Electrophoretic fluid
The present invention is directed to a display fluid comprising charged composite pigment particles dispersed in a solvent. The composite pigment particles have a density which matches to the density of the solvent in which they are dispersed. A display fluid comprising the composite pigment particles provides improved display performance.
1. An electrophoretic display fluid comprising a charge control agent and charged composite pigment particles dispersed in a hydrocarbon solvent,
wherein each of said charged composite pigment particles consist of at least one core pigment particle, an organic polymer shell, and steric stabilizer polymers, wherein each of the steric stabilizer polymers is chemically bonded on the surface of the organic polymer shell and each of the steric stabilizer polymers is selected from the group consisting of polyethylene, polypropylene, polyester, polysiloxane, and a mixture thereof,
wherein the density of the charged composite pigment particles substantially matches the density of the hydrocarbon solvent,
wherein the difference between the density of the composite pigment particles and the density of the hydrocarbon solvent is less than 2 g/cm 3 , and
wherein the hydrocarbon solvent comprises a halogenated solvent or a silicone oil solvent.
2. The electrophoretic display fluid of claim 1 , wherein said core pigment particle is an inorganic pigment particle.
3. The electrophoretic display fluid of claim 1 , wherein said core pigment particle is an organic pigment particle.
4. The electrophoretic display fluid of claim 1 , wherein said core pigment particle is surface treated.
5. The electrophoretic display fluid of claim 1 , wherein said core pigment particle is not surface treated.
6. The electrophoretic display fluid of claim 1 , wherein said organic polymer shell is formed from polyacrylate, polyurethane, polyurea, polyethylene, polyester, or polysiloxane.
7. The electrophoretic display fluid of claim 1 , wherein said organic polymer shell is completely incompatible or relatively incompatible with the hydrocarbon solvent.
8. The electrophoretic display fluid of claim 1 , wherein the surface of the organic polymer shell comprises functional groups to enable charge generation or interaction with the charge control agent.
9. The electrophoretic display fluid of claim 1 , wherein said organic polymer shell is formed from a polymer material having a polar functionality on a main chain or a side chain.
10. The electrophoretic display fluid of claim 9 , wherein the polar functionality is —COOH, —OH, —NH 2 , R—O—R or R—NH—R, wherein R is an alkyl or aryl group.
11. The electrophoretic display fluid of claim 9 , wherein the side chain has an aromatic moiety.
12. The electrophoretic display fluid of claim 1 , wherein the composite pigment particles are made from dispersion polymerization or living radical dispersion polymerization.
13. The electrophoretic display fluid of claim 1 , further comprising a second type of charged composite pigment particles.
14. The electrophoretic display fluid of claim 13 , wherein each of said second type of charged composite pigment particles consist of at least a core pigment particle, an organic polymer shell, and steric stabilizer polymers, wherein each of the steric stabilizer polymers is chemically bonded on the surface of the organic polymer shell; and the two types of charged pigment particles are of contrasting colors.
15. The electrophoretic display fluid of claim 13 , wherein the second type of charged composite pigment particles are formed from a conventional microencapsulation technique.
16. The electrophoretic display fluid of claim 1 , wherein said organic polymer shell is formed from monomers selected from the group consisting of styrene, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, vinyl pyridine, n-vinyl pyrrolidone, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, and dimethylaminoethyl methacrylate.