Lubricants with magnesium and their use for improving low speed pre-ignition
A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, one or more overbased calcium-containing detergents having a TBN greater than 225 mg KOH/g and one or more magnesium-containing detergents. A total amount of calcium from the one or more overbased calcium-containing detergents is from 900 ppm to less than 2400 ppm by weight, and a total amount of magnesium from the one or more magnesium-containing detergents is from 50 ppm to 500 ppm by weight, both based on a total weight of the lubricating oil composition. The lubricating oil composition and the method of using it are effective to reduce low speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition.
1. A lubricating oil composition comprising:
greater than 50 wt. % of a base oil of lubricating viscosity;
an overbased calcium sulfonate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896,
one or more magnesium-containing detergents, and
one of:
(a) an overbased calcium phenate or calcium salicylate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896, and
(b) at least one low-based calcium-containing detergent having a total base number of up to 175 mg KOH/g, measured by the method of ASTM D-2896 in an amount the provides at least 50 ppm by weight of calcium to the lubricating oil composition, based on a total weight of the lubricating composition,
wherein the lubricating oil composition includes an amount of the overbased calcium-containing detergents that provides 900 ppm by weight to less than 1800 ppm by weight of calcium to the lubricating oil composition, an amount of the magnesium-containing detergent that provides 50 ppm by weight to 1000 ppm by weight of magnesium to the lubricating oil composition, both amounts being based on a total weight of the lubricating oil composition based on a total weight of the lubricating oil composition; and the total calcium in the lubricating composition is up to about 1800 ppm, based on a total weight of the lubricating composition, and
the lubricating oil composition passes the TEOST-33 test and meets the ILSAC GF-5 performance requirement.
2. The lubricating oil composition of claim 1 , comprising an overbased calcium phenate detergent.
3. The lubricating oil composition of claim 1 , wherein the reduction of low speed pre-ignition (LSPI) events is 50% or greater reduction and the LSPI events are LSPI counts during 25,000 engine cycles, wherein the engine is operated at 2000 revolutions per minute with brake mean effective pressure of 18,000 kPa.
4. The lubricating oil composition of claim 1 , wherein the one or more magnesium-containing detergents are overbased magnesium-containing detergents having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896 and the one or more overbased magnesium-containing detergents are selected from an overbased magnesium sulfonate detergent, an overbased magnesium phenate detergent, an overbased magnesium salicylate detergent and mixtures thereof.
5. The lubricating oil composition of claim 1 , wherein the amount of the magnesium-containing detergent is sufficient to provide from about 100 ppm by weight to about 800 ppm by weight of magnesium to the lubricating oil composition, based on the total weight of the lubricating oil composition.
6. The lubricating oil composition of claim 1 , wherein the one or more overbased calcium-containing detergents provides from about 1000 to 1650 ppm by weight calcium to the lubricating oil composition based on a total weight of the lubricating oil composition.
7. The lubricating oil composition of claim 1 , wherein the lubricating oil composition has a ratio of a total mmol metal in the lubricating oil composition to a total base number of the lubricating oil composition ranging from greater than 4.5 to about 10.0.
8. The lubricating oil composition of claim 1 , wherein the total base number of the lubricating oil composition is at least 7.5 mg KOH/g.
9. The lubricating oil composition of claim 1 , comprising (b) the at least one low-based/neutral calcium-containing detergent.
10. The lubricating oil composition of claim 9 , wherein the at least one low-based/neutral calcium-containing detergent comprises a compound selected from a low-based calcium sulfonate detergent, a low-based calcium phenate detergent, a low-based calcium salicylate detergent and mixtures thereof.
11. The lubricating oil composition of claim 1 , wherein the total calcium in the lubricating oil composition ranges from about 1000 ppm to about 1800 ppm.
12. The lubricating oil composition of claim 1 , wherein the total calcium in the lubricating oil composition ranges from about 1050 ppm to about 1650 ppm.
13. The lubricating oil composition of claim 1 , further comprising one or more components selected from the group consisting of friction modifiers, antiwear agents, dispersants, antioxidants, and viscosity index improvers.
14. The lubricating oil composition of claim 1 , wherein the greater than 50% of base oil is selected from the group consisting of Group II, Group III, Group IV, Group V base oils, and a combination of two or more of the foregoing, and wherein the greater than 50 wt. % of base oil is other than diluent oils that arise from provision of additive components or viscosity index improvers in the composition.
