Energy efficient fractionation process for separating the reactor effluent from TOL/A9+ transalkylation processes
Processes and apparatus are disclosed for the energy efficient separation of the effluent from a TOL/A9+ transalkylation reactor. The apparatus includes a reboiled prefractionation column and a sidedraw tower that produces: 1) an overhead stream including unreacted toluene, 2) a stream including unreacted C9+ aromatics, a portion of which stream may be recycled to the reactor; and 3) a sidedraw stream including C8 aromatics that may be directed to a crystallization or selective adsorption paraxylene separation unit for recovery o a paraxylene product.
1. A process comprising the steps of:
(a) providing a prefractionation column feed stream comprising toluene, C8 aromatics, and C9+ aromatics to a reboiled prefractionation column to produce a prefractionation column top stream and a prefractionation column bottom stream; and
(b) providing the prefractionation column top stream and the prefractionation column bottom stream to a sidedraw column to produce a sidedraw column top stream comprising toluene, a sidedraw column first side stream comprising C8 aromatics, a sidedraw column second side stream comprising a liquid, and a sidedraw column bottoms stream comprising C9+ aromatics; and feeding the sidedraw second side stream to the prefractionation column as reflux.
2. The process of claim 1 , further comprising recovering paraxylene from the sidedraw column first side stream comprising C8 aromatics to produce a paraxylene product stream and a paraxylene lean stream.
3. The process of claim 1 , further comprising recycling at least a portion of the sidedraw column top stream to a transalkylation reactor.
4. The process of claim 1 , further comprising recycling at least a portion of the sidedraw column bottoms stream comprising C9+ aromatics to a transalkylation reactor.
5. The process of claim 1 , wherein the sidedraw column top stream is substantially free of C8 aromatics.
6. The process of claim 1 , wherein the sidedraw column side stream comprising C8 aromatics is substantially free of toluene and C9+ aromatics.
7. The process of claim 1 , wherein the sidedraw column receives the prefractionation column top stream as a vapor stream without condensation.