Ceria electrolyte for low-temperature sintering and solid oxide fuel cell using the same
Disclosed is a ceria electrolyte for a solid oxide fuel cell, which is a ceria (CeO 2 ) electrolyte configured such that either gadolinium (Gd) or samarium (Sm) is co-doped with ytterbium (Yb) and bismuth (Bi), wherein Bi is doped in an amount of 0.5 to 5 mol %, thus exhibiting low-temperature sintering properties.
1. A ceria (CeO 2 ) electrolyte for low-temperature sintering, suitable for use in a solid oxide fuel cell, comprising:
gadolinium (Gd), ytterbium (Yb), and bismuth (Bi), which are simultaneously co-doped to exhibit a sintering density of 95% or more at a sintering temperature of 1200° C.,
wherein the ceria (CeO 2 ) electrolyte being simultaneously co-doped with Gd, the Yb, the Bi has an average cation radius of 0.98 to 0.99 Å and a composition of Chemical Formula 1 below:
Gd x Yb y Bi z Ce 1-x-y-z O 2−δ [Chemical Formula 1]
0.05≤X≤0.15, 0.005≤Y≤0.05, 0.005≤Z≤0.05, 0.06≤X+Y+≤0.25, δ=(X+Y+Z)/2.
2. A solid oxide fuel cell, comprising:
an anode;
a zirconia electrolyte, formed through co-sintering with the anode;
a ceria buffer layer, formed by coating a surface of the zirconia electrolyte with the ceria electrolyte of claim 1 and performing thermal treatment at 1100 to 1200° C.; and
a cathode, formed through coating and thermal treatment on a surface of the ceria buffer layer.
3. The solid oxide fuel cell of claim 2 , wherein the zirconia electrolyte is a fluorite-type stabilized zirconia-based electrolyte and has a composition of Chemical Formula 3 below:
(Re 2 O 3 ) x (ZrO 2 ) 1-x [Chemical Formula 3]
Re=at least one element selected from among Y, Sc, Yb, Ce, Gd, and Sm, 0.04≤X≤0.11.
4. The solid oxide fuel cell of claim 2 , wherein the cathode comprises a mixed conductor having a perovskite (ABO 3 )-based crystal structure with both electronic and oxygen ionic conductivities, and has a composition of Chemical Formula 4 below:
ABO 3 [Chemical Formula 4]
A=at least one element selected from among La, Sm, Pr, Ba, Sr, and Ca
B=at least one element selected from among Fe, Co, Ni, and Cu
A and B have a content ratio of 0.95≤A/B≤1.
5. The solid oxide fuel cell of claim 2 , wherein the cathode comprises a mixed conductor having a double-layer perovskite (ABC 2 O 5+δ )-based crystal structure with both electronic and oxygen ionic conductivities, and has a composition of Chemical Formula 5 below:
ABC 2 O 5+δ [Chemical Formula 5]
A=at least one element selected from among La, Sm, Nd, and Pr
B=at least one element selected from among Ba, Sr, and Ca
C=at least one element selected from among Co, Fe, Ni, Cu, and Mn.
6. The solid oxide fuel cell of claim 2 , wherein the cathode comprises 50 to 70 wt % of a mixed conductor having a perovskite (ABO 3 )-based crystal structure or a mixed conductor having a double-layer perovskite (ABC 2 O 5+δ )-based crystal structure and 30 to 50 wt % of a ceria-based electrolyte.
7. The solid oxide fuel cell of claim 2 , wherein the anode comprises 30 to 50 wt % of a fluorite-type stabilized zirconia-based electrolyte and 50 to 70 wt % of NiO.
8. The solid oxide fuel cell of claim 2 , wherein the solid oxide fuel cell has a unit cell configuration of an anode-supported cell (ASC), an electrolyte-supported cell (ESC), a metal-supported cell (MSC), or a segmented-type cell.
9. The solid oxide fuel cell of claim 8 , wherein a unit cell is provided in a planar-type, tubular-type or flat-tube-type form.