Calcium carbonate barrier films and uses thereof
The present invention provides polyolefin films comprising calcium carbonate that have a reduced moisture vapor transmission rate, methods of making the films, and packaging materials comprising the films.
1. A moisture vapor barrier film comprising:
a) a polyolefin base resin comprising a high density polyethylene (HDPE); and
b) a polyolefin carrier resin admixed with CaCO 3 that has been treated with a surface treatment agent;
wherein
the CaCO 3 and the carrier resin are present in a ratio of 15/85 to 80/20 by weight, the CaCO3 is present in the film in a total concentration of 5%-35% by weight, and the film has a moisture vapor transmission rate (MVTR) of 0.213-0.390 g water vapor-mil/100 in 2 of film/day at 37.5° C. and 100% relative humidity,
the carrier resin is a high density polyethylene (HDPE),
the surface treatment agent is one or more fatty acids having 8 to 24 carbon atoms,
the base resin comprises from 29.4% to 60.7% by weight of the moisture vapor barrier film,
the carrier resin comprises from 9.8% to 35.3% by weight of the moisture vapor barrier film,
the base resin has a melt index of 0.05-2.0 dg/min and a density of 0.958-0.963 g/cm 3 , and
the carrier resin has a melt index of 4-10 dg/min and a density of 0.958-0.963 g/cm 3 .
2. The moisture vapor barrier film of claim 1 , wherein the base resin has a density of 0.962 g/cm 3 .
3. The moisture vapor barrier film of claim 2 , wherein the base resin and the carrier resin differ in molecular weight, density, melt index and/or polydispersity index.
4. The moisture vapor barrier film of claim 1 , wherein the base resin has a melt index of 0.85-1.5 dg/min.
5. The moisture vapor barrier film of claim 1 , wherein the base resin has a melt index of 1 dg/min and a density of 0.962 g/cm 3 .
6. The moisture vapor barrier film of claim 1 , wherein the carrier resin has a density of 0.962 g/cm 3 .
7. The moisture vapor barrier film of claim 1 , wherein the carrier resin has a melt index of 6.5-8.0 dg/min.
8. The moisture vapor barrier film of claim 1 , wherein the carrier resin has a melt index of 6.5 dg/min and a density of 0.962 g/cm 3 .
9. The moisture vapor barrier film of claim 1 , wherein the concentration of CaCO3 in the film is 20-30% by weight.
10. The moisture vapor barrier film of claim 1 , wherein the CaCO 3 and the carrier resin are present in a ratio of 40/60 to 80/20 by weight.
11. The moisture vapor barrier film of claim 1 , wherein the CaCO 3 and the carrier resin are present in a ratio of 40/60 to 60/40 by weight.
12. The moisture vapor barrier film of claim 1 , wherein the CaCO 3 and the carrier resin are present in a ratio of 45/55 to 55/45 by weight.
13. The moisture vapor barrier film of claim 1 , wherein the CaCO 3 /carrier resin ratio is 50/50 by weight.
14. The moisture vapor barrier film of claim 1 , wherein the base resin is a medium molecular weight high density polyethylene (MMW-HDPE).
15. The moisture vapor barrier film of claim 1 , wherein the base resin is a MMW-HDPE having a melt index of 0.85 to 1.5 dg/min.
16. The moisture vapor barrier film of claim 1 , wherein the carrier resin is a medium molecular weight high density polyethylene (MMW-HDPE).
17. The moisture vapor barrier film of claim 1 , wherein the carrier resin is MMW-HDPE having a density of 0.962 g/cm 3 .
18. The moisture vapor barrier film of claim 1 , wherein the surface treatment agent is one or more selected from the group consisting of arachidic acid, behenic acid, capric acid, cerotic acid, isostearic acid, myristic acid, montanic acid, palmitic acid and stearic acid.
19. The moisture vapor barrier film of claim 1 , wherein the calcium carbonate has a median particle size of 0.7-2.5 μm, a top cut d98 of 4-15 μm, and a surface area of 3.3-10.0 m 2 /g.
20. The moisture vapor barrier film of claim 1 , wherein
the polyolefin base resin is a MMW-HDPE; and
the polyolefin carrier resin has a melt index of 6.5-8.0 dg/min.
21. The moisture vapor barrier film of claim 1 , wherein
the high density polyethylene (HDPE) base resin is a MMW HDPE;
the HDPE carrier resin has a melt index of 6.5-8.0 dg/min;
the CaCO 3 has a median particle size of 0.7-2.5 μm, a top cut d98 of 4-15 μm, a surface area of 3.3-10.0 m 2 /g, and a total concentration in the film of 5-35% by weight, and
the CaCO 3 has been treated with a surface treatment agent at a treatment level of 0.3-2.3% by weight.
22. The moisture vapor barrier film of claim 1 , wherein
the moisture vapor barrier film comprises MMW-HDPE and
the calcium carbonate (CaCO 3 ) has a median particle size of 0.7-2.5 μm, a top cut d98 of 4-15 μm, and a surface area of 3.3-10.0 m 2 /g.
23. A package for packing moisture sensitive material comprising the moisture vapor barrier film of claim 1 .
24. A multilayer film comprising a moisture vapor barrier film, wherein the moisture vapor barrier film comprises:
a) a polyolefin base resin comprising a high density polyethylene (HDPE); and
b) a polyolefin carrier resin admixed with CaCO3 that has been treated with a surface treatment agent;
wherein
the CaCO 3 and the carrier resin are present in a ratio of 15/85 to 80/20 by weight, the CaCO 3 is present in the film in a total concentration of 5%-35% by weight of the moisture vapor barrier film, and the moisture vapor barrier film has a moisture vapor transmission rate (MVTR) of 0.213-0.390 g water vapor-mil/100 in 2 of film/day at 37.5° C. and 100% relative humidity,
the carrier resin is a high density polyethylene (HDPE),
the surface treatment agent is one or more fatty acids having 8 to 24 carbon atoms,
the base resin comprises from 29.4% to 60.7% by weight of the moisture vapor barrier film,
the carrier resin comprises from 9.8% to 35.3% by weight of the moisture vapor barrier film,
the base resin has a melt index of 0.05-2.0 dg/min and a density of 0.958-0.963 g/cm 3 , and
the carrier resin has a melt index of 4-10 dg/min and a density of 0.958-0.963 g/cm 3 .
25. The multilayer film of claim 24 , wherein at least a first layer of the multilayer film comprises one or more of ethylene vinyl acetate (EVA), ethylene ethyl acetate (EEA), and ethylene acrylic acid (EAA), and at least a second layer of the multilayer film comprises polyolefin and calcium carbonate (CaCO 3 ), and wherein CaCO 3 is present in the multilayer film in a total concentration of 5%-35% by weight.
26. The multilayer film of claim 25 , wherein the first layer does not comprise CaCO 3 .
27. The multilayer film of claim 24 , wherein the base resin comprises from 29.4% to 53% by weight of the moisture vapor barrier film.
28. The multilayer film of claim 24 , wherein the carrier resin comprises from 23.5% to 35.3% by weight of the moisture vapor barrier film.
29. The multilayer film of claim 24 , wherein the CaCO 3 and the carrier resin are present in a ratio of 45/55 to 55/45 by weight of the moisture vapor barrier film.
30. The multilayer film of claim 24 , wherein the sum of the layers which comprise CaCO 3 , comprise from 75% to 95% by weight of the multilayer film.
31. The multilayer film of claim 24 , wherein the concentration of CaCO 3 in the moisture vapor barrier film is 20-30% by weight.
32. A package for packing moisture sensitive material comprising the multilayer film of claim 24 .