiating the curable composition primed on the substrate.
10. A printed wiring board, comprising:
a substrate; and
a pattern-cured coating film obtained by printing the curable composition of claim 1 on the substrate by an ink jet printing method and subsequently photoirradiating the curable composition printed on the substrate.
11. The printed wiring board according to claim 9 , wherein the substrate is a plastic substrate.
12. The printed wiring board according to claim 10 , wherein the substrate is a plastic substrate.
13. The curable composition for a printed wiring board according to claim 1 , wherein the filler is an inorganic filler in an amount of 5 to 30 parts by mass with respect to 100 parts by mass of the curable composition.
14. The curable composition for a printed wiring board according to claim 13 , wherein the filler is particles having a maximum particle size in a range of 0.1 to 5 μm.
15. The curable composition for a printed wiring board according to claim 1 , wherein the bifunctional (meth)acrylate compound is in an amount of 20 to 80 parts by mass with respect to 100 parts by mass of the curable composition.
16. The curable composition for a printed wiring board according to claim 1 , wherein the bifunctional (meth)acrylate compound has a viscosity of 5 to 30 mPa·s at 25° C.
17. The curable composition for a printed wiring board according to claim 1 , further comprising a thermosetting component in an amount of 1 to 30 parts by mass with respect to 100 parts by mass of the curable composition.
18. The curable composition for a printed wiring board according to claim 1 , wherein the bifunctional (meth)acrylate compound is in an amount of 40 to 70 parts by mass with respect to 100 parts by mass of the curable composition.
19. The curable composition for a printed wiring board according to claim 1 , wherein the photopolymerization initiator is in an amount of 0.5 to 10 parts by mass with respect to 100 parts by mass of the curable composition.
20. The curable composition for a printed wiring board according to claim 1 , wherein the filler is an inorganic filler in an amount of 5 to 30 parts by mass with respect to 100 parts by mass of the curable composition and is particles having a maximum particle size in a range of 0.1 to 5 μm, the bifunctional (meth)acrylate compound has a viscosity of 5 to 50 mPa·s at 25° C. and is in an amount of 20 to 80 parts by mass with respect to 100 parts by mass of the curable composition, and the photopolymerization initiator is in an amount of 0.5 to 10 parts by mass with respect to 100 parts by mass of the curable composition.