Method for producing fluorinated copolymer latex, fluorinated copolymer latex, binder for producing electrode, electrode mixture for storage battery device, and electrode for storage battery device
To produce a method for producing a fluorinated copolymer latex with a low content of metal components and with favorable stability of the latex even with a low content of an organic solvent. A method for producing a fluorinated copolymer latex, which comprises emulsion-polymerizing a monomer mixture containing tetrafluoroethylene and propylene in the presence of an aqueous medium, an anionic emulsifying agent and a thermally decomposable radical polymerization initiator at a polymerization temperature within a range of from 50° C. to 100° C., wherein the aqueous medium comprises water alone, or water and a water-soluble organic solvent, and the content of the water-soluble organic solvent is less than 1 part by mass per 100 parts by mass of water; and the amount of use of the anionic emulsifying agent is from 1.5 to 5.0 parts by mass per 100 parts by mass of the fluorinated copolymer to be formed.
1. A method for producing a fluorinated copolymer latex, comprising:
emulsion-polymerizing a monomer mixture comprising tetrafluoroethylene and propylene in the presence of an aqueous medium, an anionic emulsifying agent and a thermally decomposable radical polymerization initiator at a polymerization temperature within a range of from 50° C. to 100° C. to produce a latex of a fluorinated copolymer,
wherein the aqueous medium comprises water alone, or water and a water-soluble organic solvent such that a content of the water-soluble organic solvent is less than 1 part by mass per 100 parts by mass of water,
the anionic emulsifying agent is present in the emulsion-polymerizing in an amount of from 1.5 to 5.0 parts by mass per 100 parts by mass of the fluorinated copolymer to be formed, and
the emulsion-polymerizing is performed such that the latex produced includes the fluorinated copolymer in a particulate form having an average particle size in a range of from 20 to 200 nm.
2. The method according to claim 1 , wherein the anionic emulsifying agent is sodium lauryl sulfate.
3. The method according to claim 1 , wherein the monomer mixture consists of tetrafluoroethylene and propylene.
4. The method according to claim 1 , wherein the emulsion polymerization is carried out in the absence of a pH adjusting agent.
5. The method according to claim 1 , wherein the fluorinated copolymer latex is a binder for producing an electrode of a storage battery device.
6. The method according to claim 1 , wherein the emulsion-polymerizing is performed in a presence of an anionic emulsifying agent comprising an alkali metal salt such that the fluorinated copolymer latex produced includes at least one metal component, including an alkali metal component of the anionic emulsifying agent, at a total content of at most 0.2 mass % per 100 mass % of the fluorinated copolymer latex.
7. The method according to claim 1 , wherein the anionic emulsifying agent is present in the emulsion-polymerizing in an amount of from 1.5 to 3.8 parts by mass per 100 parts by mass of the fluorinated copolymer to be formed.
8. The method according to claim 1 , wherein the anionic emulsifying agent is present in the emulsion-polymerizing in an amount of from 1.7 to 3.2 parts by mass per 100 parts by mass of the fluorinated copolymer to be formed.
9. The method according to claim 1 , wherein the polymerization temperature is within a range of from 60° C. to 90° C.
10. The method according to claim 1 , wherein the polymerization temperature is within a range of from 65° C. to 80° C.
11. The method according to claim 8 , wherein the polymerization temperature is within a range of from 65° C. to 80° C.
12. The method according to claim 1 , wherein the content of the water-soluble organic solvent is at most 0.5 part by mass per 100 parts by mass of water.
13. The method according to claim 1 , wherein the content of the water-soluble organic solvent is at most 0.1 part by mass per 100 parts by mass of water.
14. The method according to claim 1 , wherein the aqueous medium does not contain the water-soluble organic solvent.
15. The method according to claim 11 , wherein the aqueous medium does not contain the water-soluble organic solvent.
16. The method according to claim 1 , wherein the thermally decomposable radical polymerization initiator is one of disuccinic acid peroxide and azobisisobutyramidine dihydrochloride.
17. The method according to claim 1 , wherein the thermally decomposable radical polymerization initiator is a persulfate.
18. The method according to claim 1 , wherein the thermally decomposable radical polymerization initiator is ammonium persulfate.
19. The method according to claim 15 , wherein the thermally decomposable radical polymerization initiator is ammonium persulfate.
20. The method according to claim 11 , wherein the thermally decomposable radical polymerization initiator is ammonium persulfate.