IP Library Granted Patent US 10,125,046
Granted Patent B2
US 10,125,046 · App. 15/029,183 · Granted Nov 13, 2018

Expanded, micronized surface treated aluminosilicate volcanic glass as lamellar functional filler for plastics and special coatings

Inventors: Athanasios Karalis (Attiki, GR); Ioannis Poulakis (St. Simons Island, GA); Salvatore Peter Larosa (Peru, NY); Christina Kapralou (Nea Makri, GR); Gary Charles Phillips (Allen Park, MI); Nils Rickertsen (Olfen, DE); Christos Dedeloudis (Nea Smyrni, GR); Doukas Efstathiadis (Acharnes Attikis, GR)
Assignee: S & B Industrial Minerals S.A.
C03C11/00C03C12/00C03C17/28C08K9/04C08K9/06C08L23/14C09D5/033C09D5/084C09D7/62C09D163/00
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Quick Facts
Patent No.
US 10,125,046
App. No.
15/029,183
Granted
Nov 13, 2018
Kind
B2
Abstract

The present disclosure relates to a composition comprising an expanded and micronized volcanic glass (EMVG) and at least one chemical agent, wherein the at least one chemical agent is coated on the surface of the volcanic glass. The present disclosure also relates to an improved process to remove mineral impurities and to coat the surface of the EMVG. The disclosed composition can be used a functional reinforcing filler to improve the mechanical properties of plastic.

Claims (25)

1. A powder coating composition comprising:

micronized expanded volcanic glass filler (EMVG); and

at least one chemical agent, wherein

the at least one chemical agent is coated on the surface of the EMVG,

the EMVG has a median particle size less than 10 μm, and

the powder coating composition is between 0.25% and 4% by weight of EMVG.

2. The powder coating composition of claim 1 , comprising at least two chemical agents coated on the surface of the EMVG.

3. The powder coating composition of claim 1 , wherein the at least one chemical agent is selected from the group consisting of a polymer, a wax, an emulsion, an organo-based silane, and combinations of any thereof.

4. The powder coating composition of claim 1 , wherein the EMVG is selected from the group consisting of a perlite, a pitchstone, a pumicite, and combinations of any thereof.

5. The powder coating composition of claim 1 , wherein the EMVG contains less than 5% mineral impurities.

6. The powder coating composition of claim 5 , wherein the EMVG is substantially free of mineral impurities.

7. The powder coating composition of claim 5 , wherein the mineral impurities comprise an impurity selected from the group consisting of ferromagnetic matter, crystalline silica, cristobalite, mica, feldspars, and combinations of any thereof.

8. A powder coating composition comprising

surface coated micronized expanded volcanic glass filler (c-EMVG) and

a material selected from the group consisting of a polyolefin, an

engineering plastic, and a coating, wherein

the c-EMVG has a median particle size less than 10 μm, and

the composition is between 0.25% and 4% by weight of c-EMVG.

9. The powder coating composition of claim 8 , wherein the polyolefin comprises polypropylene.

10. The powder coating composition of claim 8 , wherein the engineering plastic is selected from the group consisting of nylon 6, nylon 66, PC/ABS, PET/PBT, LCP, PC/ABS, LCP PET/PBT, PPE-PA, and combinations of any thereof.

11. The powder coating composition of claim 8 , wherein the coating comprises a powder coating.

12. The powder coating composition of claim 1 , wherein the powder coating composition is an epoxy based powder coating composition.

13. The powder coating composition of claim 12 , wherein the epoxy based powder composition comprises an epoxy phenolic or an epoxy-dicyandiamide (epoxy-D ICY).

14. The powder coating composition of claim 8 , wherein the powder coating composition is an epoxy based powder coating composition.

15. The powder coating composition of claim 14 wherein the epoxy based powder composition comprises an epoxy phenolic or an epoxy-dicyandiamide (epoxy-D ICY).

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2019
From: IMERYS INDUSTRIAL MINERALS GREECE SA
To: IMERTECH SAS
Reel/Frame 049124/0356 →
CHANGE OF NAME Recorded May 9, 2019
From: S & B INDUSTRIAL MINERALS S.A.
To: IMERYS INDUSTRIAL MINERALS GREECE SA
Reel/Frame 049124/0533 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNOR NAME PREVIOUSLY RECORDED AT REEL: 048419 FRAME: 0791. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 26, 2019
From: S & B INDUSTRIAL MINERALS SA
To: IMERTECH SAS
Reel/Frame 048436/0367 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2019
From: S & B INDUSTRIAL MINERALS.A.
To: IMERTECH SAS
Reel/Frame 048419/0791 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 19, 2018
From: KARALIS, ATHANASIOS; POULAKIS, IOANNIS; LAROSA, SALVATORE PETER; KAPRALOU, CHRISTINA; PHILLIPS, GARY CHARLES; RICKERTSEN, NILS; DEDELOUDIS, CHRISTOS; EFSTATHIADIS, DOUKAS
To: S & B INDUSTRIAL MINERALS S.A.
Reel/Frame 047231/0942 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 28, 2018
From: KARALIS, ATHANASIOS; POULAKIS, IOANNIS; LAROSA, SALVATORE PETER; KAPRALOU, CHRISTINA; PHILLIPS, GARY CHARLES; RICKERTSEN, NILS; DEDELOUDIS, CHRISTOS; EFSTATHIADIS, DOUKAS
To: S & B INDUSTRIAL MINERALS S.A.
Reel/Frame 047008/0071 →
Continuity (3)
Provisional Application 61891192 · Oct 15, 2013
Provisional Application 61891873 · Oct 16, 2013
Related Publication 20160257609A1 · Sep 8, 2016