Device for fabricating ion exchange membrane and method of fabricating the ion exchange membrane
The present disclosure relates to a technique for improving the ionic conductivity by introducing an electric field concept to a process for preparing an ion exchange membrane and deflecting an ion channel within an ion exchange membrane in one direction, and specifically to a device for fabricating an ion exchange membrane and a method therefor in a roll-to-roll manner and a casting manner with a deflected ion channel which can improve the ionic conductivity of the ion exchange membrane by reducing a travelling distance of the ions in the deflected ion channels.
1. A device for fabricating an ion exchange membrane, comprising:
a substrate on which a polymer solution is placed;
a doctor blade which is arranged spaced apart from the substrate, and is in contact with the polymer solution to transfer the same to both ends of the substrate to perform a casting process; and
a function generator which is electrically connected to the substrate and the doctor blade to give an AC voltage and an AC frequency.
2. The device of claim 1 , wherein the substrate and the doctor blade are formed of at least one material selected from the group consisting of stainless steel, aluminum (Al), iron (Fe), brass, and copper (Cu).
3. The device of claim 1 , wherein the doctor blade transfers the polymer solution at a rate of 5 to 7 mm/min toward one of both ends of the substrate.
4. The device of claim 1 , wherein while casting the polymer solution, the AC voltage and AC frequency are applied to the substrate and the doctor blade.
5. The device of claim 1 , further comprising an oscilloscope connected to the substrate and the doctor blade for measuring a change in voltages applied to the substrate and the doctor blade.
6. A method for fabricating an ion exchange membrane using the device according to claim 1 , comprising:
placing the polymer solution on the substrate; and
forming the ion exchange membrane by performing a casting process with the polymer solution using the device,
wherein an AC electric field is applied to the polymer solution while performing the casting process.
7. The method of claim 6 , wherein the polymer solution comprises:
at least one ion conductive polymer selected from the group consisting of a hydrocarbon-based polymer, a fluorine-based polymer, a partially fluorine-based polymer, and an aliphatic hydrocarbon-based polymer; and
an organic solvent.
8. The method of claim 6 , wherein the polymer solution comprises a sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO) and a solvent.
9. The method of claim 6 , wherein in the step of forming the ion exchange membrane, 1 to 2 V of AC voltage is applied to the substrate and the doctor blade.
10. The method of claim 6 , wherein in the step of forming the ion exchange membrane, 10 to 100 kHz of AC frequency is applied to the substrate and the doctor blade.
11. The method of claim 6 , wherein the ion exchange membrane has an aligned structure of ion channels from the applied AC electric field.