Magnetic recording medium, and magnetic recording and reproducing apparatus
View Patent ↗A magnetic recording medium which is capable of effectively preventing a surface thereof from being contaminated, and is capable of preventing a contaminant thereon from adhering (being transferred) to a magnetic head, and a magnetic recording and reproducing apparatus including the magnetic recording medium are provided, A carbon protective layer of the magnetic recording medium is nitrided, and as a lubricant a compound A expressed by the following General Formula (1) and a compound B expressed by the following General Formula (2) are mixed and used. R 1 —C 6 H 4 OCH 2 CH(OH)CH 2 OCH 2 —R 2 —CH 2 OCH 2 CH(OH)CH 2 OH (1) CH 2 (OH)CH(OH)CH 2 OCH 2 CF 2 CF 2 (OCF 2 CF 2 CF 2 ) m OCF 2 CF 2 CH 2 OCH 2 CH(OH)CH 2 OH (2)
1. A magnetic recording medium comprising:
a magnetic layer, a protective layer, and a lubricant layer in this order on a non-magnetic substrate,
wherein the protective layer comprises carbon or hydrogenated carbon,
the lubricant layer is formed on the protective layer to come into contact therewith,
the carbon protective layer in an interface with the lubricant layer comprises nitrogen,
an amount of the nitrogen contained in the interface is in a range of 50 atomic % to 90 atomic %,
the lubricant layer comprises
a compound A expressed by the following General Formula (1):
R 1 —C 6 H 4 OCH 2 CH(OH)CH 2 OCH 2 —R 2 —CH 2 OCH 2 CH(OH)CH 2 OH (1)
wherein R 1 represents an alkoxy group having 1 to 4 carbon atoms, and
R 2 represents (i) —CF 2 O(CF 2 CF 2 O) x (CF 2 O) y CF 2 —, wherein those inside of parentheses of x, y are coupled in this order, in reverse order, or in a random manner, and x and y each represents real numbers of 0 to 15; (ii) —CF 2 CF 2 O(CF 2 CF 2 CF 2 O) z CF 2 CF 2 —, wherein z represents a real number of 1 to 15; or (iii) —CF 2 CF 2 CF 2 O(CF 2 CF 2 CF 2 CF 2 O)CF 2 CF 2 CF 2 —, wherein n represents a real number of 0 to 4, and
a compound B expressed by the following General Formula (2):
CH 2 (OH)CH(OH)CH 2 OCH 2 CF 2 CF 2 (OCF 2 CF 2 CF 2 ) m OCF 2 CF 2 CH 2 OCH 2 CH(OH)CH 2 OH (2)
wherein m represents an integer in a range of 4 to 60,
a mass ratio (A/(A+B)) of the compound A to the sum of the compound A and the compound B is in a range of 0.05 to 0.9, and
an average film thickness of the lubricant layer is in a range of 0.5 nm to 2 nm.
2. The magnetic recording medium according to claim 1 ,
wherein an average molecular weight of the compound A is in a range of 1000 to 2500.
3. The magnetic recording medium according to claim 1 ,
wherein an average molecular weight of the compound B is in a range of 1000 to 8000.
4. The magnetic recording medium according to claim 1 ,
wherein the protective layer comprises carbon or hydrogenated carbon, and only an interface of the protective layer with the lubricant layer is nitrided.
5. A magnetic recording and reproducing apparatus comprising:
the magnetic recording medium according to claim 1 ;
a medium drive unit that drives the magnetic recording medium in a recording direction;
a magnetic head that performs recording and reproduction of information on and from the magnetic recording medium;
a head-moving unit that moves the magnetic head relatively to the magnetic recording medium; and
a recording and reproducing signal-processing unit that perform processing of a recording and reproducing signal that is transmitted from the magnetic head.
6. The magnetic recording medium according to claim 1 ,
wherein the amount of the nitrogen contained in the interface is obtained by measuring a composition of the surface of the protective layer by secondary ion mass spectrometry (SIMS), after the protective layer is formed from carbon or hydrogenated carbon.
7. The magnetic recording medium according to claim 1 ,
wherein the interface with the lubricant layer is obtained by implanting a nitrogen ion into a surface of the protective layer or by exposing a surface of the protective layer to nitrogen plasma, after the protective layer is formed from carbon or hydrogenated carbon.
8. The magnetic recording medium according to claim 6 ,
into a surface of the protective layer or by exposing a surface of the protective layer to nitrogen plasma, after the protective layer is formed from carbon or hydrogenated carbon.
9. The magnetic recording medium according to claim 2 ,
wherein an average molecular weight of the compound B is in a range of 1000 to 8000.
10. The magnetic recording medium according to claim 2 , wherein the protective layer comprises carbon or hydrogenated carbon, and only an interface of the protective layer with the lubricant layer is nitrided.
11. The magnetic recording medium according to claim 3 , wherein the protective layer comprises carbon or hydrogenated carbon, and only an interface of the protective layer with the lubricant layer is nitrided.
12. The magnetic recording medium according to claim 9 ,
wherein the protective layer comprises carbon or hydrogenated carbon, and only an interface of the protective layer with the lubricant layer is nitrided.