OXIDATION OF SOLIDS BIO-CHAR FROM LEVULINIC ACID PROCESSES
The invention describes processes to convert biomass char, such as levulinic acid process char, into useful products.
1 . A method to convert biomass based char into water soluble products comprising the step:
subjecting biomass based char to an oxidant to provide a mixture, whereby the biomass based char of the mixture is converted into water soluble products.
2 . The method of claim 1 , wherein the biomass based char is a result of treatment of a biomass based material with a mineral acid.
3 . The method of claim 2 , wherein the biomass based material is a C5 sugar, a C6 sugar, a lignocelluloses, cellulose, starch, a polysaccharide, a disaccharide, a monosaccharide or mixtures thereof.
4 . The method of claim 3 , wherein the sugar is a high fructose corn syrup.
5 . The method of claim 3 , wherein the sugar is glucose, fructose, sucrose or combinations thereof.
6 . The method of claim 1 , wherein the oxidant is oxygen, air, a permanganate, nitric acid, or a peroxide.
7 . The method of claim 1 , wherein the mixture includes water.
8 . The method of claim 7 , wherein the mixture is subjected to the oxidant at a temperature of from about 20° C. to about 300° C.
9 . The method of claim 1 , wherein no char remains.
10 . The method of claim 1 , wherein the water soluble products are one or more of levulinic acid, acetic acid, succinic acid, formic acid or mixtures thereof.
11 . The method of claim 1 , further comprising a metal containing catalyst.
12 . The method of claim 11 , wherein the catalyst comprises a metal selected from platinum, palladium, ruthenium, copper, cobalt, nickel, vanadium, tungsten, iron, silver, manganese, or gold, or a combination thereof.