IP Library › Granted Patent US 10,190,187
Granted Patent B2
US 10,190,187 · App. 15/097,039 · Granted Jan 29, 2019

Manufacturing method for very high-strength, cold-rolled, dual-phase steel sheets

Inventors: Antoine Moulin (Woippy, FR); Veronique Sardoy (Saint Julien Metz, FR); Catherine Vinci (Jury, FR); Gloria Restrepo Gacess (Salon de Provence, FR); Tom Watershoot (Lokeren, BE); Mohamed Goune (Pont A Mousson, FR)
Assignee: ARCELORMITTAL
C21D9/46B22D7/00B22D11/001C21D1/84C21D6/004C21D6/005C21D6/008C21D8/021C21D8/0205C21D8/0226C21D8/0236C21D8/0263C21D8/0273C21D8/0278C22C38/001C22C38/002C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/50C22C38/54C22C38/58C23C2/02C23C2/06C23C2/28C23C2/36
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Quick Facts
Patent No.
US 10,190,187
App. No.
15/097,039
Granted
Jan 29, 2019
Kind
B2
Abstract

The present invention provides a cold-rolled and annealed Dual-Phase steel sheet having strength from 980 to 1100 MPa and a breaking elongation greater than 9%. The composition includes the contents being expressed by weight: 0.055%≤C≤0.095%, 2%≤Mn≤2.6%, 0.005%≤Si≤0.35%, S≤0.005%, P≤0.050%, 0.1≤Al≤0.3%, 0.05%≤Mo≤0.25%, 0.2%≤Cr≤0.5%, Cr+2Mo≤0.6%, Ni≤0.1%, 0.010≤Nb≤0.040%, 0.010≤Ti≤0.050%, 0.0005≤B≤0.0025%, and 0.002%≤N≤0.007%. The remainder of the composition includes iron and inevitable impurities resulting from the smelting. A manufacturing method is also provided.

Claims (57)

1. A manufacturing method for a cold-rolled and annealed Dual-Phase steel sheet, comprising the steps of:

supplying a steel sheet having a composition comprising:

0.055%≤C≤0.095%;

2%≤Mn≤2.6%;

0.005%≤Si≤0.35%;

S≤0.005%;

P≤0.050

0.1≤Al≤0.3%;

0.05%≤Mo≤0.25%;

0.2%≤Cr≤0.5%;

Cr+2Mo≤0.6%;

Ni≤0.1%;

0.010≤Nb≤0.040%;

0.010≤Ti≤0.050%;

0.0005≤B≤0.0025% and

0.002%≤N≤0.007%,

a remainder of the composition comprising iron and the inevitable impurities resulting from smelting;

casting the steel sheet as a semi-finished product;

bringing the semi-finished product to a temperature T R in which 1150° C. ≤T R ≤1250° C.;

hot-rolling the semi-finished product with an end-of-rolling temperature TFL ≥A r3 to obtain a hot-rolled product;

coiling the hot-rolled product at a temperature T bob in which 500° C. ≤T bob ≤570° C.;

descaling the hot-rolled product;

cold-rolling with a reduction from 30 to 80% to obtain a cold-rolled product;

heating the cold-rolled product at a rate 1° C./s≤Vc ≤5° C/s to an annealing temperature T M in which Ac1+40° C. ≤T M ≤Ac3-30° C. at which the product is held for a time 30s≤t M ≤300s so as to obtain a heated and annealed product with a structure comprising austenite and a non-recrystallized ferrite fraction less than or equal to 15%;

cooling the product to a temperature less than a temperature Ms at a rate V high enough for all of the austenite to transform to martensite;

the steel sheet having a tensile strength between 980 and 1100 MPA and a microstructure consisting of 40 to 65% ferrite, 35 to 50% martensite and 0 to 10% bainite.

2. The manufacturing method as recited in claim 1 , further comprising the steps of:

cooling the heated and annealed product at a rate V R high enough to prevent transformation of the austenite to ferrite, until a temperature close to the hot-dip galvanizing temperature T zn is reached;

continuously galvanizing the product by immersion in a bath of zinc or Zn alloy at a temperature 450° C. ≤T zn ≤480° C. to obtain a galvanized product;

cooling the galvanized product to ambient temperature at a rate V′ R greater than 4° C./s to obtain a cold-rolled, annealed and galvanized steel sheet.

3. The manufacturing method as recited in claim 1 , further comprising the steps of:

cooling the heated and annealed product at a rate V R high enough to prevent transformation of the austenite to ferrite, until a temperature close to the hot-dip galvanizing temperature T zn is reached;

continuously galvanized the product by immersion in a bath of zinc or Zn alloy at a temperature 450° C. ≤T zn ≤480° C. to obtain a galvanized product;

heating the galvanized product to a temperature TG from 490 to 550° C. for a time t G from 10 to 40s to obtain a galvannealed product;

cooling the galvannealed product to ambient temperature at a rate V″ R greater than 4° C./s, to obtain a cold-rolled and galvannealed steel sheet.

4. The manufacturing method as recited in claim 1 wherein the temperature T M is from 760 to 830° C.

5. The manufacturing method as recited in claim 2 , wherein the rate of cooling V R is greater than or equal to 15° C./s.

6. The manufacturing method as recited in claim 3 , wherein the rate of cooling V R is greater than or equal to 15° C./s.

7. A method for manufacturing a structural or safety part for a motor vehicle comprising:

the manufacturing method recited in claim 1 .

8. The manufacturing method as recited in claim 1 , wherein the microstructure of the cold-rolled and annealed dual-phase steel sheet consists of ferrite and martensite.

9. The manufacturing method as recited in claim 1 , wherein the composition of the steel sheet consists essentially of:

0.055%≤C≤0.095%;

2%≤Mn≤2.6%;

0.005%≤Si≤0.35%;

S≤0.005%;

P≤0.050%;

0.1≤Al≤0.3%;

0.05%≤Mo≤0.25%;

0.2%≤Cr≤0.5%;

Cr+2Mo≤0.6%;

Ni≤0.1%;

0.010≤Nb≤0.040%;

0.010≤Ti≤0.050%;

0.0005≤B≤0.0025% and

0.002%≤N≤0.007%,

a remainder of the composition consisting of iron and the inevitable impurities resulting from smelting.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 15, 2016
From: GOUNE, MOHAMED
To: ARCELORMITTAL
Reel/Frame 040945/0613 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 20, 2016
From: MOULIN, ANTOINE; SARDOY, VERONIQUE; VINCI, CATHERINE; RESTREPO GACESS, GLORIA; WATERSHOOT, TOM
To: ARCELORMITTAL
Reel/Frame 038656/0323 →
Priority Claims (1)
EP 08290474 · May 21, 2008 · regional
Continuity (2)
Continuation 12993498
Related Publication 20160222486A1 · Aug 4, 2016