IP Library Granted Patent US 9,472,408
Granted Patent B2
US 9,472,408 · App. 15/062,911 · Granted Oct 18, 2016

Nitridation on HDP oxide before high-k deposition to prevent oxygen ingress

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Quick Facts
Patent No.
US 9,472,408
App. No.
15/062,911
Granted
Oct 18, 2016
Kind
B2
Abstract

A method of reducing a migration of oxygen into a high-k dielectric layer of a semiconducting device is disclosed. An oxide layer of the semiconducting device is deposited on a substrate. A chemical composition of a top portion of the oxide layer is altered. The high-k dielectric layer is deposited on the top portion of the oxide layer to form the semiconducting device. The altered chemical composition of the top portion of the oxide layer reduces migration of oxygen into the high-k dielectric layer.

Claims (10)

1. A method of reducing a migration of oxygen into a high-k dielectric layer of a semiconducting device, comprising:

forming a substrate;

forming dummy gates on the substrate, the dummy gates separated by at least one first gap;

depositing a flowable oxide into the at least one first gap to form an oxide layer of the semiconducting device on the substrate;

altering a chemical composition of a top portion of the oxide layer by diffusing nitrogen into the top portion;

removing the dummy gates to define at least one second gap;

depositing the high-k dielectric layer on the top portion of the oxide layer and the at least one second gap to form the semiconducting device, wherein the altered chemical composition of the top portion of the oxide layer reduces migration of oxygen into the high-k dielectric layer and diffuses nitrogen into the top portion of the oxide layer;

depositing a titanium nitride layer on the high-k dielectric layer;

depositing a low resistivity metal into the at least one second gap; and

annealing the semiconductor device, wherein the top portion of the oxide layer prevents migration of oxygen from the oxide layer into the high-k dielectric layer during the annealing.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 11, 2020
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: ELPIS TECHNOLOGIES INC.
Reel/Frame 052620/0961 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 7, 2016
From: ANDO, TAKASHI; BASKER, VEERARAGHAVAN S.; FALTERMEIER, JOHNATHAN E.; JAGANNATHAN, HEMANTH; YAMASHITA, TENKO
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 037912/0527 →