IP Library › Granted Patent US 9,902,655
Granted Patent B2
US 9,902,655 · App. 15/029,440 · Granted Feb 27, 2018

Zirconium oxide-titanium oxide composite sol and production method thereof

Inventor: Taku Nishikawa (Osaka, JP)
Assignee: DAIICHI KIGENSO KAGAKU KOGYO CO., LTD.
C04B35/49C01G25/00C01G25/02C04B35/46C01P2002/50C01P2002/72C01P2004/04C01P2004/51C01P2004/64
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Quick Facts
Patent No.
US 9,902,655
App. No.
15/029,440
Granted
Feb 27, 2018
Kind
B2
Abstract

The present invention provides a zirconium oxide-titanium oxide composite sol comprising single nano-level, monodisperse, and amorphous zirconium oxide-titanium oxide composite nanoparticles. Specifically, the present invention provides a zirconium oxide-titanium oxide composite sol comprising zirconium oxide-titanium oxide composite nanoparticles dispersed in a dispersion medium; wherein the zirconium oxide-titanium oxide composite nanoparticles have a ZrO 2 /TiO 2 composition ratio of 95/5 to 50/50, and a primary particle diameter of 10 nm or less, and the dispersion medium is a polar dispersion medium.

Claims (11)

1. A zirconium oxide-titanium oxide composite sol comprising zirconium oxide-titanium oxide composite nanoparticles dispersed in a dispersion medium;

wherein the zirconium oxide-titanium oxide composite nanoparticles have a ZrO 2 /TiO 2 composition ratio of 95/5 to 50/50, and a primary particle diameter of 10 nm or less,

both zirconium oxide and titanium oxide contained in the zirconium oxide-titanium oxide composite nanoparticles have an amorphous crystal structure, and

the dispersion medium is a polar dispersion medium.

2. The zirconium oxide-titanium oxide composite sol according to claim 1 , wherein the composite sol has a haze value of 20% or less.

3. A method for producing a zirconium oxide-titanium oxide composite sol comprising zirconium oxide-titanium oxide composite nanoparticles dispersed in a dispersion medium, the method comprising:

(1) step 1 of mixing a zirconium salt solution and a titanium salt solution so that the ZrO 2 /TiO 2 composition ratio in terms of oxide is 95/5 to 50/50, thereby obtaining a mixed solution;

(2) step 2 of adding a base to the mixed solution to thereby obtain a zirconium-titanium composite hydroxide;

(3) step 3 of dispersing the zirconium-titanium composite hydroxide in a polar dispersion medium to thereby obtain a dispersion;

(4) step 4 of adding an acid to the dispersion to thereby obtain an acid dispersion; and

(5) step 5 of heating the acid dispersion under reflux at 90 to 120° C. to thereby obtain a zirconium oxide-titanium oxide composite sol.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 14, 2016
From: NISHIKAWA, TAKU
To: DAIICHI KIGENSO KAGAKU KOGYO CO., LTD.
Reel/Frame 038285/0656 →
Priority Claims (1)
JP 2013-217434 · Oct 18, 2013 · national
Continuity (1)
Related Publication 20160229751A1 · Aug 11, 2016