Metal contacts to group IV semiconductors by inserting interfacial atomic monolayers
Techniques for reducing the specific contact resistance of metal-semiconductor (group IV) junctions by interposing a monolayer of group V or group III atoms at the interface between the metal and the semiconductor, or interposing a bi-layer made of one monolayer of each, or interposing multiple such bi-layers. The resulting low specific resistance metal—group IV semiconductor junctions find application as a low resistance electrode in semiconductor devices including electronic devices (e.g., transistors, diodes, etc.) and optoelectronic devices (e.g., lasers, solar cells, photodetectors, etc.) and/or as a metal source and/or drain region (or a portion thereof) in a field effect transistor (FET). The monolayers of group III and group V atoms are predominantly ordered layers of atoms formed on the surface of the group IV semiconductor and chemically bonded to the surface atoms of the group IV semiconductor.
1. An electrical contact, consisting of a metal and a group IV semiconductor separated by a monolayer of group III atoms at an interface between the metal and the group IV semiconductor, the atoms of the monolayer of group III being in epitaxial alignment with a lattice structure of the group IV semiconductor.
2. The contact of claim 1 , wherein the metal comprises atoms of a same metallic element that is the metallic element of the group III metal atoms.
3. The contact of claim 1 , wherein the metal comprises atoms of a different metallic element than that of the monolayer of group III metal atoms.
4. The contact of claim 3 , wherein the metal comprises ruthenium, tantalum nitride or titanium nitride.
5. The contact of claim 1 , wherein the group IV semiconductor comprises any of germanium, silicon, an alloy of silicon and germanium, an alloy of germanium and tin, an alloy of silicon with carbon, a compound of silicon and carbon, an alloy of germanium with carbon, a compound of germanium and carbon, silicon germanium carbon.
6. The contact of claim 1 , wherein the group III atoms comprise any one or more of aluminum, gallium, indium, or alloys of aluminum, gallium and/or indium.
7. The contact of claim 1 , wherein a surface of the group IV semiconductor at the interface is a {111}-oriented surface, a {110}-oriented surface, or a {100}-oriented surface.