15. The lubricating oil composition of claim 1 , wherein the lubricating oil composition is effective to reduce low speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition relative to a number of low speed pre-ignition events in the same engine lubricated with reference lubricating oil R-1,
wherein R-1 is formulated from about 80.7 wt. % of a Group III base oil, 12.1 wt. % of passenger car motor oil additive package and 7.2 wt. % of a 35 SSI ethylene/propylene copolymer viscosity index improver, and R-1 also showed the following properties and partial elemental analysis:
10.9
Kinematic Viscosity at 100° C., (mm 2 /sec)
3.3
TBS, APPARENT_VISCOSITY, cPa
2438
calcium (ppmw)
<10
magnesium (ppmw)
80
molybdenum (ppmw)
772
phosphorus (ppmw)
855
zinc (ppmw)
9.0
Total Base Number ASTM D-2896 (mg
KOH/g)
165
Viscosity Index.
16. A method for operating a boosted internal combustion engine comprising:
lubricating a boosted internal combustion engine with a lubricating oil composition comprising
greater than 50 wt. % of a base oil of lubricating viscosity;
an overbased calcium sulfonate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896,
an amount of one or more magnesium-containing detergents sufficient to provide 50 ppm by weight to 1000 ppm by weight of magnesium to the lubricating oil composition, based on a total weight of the lubricating oil composition, and
one of:
(a) an overbased calcium phenate or calcium salicylate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896, and
(b) at least one low-based calcium-containing detergent having a total base number of up to 175 mg KOH/g, measured by the method of ASTM D-2896 in an amount the provides at least 50 ppm by weight of calcium to the lubricating oil composition, based on a total weight of the lubricating composition,
wherein the lubricating oil composition includes an amount of the overbased calcium-containing detergents that provides 900 ppm by weight to less than 1800 ppm by weight of calcium to the lubricating oil composition, based on a total weight of the lubricating composition and the total calcium in the lubricating composition is up to about 1800 ppm, based on a total weight of the lubricating composition, and
operating the engine lubricated with the lubricating oil composition,
wherein the lubricant composition passes a TEOST 33 bench oxidation test and satisfies the ILSAC GF-5 performance requirement.
17. The method of claim 16 , wherein the low speed pre-ignition events in the boosted internal combustion engine lubricated with the lubricating oil composition are reduced relative to a number of low speed pre-ignition events in the same engine lubricated with reference lubricating oil R-,
wherein R-1 is formulated from about 80.7 wt. % of a Group III base oil, 12.1 wt. % of passenger car motor oil additive package and 7.2 wt. % of a 35 SSI ethylene/propylene copolymer viscosity index improver, and R-1 also showed the following properties and partial elemental analysis:
10.9
Kinematic Viscosity at 100° C., (mm 2 /sec)
3.3
TBS, APPARENT_VISCOSITY, cPa
2438
calcium (ppmw)
<10
magnesium (ppmw)
80
molybdenum (ppmw)
772
phosphorus (ppmw)
855
zinc (ppmw)
9.0
Total Base Number ASTM D-2896 (mg
KOH/g)
165
Viscosity Index.
18. The method of claim 17 , wherein LSPI events are based on LSPI counts during 25,000 engine cycles, wherein the engine is operated at 2000 revolutions per minute (RPM) with brake mean effective pressure (BMEP) of 18,000 kPa.
19. The method of claim 16 , wherein the amount of the magnesium-containing detergent is sufficient to provide from about 100 ppm by weight to about 800 ppm by weight of magnesium to the lubricating oil composition, based on the total weight of the lubricating oil composition.
20. The method of claim 16 , wherein the total calcium in the lubricating oil composition ranges from about 1000 ppm to about 1800 ppm.
21. The lubricating oil composition of claim 1 , comprising (a) the overbased calcium phenate or calcium salicylate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896.
22. The method of claim 16 , wherein the lubricating oil composition comprise (a) the overbased calcium phenate or calcium salicylate detergent having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896.
23. The method of claim 16 , wherein the lubricating oil composition comprises (b) the at least one low-based/neutral calcium-containing detergent.