Quantum dots with inorganic ligands in an inorganic matrix
The invention provides a luminescent material ( 10 ) based on quantum dots ( 100 ), wherein the quantum dots ( 100 ) have inorganic capping agents ( 110 ), wherein the luminescent material ( 10 ) comprises particles ( 12 ) having an inorganic salt matrix ( 14 ) hosting the quantum dots ( 100 ) with inorganic capping agents ( 110 ), wherein the luminescent quantum dots ( 100 ) have an outer layer ( 105 ). The invention also provides a method for the production of such luminescent material ( 10 ). The new luminescent material can be used and processed as conventional particulate luminescent material.
1. A method comprising:
providing luminescent quantum dots with an inorganic capping agent in a starting liquid;
precipitating in a co-precipitation process an inorganic salt comprising precipitated material from the starting liquid, the precipitated material comprising said quantum dots hosted by the co-precipitated inorganic salt; and
separating in a separation process the precipitated material from the starting liquid to thereby provide a luminescent material.
2. The method according to claim 1 , wherein the method comprises:
providing the luminescent quantum dots with an organic capping agent and providing in an exchange process said luminescent quantum dots with the inorganic capping agent in the starting liquid.
3. The method according to claim 2 , wherein the exchange process comprises a phase transfer process.
4. The method according to claim 1 , wherein subsequent to the separation process the precipitated material is further subjected to a process for providing luminescent material with a number averaged particle size in the range of 0.5-40 μm.
5. The method according to claim 1 , wherein the luminescent quantum dots have an outer layer, wherein in the co-precipitation process two or more salts (M 1 -A 1 ; M 2 -A 2 ) are applied, wherein at least one of the salts and the outer layer have an element in common, and wherein the inorganic capping agent and one or more of the salts have an element in common.
6. The method according to claim 1 , wherein the luminescent quantum dots have an outer layer comprising ZnS, wherein the inorganic capping agents comprise one or more of S 2− , HS − , SnS 4 4− , Sn 2 S 6 4− , ZnCl 4 2− , Zn(OH) 4 2− , and Zn(NO 3 ) 4 2− , and wherein the at least two salts comprise a first zinc salt and a second non-zinc salt, wherein the first zinc salt comprises a zinc cation and wherein the second non-zinc salt comprises an anion, and wherein the zinc cation and the anion form an insoluble salt in the starting liquid.
7. The method according to claim 1 , wherein at least two different types of luminescent quantum dots are provided, wherein the different types of luminescent quantum dots have different emission spectra upon excitation with blue or UV light.
8. The method of claim 1 , further comprising embedding the luminescent material in a wavelength converter element.
9. The method of claim 1 , further comprising configuring a light source in a lighting device to illuminate the luminescent material.
10. The method according to claim 9 , wherein the quantum dots are of the core-shell type, with a shell comprising ZnS, wherein the inorganic salt matrix hosting the quantum dots with inorganic capping agents also comprises ZnS, and wherein the capping agents comprise one or more of S 2− , HS − , SnS 4 4− , Sn 2 S 6 4− , ZnCl 4 2− , Zn(OH) 4 2− , and Zn(NO 3 ) 4 2− .
11. The method according to claim 9 , further comprising the embedding the luminescent material in a wavelength converter element and incorporating the wavelength converter element in the lighting device.