Method for incorporating micronutrients in the outer shell of urea-based particles
The invention concerns a method for incorporating micronutrients in an outer shell of urea-based particles, characterized in that it comprises the steps of a) applying a liquid concentrated mineral acid with a water content of at most 25 weight % to urea-based particles having a water content of at most 2 weight %, in order to at least form a double salt layer at the outer surface of the urea-based particles such that an acidified particle grasping layer is obtained, and subsequently b) applying a solid mineral base in powder form to the urea-based particles of step a) in order to react with the grasping layer of the urea-based particles; wherein the mineral acid or the solid mineral base are the source of any one of the micronutrients and wherein the liquid concentrated mineral acid and the solid mineral base in powder form are applied in a non-equimolar ratio between 0.1 and 1 mol/mol mineral acid/mineral base. The invention furthermore concerns a particulate urea-based fertilizer, comprising urea-based particles with a water content of at most 2 weight %, comprising micronutrients in an outer shell, the urea-based particles being obtained by a method according to the invention.
1. A method for incorporating at least one micronutrient in an outer shell of urea-based particles, said method comprising the steps of:
a) applying less than 2 weight % of a liquid concentrated mineral acid, relative to the weight of the urea-based particles, to urea-based particles having a water content of at the most 2 weight %, wherein the liquid concentrated mineral acid has a water content of at most 25 weight %, relative to the weight of the urea-based particles, and wherein the liquid concentrated mineral acid reacts with the urea in order to form at least a double salt layer on at least part of the outer surface of the urea-based particles such that an acidified particle grasping layer is obtained,
and subsequently
b) applying between 2 and 6 weight % of a solid mineral base in powder form, based on the weight of the urea-based particles, to the urea-based particles of step a) in order to attach the solid mineral base in powder form to the grasping layer of the urea-based particles;
wherein at least one of the mineral acid and the solid mineral base comprises at least one micronutrient,
wherein the outer shell comprises the acidified particle grasping layer with the solid mineral base in powder attached thereto, and
wherein the liquid concentrated mineral acid and the solid mineral base in powder form are applied in a non-equimolar ratio between 0.1 and 1 mol/mol mineral acid/mineral base.
2. The method according to claim 1 , wherein the water content of the liquid concentrated mineral acid is less than 25%.
3. The method according to claim 1 , wherein the liquid concentrated mineral acid is sulphuric acid.
4. The method according to claim 1 , wherein the liquid concentrated mineral acid and the solid mineral base in powder form are applied in a non-equimolar ratio between 0.1 and 0.5 mol/mol mineral acid/mineral base.
5. The method according to claim 1 , wherein the urea-based particles contain an amount of water which is less than 2 weight % or less, relative to the weight of the urea-based particles.
6. The method according to claim 1 , wherein between 0.1 and 2.0 weight % of liquid concentrated mineral acid and between 2 and 6weight % of solid mineral base in powder form, based on the weight of the urea-based particles, are applied to the particles of steps a) and b).
7. The method according to claim 1 , wherein between 0.9 and 1.0 weight % of liquid concentrated mineral acid and between 2.5 and 4.0weight % of solid mineral base in powder form, based on the weight of the urea-based particles, are applied to the particles of steps a) and b).
8. The method according to claim 1 , wherein between 0.2 and 0.8 weight % of liquid concentrated mineral acid and between 3 and 5.8weight % of solid mineral base, in powder form based on the weight of the urea-based particles are applied to the particles of steps a) and b).
9. The method according to claim 1 , further comprising the step of post-acidifying the particles obtained in step b).
10. The method according to claim 1 , wherein the micronutrients are selected from the group consisting of boron, chlorine, copper, iron, manganese, molybdenum, and zinc.
11. The method according to claim 1 , wherein the solid mineral base in powder form is selected from the group consisting of oxides, hydroxides, and carbonates of the micronutrients.
12. The method according to claim 11 , wherein the solid mineral base in powder form is selected from the group consisting of boric oxide (B 2 O 3 ), zinc oxide (ZnO), copper oxide (CuO), copper carbonate (CuCO 3 ), manganese (II) oxide (MnO), manganese dioxide (MnO 2 ), and colemanite (CaB 3 O 4 (OH) 3 H 2 O).
13. The method according to claim 1 , wherein steps a) and b) are performed simultaneously in a device, and wherein the device is capable of coating urea-based particles.
14. The method according to claim 1 , wherein first step a) and subsequently step b) are performed in a device, and wherein the device is capable of coating urea-based particles.
15. The method according to claim 1 , wherein the liquid concentrated mineral acid is sprayed onto the urea-based particles.
16. A particulate urea-based fertilizer comprising urea-based particles with a water content of at most 2 weight %, comprising micronutrients in an outer shell, wherein the urea-based particles are obtained by the method according to claim 1 .
17. A particulate urea-based fertilizer comprising urea-based particles with a water content of at most 2 weight %, comprising micronutrients in an outer shell, wherein the outer shell comprises:
a) less than 2 weight % of liquid concentrated mineral acid, relative to the weight of the urea-based particles, said liquid concentrated mineral acid having a water content of at most 25 weight %, reacting with urea in order to form at least a double salt layer on at least a part of the urea-based particles, and
b) between 2 and 6weight % of solid mineral base in powder form, based on the weight of the urea-based particles, wherein the liquid concentrated mineral acid or the solid mineral base in powder form comprise at least one micronutrient selected from the group consisting of boron, chlorine, copper, iron, manganese, molybdenum, and zinc.