Thermosetting resin composition, method for producing resin composition varnish, prepreg and laminate
Discloses are a thermosetting resin composition containing a maleimide compound including an unsaturated maleimide compound having a specified chemical structure, a thermosetting resin, an inorganic filler, and a molybdenum compound; a laminate plate for wiring boards obtained by coating a base material with a thermosetting resin composition containing a thermosetting resin, silica, and a specified molybdenum compound and then performing semi-curing to form a prepreg, and laminating and molding the prepreg; and a method for manufacturing a resin composition varnish including specified steps. According to the present invention, electronic components having low thermal expansion properties and excellent drilling processability and heat resistance, for example, a prepreg, a laminate plate, an interposer, etc., can be provided.
1. A method for manufacturing a wiring board to be used for semiconductor packages, comprising: a step of drilling processing for drilling a hole in a copper clad laminate plate which comprises a prepreg,
wherein the prepreg comprises a thermosetting resin composition comprising a component (A) comprising an unsaturated maleimide compound having an acidic substituent, a component (B) comprising a thermosetting resin, a component (C) comprising an inorganic filler, and a component (D) comprising a molybdenum compound.
2. The method according to claim 1 , wherein the hole is drilled in the copper clad laminate plate, after disposition of aluminum foil above the copper clad laminate plate and disposition of a paper phenol board under the copper clad laminate plate, in the step of drilling processing.
3. The method according to claim 1 , wherein the component (D) comprises one or more selected from the group consisting of molybdenum trioxide, zinc molybdate, ammonium molybdate, magnesium molybdate, calcium molybdate, barium molybdate, sodium molybdate, potassium molybdate, phosphomolybdic acid, ammonium phosphomolybdate, sodium phosphomolybdate, silicomolybdic acid, molybdenum boride, molybdenum disilicate, molybdenum nitride, and molybdenum carbide.
4. The method according to claim 1 , wherein the component (B) comprises one or more selected from the group consisting of an epoxy resin, a phenol resin, an unsaturated imide resin, a cyanate resin, an isocyanate resin, a benzoxazine resin, an oxetane resin, an amino resin, an unsaturated polyester resin, an allyl resin, a dicyclopentadiene resin, a silicone resin, a triazine resin, and a melamine resin.
5. The method according to claim 1 , wherein the component (C) comprises one or more selected from the group consisting of silica, alumina, talc, mica, kaolin, aluminum hydroxide, magnesium hydroxide, zinc borate, zinc stannate, zinc oxide, titanium oxide, boron nitride, calcium carbonate, barium sulfate, aluminum borate, potassium titanate, a glass powder, and hollow glass beads.
6. The method according to claim 5 , wherein the component (C) comprises the glass powder, and the glass powder comprises one or more selected from E-glass, S-glass, and D-glass.
7. The method according to claim 1 , wherein the component (C) comprises a fused spherical silica having an average particle size from 0.1 to 10 μm.
8. The method according to claim 1 , wherein the component (D) comprises one or more selected from the group consisting of a molybdenum oxide and a molybdic acid compound.
9. The method according to claim 1 , wherein a total sum content of the component (A) and the component (B) is from 30 to 80% by volume of the whole of the resin composition.
10. The method according to claim 1 , wherein a content of the component (C) is from 10 to 60% by volume of the whole of the resin composition.
11. The method according to claim 1 , wherein a content of the component (D) is from 0.02 to 20% by volume of the whole of the resin composition.