Direct polymer templating synthesis of mesoporous carbon
The invention is directed to a method for fabricating a mesoporous carbon composite material. The method comprises providing a precursor composition and subjecting the precursor material to a curing step followed by carbonization step. The precursor composition comprises (i) a templating component comprised of a linear homopolymer material, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) an acid catalyst.
1. A method of fabricating a mesoporous carbon composite material, the method comprising providing a precursor composition and subjecting the precursor material to a curing step followed by carbonization step, the precursor composition comprising (i) a templating component comprised of a linear homopolymer material, wherein the linear homopolymer material is polyethylene oxide, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) an acid catalyst, wherein a mesoporous carbon composite material is fabricated.
2. A method according to claim 1 , wherein the polyethylene oxide has a molecular weight between 2,000 to 200,000 Da.
3. A method according to claim 1 , wherein the phenolic compound or material is selected from the group consisting of phenol, catechol, resorcinol, dihydroquinone, phloroglucinol, cresols, halophenols, aminophenols, hydroxybenzoic acid, and dihydroxybiphenyls.
4. A method according to claim 1 , wherein the crosslinkable aldehyde component is formaldehyde.