SLURRY COMPOSITION, USE THEREOF, AND POLISHING METHOD
Provided is a slurry composition including abrasive particles, halogen oxide, and nitroxide compound. The combination of halogen oxide and nitroxide compound has a synergistic effect to remove a substrate containing tungsten and silicon oxide. Moreover, a use of the slurry composition and a polishing method using the slurry composition are provided.
1 . A slurry composition, comprising:
a plurality of abrasive particles;
a halogen oxide; and
a nitroxide compound.
2 . The slurry composition of claim 1 , wherein the abrasive particles are selected from colloidal silicon oxide, fumed silicon oxide, nano aluminum oxide, or a combination of any two or more of the above.
3 . The slurry composition of claim 1 , wherein the halogen oxide is selected from chlorate, bromate, iodate, sodium hypochlorite, or a combination of any two or more of the above.
4 . The slurry composition of claim 1 , wherein the nitroxide compound is selected from pyridine-N-oxide, 4-methylpyridine-N-oxide, 2-methylpyridine-N-oxide, N-methylmorpholine-N-oxide, 5.5-dimethyl-1-pyrroline N-oxide, trimethylamine oxide, quinoline oxide, 2-mercaptopyridine oxide, or a combination of any two or more of the above.
5 . The slurry composition of claim 1 , wherein at least one nitrogen atom in the nitroxide compound is directly bonded to an oxygen atom.
6 . The slurry composition of claim 1 , wherein a content of the abrasive particles is 0.5 wt % to 10 wt %.
7 . The slurry composition of claim 1 , wherein a content of the halogen oxide is 100 ppm to 10000 ppm.
8 . The slurry composition of claim 1 , wherein a content of the nitroxide compound is 100 ppm to 10000 ppm.
9 . The slurry composition of claim 1 , wherein a content of the nitroxide compound is 300 ppm to 3000 ppm.
10 . The slurry composition of claim 1 , wherein a pH value of the slurry composition is between 2 and 6.
11 . The slurry composition of claim 1 , further comprising water-soluble starch having a molecular weight less than 8000.
12 . The slurry composition of claim 11 , wherein a content of the water-soluble starch is 100 ppm to 500 ppm.
13 . The slurry composition of claim 1 for performing chemical-mechanical polishing on a substrate containing tungsten and silicon oxide, wherein when a content of the abrasive particles is 0.5 wt % to 10 wt % and a content of the halogen oxide is greater than or equal to 3000 ppm, a removal ratio of tungsten to silicon oxide is greater than 1.
14 . The slurry composition of claim 1 for performing chemical-mechanical polishing on a substrate containing tungsten and silicon oxide, wherein when a content of the abrasive particles is 7.5 wt % to 10 wt % and a content of the halogen oxide is less than or equal to 1600 ppm, a removal ratio of tungsten to silicon oxide is less than 1.
15 . A use of the slurry composition of claim 1 for polishing the substrate containing tungsten and silicon oxide.
16 . A polishing method, comprising:
performing polishing on the substrate containing tungsten and silicon oxide using the slurry composition of claim 1 .