Method for manufacturing magnetic particles from a silicon oxide-iron core-shell structure
Provided is a method for manufacturing magnetic particles, in which an oxidation treatment, a reduction treatment, and a nitriding treatment are performed in that order on raw material particles with a core-shell structure in which a silicon oxide layer is formed on the surfaces of iron microparticles, thereby nitriding the iron microparticles while maintaining the core-shell structure. Due to this configuration, granular magnetic particles with a core-shell structure in which a silicon oxide layer is formed on the surfaces of iron nitride microparticles can be obtained.
1. A magnetic particle manufacturing method, comprising:
an oxidation treatment step of subjecting raw particles each having a core-shell structure in which a silicon oxide layer is formed on a surface of an iron fine particle to oxidation treatment;
a reduction treatment step of subjecting the raw particles having undergone the oxidation treatment to reduction treatment; and
a nitridation treatment step of subjecting the raw particles having undergone the reduction treatment to nitridation treatment to nitride iron fine particles with the core-shell structure being maintained,
wherein the oxidation treatment step, the reduction treatment step, and the nitridation treatment step are performed by thermal treatment.
2. The magnetic particle manufacturing method according to claim 1 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
3. The magnetic particle manufacturing method according to claim 1 , wherein the oxidation treatment is performed on the raw particles in air at 100° C. to 500° C. for 1 to 20 hours.
4. The magnetic particle manufacturing method according to claim 3 , wherein the reduction treatment is performed at 100° C. to 500° C. for 1 to 20 hours as mixed gas of hydrogen gas and nitrogen gas is supplied to the raw particles.
5. The magnetic particle manufacturing method according to claim 4 , wherein the nitridation treatment is performed at 140° C. to 200° C. for 3 to 50 hours as nitrogen element-containing gas is supplied to the raw particles.
6. The magnetic particle manufacturing method according to claim 5 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
7. The magnetic particle manufacturing method according to claim 4 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
8. The magnetic particle manufacturing method according to claim 3 , wherein the nitridation treatment is performed at 140° C. to 200° C. for 3 to 50 hours as nitrogen element-containing gas is supplied to the raw particles.
9. The magnetic particle manufacturing method according to claim 8 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
10. The magnetic particle manufacturing method according to claim 3 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
11. The magnetic particle manufacturing method according to claim 1 , wherein the reduction treatment is performed at 100° C. to 500° C. for 1 to 20 hours as mixed gas of hydrogen gas and nitrogen gas is supplied to the raw particles.
12. The magnetic particle manufacturing method according to claim 11 , wherein the nitridation treatment is performed at 140° C. to 200° C. for 3 to 50 hours as nitrogen element-containing gas is supplied to the raw particles.
13. The magnetic particle manufacturing method according to claim 12 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
14. The magnetic particle manufacturing method according to claim 11 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.
15. The magnetic particle manufacturing method according to claim 1 , wherein the nitridation treatment is performed at 140° C. to 200° C. for 3 to 50 hours as nitrogen element-containing gas is supplied to the raw particles.
16. The magnetic particle manufacturing method according to claim 15 , wherein the raw particles take on a spherical shape and have a particle size of less than 200 nm.