Integrated process for producing hydrocarbons
The present invention relates to an integrated process for producing hydrocarbons, wherein feedstock originating from renewable sources is subjected to catalytic hydroprocessing followed by separation of an aqueous component, a heavy component, and a light component, separating carbon dioxide and hydrogen sulfide from said light component to obtain a recycle stream, followed by dividing the recycle stream to a first recycle stream and a second recycle stream, directing the first recycle stream to the hydroprocessing system, and the second recycle stream to a hydrogen plant, where the light component is converted to hydrogen, and directing the hydrogen to the hydroprocessing system.
1. An integrated process for producing hydrocarbons, said process comprising the steps of
hydroprocessing a feedstock originating from renewable sources in a hydroprocessing system in the presence of a catalyst and hydrogen to produce an effluent;
separating the effluent into an aqueous component, a heavy component comprising hydrocarbons having a carbon number of more than 5, and a light component comprising gases and hydrocarbons having a carbon number of 1 to 5;
passing the light component to a separation to remove carbon dioxide and hydrogen sulfide to obtain a recycle stream comprising hydrogen and hydrocarbons having a carbon number of 1 to 5;
dividing the recycle stream into a first recycle stream and a second recycle stream;
passing the first recycle stream to the hydroprocessing system;
passing the second recycle stream to a hydrogen plant, wherein the hydrogen plant comprises a steam reformer unit, a desulfurization unit upstream the steam reformer unit, and water gas shift unit;
converting said hydrocarbons having a carbon number of 1 to 5 to a hydrogen stream in said hydrogen plant; and
passing the hydrogen stream from the plant to the hydroprocessing system.
2. The integrated process for producing hydrocarbons according to claim 1 , wherein natural gas, LPG, naphtha, biogas, methane, ethane, propane, butane or a combination thereof is used as starting material to the hydrogen plant.
3. The integrated process for producing hydrocarbons according to claim 2 , wherein the second recycle stream is directed to the desulfurization unit of the hydrogen plant and sulfur compounds are removed from the starting material.
4. The integrated process for producing hydrocarbons according to claim 1 , wherein the hydrogen plant comprises additionally a carbon dioxide/carbon monoxide/water separator unit.
5. The integrated process for producing hydrocarbons according to claim 1 , wherein the first recycle stream is combined with the hydrogen stream to obtain a combined stream, and the amount of hydrocarbons having carbon number from 1 to 5 in the combined stream is adjusted to the range not more than 30% by mole, calculated from the total amount of feedstock to the hydroprocessing system.
6. The integrated process for producing hydrocarbons according to claim 5 , wherein the hydrocarbons having carbon number from 1 to 5 comprise methane.
7. The integrated process for producing hydrocarbons according to claim 1 , wherein the light component is subjected to separation using one or more amine scrubbers capable of removing hydrogen sulfide and carbon dioxide.
8. The integrated process for producing hydrocarbons according to claim 1 , wherein the separation of the aqueous component, the heavy component, and the light component is carried out using a cold separator.
9. The integrated process for producing hydrocarbons according to claim 1 , wherein the heavy component is subjected to separation and/or fractionation to obtain hydrocarbons boiling in the transportation fuel range.
10. The integrated process for producing hydrocarbons according to claim 1 , wherein the feedstock originating from renewable source is selected from feedstock originating from plants, animals, algae, fish, microbiological processes, side streams and waste streams originating from processing said feedstocks, and sewage sludge.
11. The integrated process for producing hydrocarbons according to claim 1 , wherein the feedstock comprises plant oil, or compounds which are obtained as a by-product from the forest industry, and combinations thereof.
12. The integrated process for producing hydrocarbons according to claim 1 , wherein the hydrogen partial pressure in the catalytic hydroprocessing is in the range from 25 to 250 bar.
13. The integrated process for producing hydrocarbons according to claim 1 , wherein the total pressure in the catalytic hydroprocessing is from 25 to 250 bar.
14. The integrated process for producing hydrocarbons according to claim 1 , wherein the catalytic hydroprocessing is carried out at a temperature from 280 to 450° C.
15. A liquid hydrocarbon product obtainable by the process according to claim 1 .
16. The integrated process for producing hydrocarbons according to claim 1 , wherein the hydrogen partial pressure in the catalytic hydroprocessing is in the range from 60 to 200 bar.
17. The integrated process for producing hydrocarbons according to claim 1 , wherein the hydrogen partial pressure in the catalytic hydroprocessing is in the range from 80 to 150 bar.
18. The integrated process for producing hydrocarbons according to claim 1 , wherein the total pressure in the catalytic hydroprocessing is from 80 to 160 bar.
19. An integrated process for converting hydrocarbons having carbon number of 1 to 5 to hydrogen, the process comprising:
hydroprocessing a feedstock originating from renewable sources in a hydroprocessing system in the presence of a catalyst and hydrogen to produce an effluent;
separating the effluent into an aqueous component, a heavy component comprising hydrocarbons having a carbon number of more than 5, and a light component comprising gases and hydrocarbons having a carbon number of 1 to 5;
passing the light component to a separation unit to remove carbon dioxide and hydrogen sulfide to obtain a recycle stream comprising hydrogen and hydrocarbons having a carbon number of 1 to 5;
dividing the recycle stream into a first recycle stream and a second recycle stream,
passing the first recycle stream to the hydroprocessing system;
passing the second recycle stream to a hydrogen plant, wherein the hydrogen plant comprises a steam reformer unit, a desulfurization unit upstream of the steam reformer unit, and a water gas shift unit; and
converting the hydrocarbons having a carbon number of 1 to 5 in said hydrogen plant to hydrogen.
20. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein hydrogen stream comprising said hydrogen converted in said hydrogen plant is directed to the hydroprocessing system.
21. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein natural gas, LPG, naphtha, biogas, methane, ethane, propane, butane or a combination thereof is used as starting material to the hydrogen plant.
22. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 21 , wherein the second recycle stream is directed to the desulfurization unit of the hydrogen plant and sulfur compounds are removed from the starting material.
23. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein the hydrogen plant comprises additionally carbon dioxide/carbon monoxide/water separator unit.
24. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein the light component is subjected to separation using one or more amine scrubbers capable of removing hydrogen sulfide and carbon dioxide.
25. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein the feedstock originating from renewable source is selected from feedstock originating from plants, animals, algae, fish, microbiological processes, side streams and waste streams originating from processing said feedstocks, and sewage sludge.
26. The integrated process for converting hydrocarbons having carbon number from 1 to 5 to hydrogen according to claim 19 , wherein the feedstock comprises plant oil, or compounds which are obtained as a by-product from the forest industry, and combinations thereof.