Fluorination process and reactor
The invention relates to a process to prepare tetrahalopropenes, such as 2-chloro-3,3,3-trifluoropropene (1233xf). The process comprises atomizing a feed material, such as 1,1,2,3-tetrachloropropene (1230xa) and the like, and mixing it with superheated HF to form a vaporized composition of feed material and HF with substantially instantaneous contact with a vapor phase fluorination catalyst. The invention extends catalyst life and forestalls catalyst deactivation.
1. A process to prepare 2-chloro-3,3,3-trifluoropropene (1233xf) comprising:
a) atomizing a starting composition comprising at least one compound having a structure selected from Formula I, II and II:
CX 2 ═CCl—CH 2 X (Formula I)
CX 3 —CCl═CH 2 (Formula II)
CX 3 —CHCl—CH 2 X (Formula III)
wherein X is independently selected from F, Cl, Br and I, provided that at least one of X is not F;
b) feeding said atomized starting composition into a fluorination reactor and contacting the atomized composition with superheated HF in said reactor to form a vaporized starting composition, which contacts a fluorination catalyst under conditions effective to form 1233xf.
2. The process of claim 1 wherein the vapor phase fluorination catalyst is selected from the group consisting of Cr 2 O 3 , FeCl 3 /C, Cr 2 O 3 /Al 2 O 3 , Cr 2 O 3 /AlF 3 , Cr 2 O 3 /carbon, CoCl 2 /Cr 2 O 3 /Al 2 O 3 , NiCl 2 /Cr 2 O 3 /Al 2 O 3 , CoCl 2 /AlF 3 , NiCl 2 /AlF 3 , and mixtures thereof.
3. The process of claim 1 wherein the contacting of step (b) occurs substantially instantaneously with formation of the vaporized starting composition.
4. A process to prepare 2,3,3,3-tetrafluoropropene (1234yf) comprising:
a) providing a first intermediate composition comprising 2-chloro-3,3,3-trifluoropropene (1233xf) as prepared according to claim 1 ;
b) contacting said first intemiediate composition comprising 1233xf with HF in the presence of a fluorination catalyst under conditions effective to produce a second intermediate composition comprising 244bb; and
c) dehydrochlorinating at least a portion of said 244bb to produce a reaction product comprising 1234yf.
5. The process according to claim 1 wherein HF and the starting composition have a residence time in a heating chamber of no greater than about 1 second wherein said reactor is comprised of a heating chamber.
6. The process according to claim 1 wherein the starting composition comprises a compound selected from the group consisting of 1,1,2,3,tetrachloropropene, 1,1,1,2,3-pentachloropropane, 2,3,3,3-tetrachloropropene and combination thereof.
7. The process according to claim 1 wherein the starting composition is atomized proximate the catalyst.
8. The process according to claim 1 wherein the starting composition is atomized by passing it through an atomizing nozzle exiting into the reactor, the nozzle located proximate to the catalyst.