Epoxy resin composition for encapsulating semiconductor device and semiconductor device encapsulated by the same
An epoxy resin composition for encapsulating a semiconductor device and a semiconductor device encapsulated by the epoxy resin composition, the composition including a base resin; a filler; a colorant; and a thermochromic pigment, wherein a color of the thermochromic pigment is irreversibly changed when a temperature thereof exceeds a predetermined temperature.
1. An epoxy resin composition for encapsulating a semiconductor device, the composition comprising:
a base resin;
a filler;
a colorant; and
a thermochromic pigment, wherein:
a color of the thermochromic pigment is irreversibly changed when a temperature thereof exceeds a predetermined temperature, and
the thermochromic pigment is a metal oxalate pigment.
2. The epoxy resin composition as claimed in claim 1 , wherein the thermochromic pigment is represented by the following Formula 1:
wherein, in Formula 1, a is 1 or 2, b is 1 to 10, and M is a metal element.
3. The epoxy resin composition as claimed in claim 2 , wherein the metal element is an alkali metal, an alkali earth metal, a group XIII element, a group XIV element, a group XI element, a group XII element, a group III element, a group IV element, a group V element, a group VI element, a group VII element, a group VIII element, a group IX element, or a group X element.
4. The epoxy resin composition as claimed in claim 1 , wherein the predetermined temperature at which the thermochromic pigment undergoes the irreversible color change is about 260° C. or higher.
5. The epoxy resin composition as claimed in claim 1 , wherein the thermochromic pigment is present in the epoxy resin composition in an amount of about 0.01wt % to about 5 wt %, based on a total weight of the epoxy resin composition.
6. The epoxy resin composition as claimed in claim 1 , wherein the colorant includes sodium, calcium, aluminum, tin, gold, zinc, yttrium, titanium, tantalum, chromium, manganese, iron, cobalt, iridium, nickel, palladium, or mixtures thereof.
7. The epoxy resin composition as claimed in claim 1 , wherein the colorant is present in the epoxy resin composition in an amount of about 0.05 wt % to about 10wt %, based on a total weight of the epoxy resin composition.
8. The epoxy resin composition as claimed in claim 1 , wherein the base resin includes an epoxy resin and a curing agent.
9. The epoxy resin composition as claimed in claim 1 , wherein the composition includes:
about 1 wt % to about 30 wt % of the base resin,
about 65 wt % to about 97 wt % of the filler,
about 0.05 wt % to about 10 wt % of the colorant, and
about 0.01 wt % to about 5 wt % of the thermochromic pigment, all wt % being based on a total weight of the epoxy resin composition.
10. The epoxy resin composition as claimed in claim 1 , further comprising: a curing accelerator.
11. The epoxy resin composition as claimed in claim 10 , wherein the curing accelerator includes a triphenylphosphine compound, an imidazole compound, or mixtures thereof.
12. The epoxy resin composition as claimed in claim 10 , wherein the curing accelerator is present in the epoxy resin composition in an amount of about 0.001 wt % to about 1 wt %, based on a total weight of the epoxy resin composition.
13. The epoxy resin composition as claimed in claim 1 , further comprising a white additive, the white additive including talc, barium sulfate, zinc sulfide, zinc sulfate, kaolin, or mixtures thereof.
14. The epoxy resin composition as claimed in claim 13 , wherein the white additive is present in the epoxy resin composition in an amount of about 0.1 wt % to about 20 wt %, based on a total weight of the epoxy resin composition.
15. The epoxy resin composition as claimed in claim 1 , further comprising a silane coupling agent.
16. The epoxy resin composition as claimed in claim 1 , wherein the color of the thermochromic pigment after the irreversible change is different from a color of the colorant.
17. The epoxy resin composition as claimed in claim 1 , wherein the color of the thermochromic pigment after the irreversible change is complementary to a color of the colorant.
18. A semiconductor device encapsulated by the epoxy resin composition as claimed in claim 1 .
19. A method of manufacturing a device, the method comprising:
encapsulating a semiconductor device with the epoxy resin composition as claimed in claim 1 ; and
marking a site on the encapsulated semiconductor device such that the site maintains a color that is different from other parts of the encapsulated semiconductor.
20. An epoxy resin composition for encapsulating a semiconductor device, the composition comprising:
a base resin;
a filler;
a colorant; and
a thermochromic pigment, wherein:
a color of the thermochromic pigment is irreversibly changed when a temperature thereof exceeds a predetermined temperature, and
the thermochromic pigment is present in the epoxy resin composition in an amount of about 0.01 wt % to about 5 wt %, based on a total weight of the epoxy resin composition.
21. An epoxy resin composition for encapsulating a semiconductor device, the composition comprising:
a base resin;
a filler;
a colorant; and
a thermochromic pigment, wherein:
a color of the thermochromic pigment is irreversibly changed when a temperature thereof exceeds a predetermined temperature, and
the color of the thermochromic pigment after the irreversible change is complementary to a color of the colorant.