Solid lithium electrolyte via addition of lithium salts to metal-organic frameworks
Various embodiments of the invention disclose that the uptake of LiO i Pr in Mg 2 (dobdc) (dobdc 4− =1,4-dioxido-2,5-benzenedicarboxylate) followed by soaking in a typical electrolyte solution leads to a new solid lithium electrolyte Mg 2 (dobdc).0.35LiO i Pr.0.25LiBF 4 .EC.DEC. Two-point ac impedance data show a pressed pellet of this material to have a conductivity of 3.1×10 −4 S/cm at 300 K. In addition, the results from variable-temperature measurements reveal an activation energy of approximately 0.15 eV, while single-particle data suggest that intraparticle transport dominates conduction.
1. A method of forming a solid lithium electrolyte composition including a metal-organic framework comprises Mg 2 (dobdc), wherein dobdc=1,4-dioxido-2,5-benzenedicarboxylate and a lithium alkoxide comprising:
dissolving solid portions of H 4 dobdc and Mg(NO 3 ) 2 .H 2 O in a mixture of DMF, ethanol and deionized water and heating the solution to produce a solid;
soaking the resulting solid in DMF and then soaking in anhydrous methanol followed by filtering and evacuating the resultant solid to activate the metal-organic framework and form an activated framework;
reacting the activated framework with lithium isopropoxide in hexanes and collecting the sample by filtration and washing repeatedly with hexanes followed by evacuation; and
soaking the activated framework in a lithium tetrafluoroborate (LiBF4) solution including a mixture of ethylenecarbonate (EC) and diethylcarbonate (DEC).
2. The method of claim 1 , wherein the lithium alkoxide comprises lithium isopropoxide (LiO i Pr).
3. The method of claim 1 , wherein the lithium alkoxide comprises lithium ethoxide LiOEt).
4. The method of claim 1 , wherein the lithium alkoxide comprises lithium methoxide (LiOMe).
5. The method of claim 1 , wherein metal-organic framework comprises open metal cation Mg 2+ sites.
6. The method of claim 1 , wherein metal-organic framework further comprises lithium tetrafluoroborate (LiBF 4 ).
7. The method of claim 1 , wherein metal-organic framework further comprises ethylene carbonate (EC).
8. The method of claim 1 , wherein metal-organic framework further comprises diethyl carbonate (DEC).
9. The method of claim 1 , wherein the composition comprises Mg 2 (dobdc).0.35LiO i Pr.0.25LiBF 4 .EC.DEC.