Lithium sulfur nitrogen compound for anode barrier coating or solid electrolyte
Provided is a lithium-conductive solid-state electrolyte material that comprises a sulfide compound of a composition that does not deviate substantially from a formula of Li 9 S 3 N. The compound's conductivity is greater than about 1×10 −7 S/cm at about 25° C. and is in contact with a negative electroactive material. Also provided is an electrochemical cell that includes an anode layer, a cathode layer, and the electrolyte layer between the anode and cathode layers. In an example, the material's activation energy can be no greater than about 0.52 eV at about 25° C.
1. A battery comprising:
a cathode;
a barrier layer comprising a sulfide compound having a formula of Li 9 S 3 N;
an anode comprising an anode material electrically coupled to the sulfide compound; and
an electrolyte layer comprising the sulfide compound,
wherein the electrolyte layer is between the cathode and the anode, and the barrier layer is between the electrolyte layer and the anode, and
wherein an electrically conductive pathway is present between the sulfide compound and the anode material.
2. The battery of claim 1 , wherein the sulfide compound has a conductivity greater than about 5×10 −7 S/cm at about 25° C.
3. The battery of claim 2 , wherein the conductivity of the sulfide compound is greater than about 1×10 −6 S/cm.
4. The battery of claim 1 , wherein the sulfide compound is in contact with metallic lithium at a temperature lower than a melting temperature for metallic lithium.
5. The battery of claim 1 , wherein the sulfide compound is in contact with a lithiated material having a voltage within about 400 mV from metallic lithium's voltage.
6. The battery of claim 1 , wherein the sulfide compound is present in an anode barrier coating.
7. The battery of claim 1 , wherein the sulfide compound is present in an electrolyte.
8. The battery of claim 1 , wherein the sulfide compound has a conductivity of at least 1.0×10 −4 S/cm at a temperature of about 300K.