Piston ring
A piston ring is provided with a thermal spray coating that contains tungsten carbide and chrome carbide as a hard phase, and contains nickel as a metallic binder phase, and is characterized in that the thermal spray coating is formed by the spraying of a thermal spray powder that has been produced by means of a granulation sintering method, and that contains hard particles in which the mean particle diameter of the tungsten carbide has been adjusted by means of a BET method to fall within a range of not less than 0.15 μm and not more than 0.45 μm.
1. A method of coating a piston ring comprising:
manufacturing a thermal spray powder by adding tungsten carbide, chromium carbide, and nickel to a dispersion medium so as to create a slurry, creating granules from the slurry, sintering the granules, cracking the granules, and classifying the granules, the thermal spray powder containing nickel within a range of not less than 7.0 wt % and not more than 18.5 wt % and tungsten carbide particles of which mean particle diameter is in a range of not less than 0.15 μm and not more than 0.45 μm, and
thermal spraying the thermal spray powder to the piston ring to form the thermal spray coating on the piston ring,
wherein the method of coating the piston ring includes no step of forming a member on a surface of the thermal spray coating opposite to a surface of the thermal spray coating in contact with the piston ring.
2. The method of coating the piston ring according to claim 1 , wherein the thermal spray coating has a composition that contains 7.0 wt % of nickel, 20 wt % of chromium carbide, and the remainder is made up of tungsten carbide and impurities.
3. The method of coating the piston ring according to claim 1 , wherein the thermal spray coating has a composition that contains 12.5 wt % of nickel, and 37.5 wt % of chromium carbide, and the remainder is made up of tungsten carbide and impurities.
4. The method of coating the piston ring according to claim 1 , wherein a porosity of the thermal spray coating is 3% or less.
5. The method of coating the piston ring according to claim 1 , wherein the thermal spray coating is formed by spraying using a high-speed flame spraying method.