Method for capping MQ-type silicone resins
An intermediate reaction product to speed the reaction for producing capped MQ resins is disclosed. The intermediate reaction product includes an MQ-type silicone resin; a halosilane capping agent; and a polar organic compound. Optionally, a condensation catalyst and a solvent may be added to prepare the intermediate reaction product. Also, a method for preparing a reaction product to speed the reaction for producing capped MQ resins is disclosed. The method comprises the steps of combining ingredients comprising: an MQ-type silicone resin; a halosilane capping agent; and a polar organic compound. Optionally, a condensation catalyst and a solvent may be added to prepare the reaction product.
1. A method for producing capped MQ resins, the method comprising the steps of combining an MQ-based silicone resin having the formula: R 1 n(RO) b SiO ((4-n-b)/2) , where each R 1 is monovalent and independently selected from hydrogen, hydrocarbyl, oximo, epoxide, carboxyl, ether, polyether, amide, and alkyl amino groups, which R1 moieties may be the same or different, with the proviso that at least sixty mole percent of the R 1 groups are hydrocarbyl, subscript n is 1.1 to 1.6, subscript b has a value such that group (RO) is 1 weight % to 20 weight % of the MQ-based silicone resin, and each R is hydrogen or an alkyl group of 1 to 4 carbon atoms; an alkenyl functional halosilane capping agent having the general formula R 5 R 4 2 SiR 3 , where each R 3 is a halogen atom, where each R 4 is H, a siloxy group or a monovalent hydrocarbyl group, and where each R 5 is an alkenyl group; and a polar organic compound.
2. The method of claim 1 , further including a condensation catalyst.
3. The method of claim 2 , wherein the condensation catalyst is added in an amount of 10 ppm to 10,000 ppm based on combined weights of the ingredients.
4. The method of claim 1 , further including a solvent.
5. The method of claim 4 , wherein the solvent is added in an amount sufficient to render the mixture a liquid under ambient conditions.
6. The method of claim 1 , wherein the halosilane capping agent is present in an amount sufficient to provide 0.05 to 5 moles of capping agent per mole of (RO) groups in the MQ-based silicone resin and the polar organic compound is present in an amount sufficient to provide 0.005 to 5 moles of polar organic compound per mole of (RO) groups in the MQ-based silicone resin.
7. The method of claim 1 , wherein each R is hydrogen, each R 1 is selected from methyl, vinyl, hydrogen, and phenyl, n is 1.1 to 1.5, and b is such that the group (RO) is 1 weight % to 4 weight % of the MQ-based silicone resin.
8. The method of claim 1 , wherein the alkenyl-functional halosilane capping agent is selected from the group consisting of dimethylhexenylchlorosilane, dimethylvinylchlorosilane, methylphenylvinylchlorosilane, dimethylvinylbromosilane, methylphenylvinylbromosilane, and combinations thereof.
9. The method of claim 1 , wherein the polar organic compound is selected from an alcohol, an ether, a ketone, an ester, and a combination thereof.
10. The method of claim 9 , wherein the polar organic compound is an alcohol and the alcohol is methyl alcohol, ethyl alcohol, iso-propyl alcohol, n-propyl alcohol, tert-butyl alcohol, sec-butyl alcohol, iso-butyl alcohol, n-butyl alcohol, n-hexanol or a combination thereof.
11. The method of claim 1 , wherein the acid catalyst is present and is selected from the group consisting of HCl, HBr, trifluoroacetic acid trifluoromethanesulfonic acid, and a strong acid ion exchange resin.
12. The method of claim 1 , further comprising heating the mixture and/or recovering the capped MQ-based silicone resin.
13. A capped MQ resin produced in accordance with the method of claim 1 .