IP Library › Granted Patent US 9,938,171
Granted Patent B2
US 9,938,171 · App. 15/184,523 · Granted Apr 10, 2018

Chelating base product for use in water-based system treatments

Inventors: David Nicholas (Gulf Breeze, FL); Reid Henry Bowman (Fort Collins, CO); Freddie L. Singleton (Fruit Cove, FL)
Assignee: Earth Science Laboratories
C02F1/683C02F1/50C05C3/00C05D5/00C05D9/00C05D9/02C05G3/0064C02F1/505C02F1/68C02F2101/10C02F2103/42C02F2303/02C02F2303/04
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Quick Facts
Patent No.
US 9,938,171
App. No.
15/184,523
Granted
Apr 10, 2018
Kind
B2
Abstract

A base product fluid is produced by adding anhydrous liquid ammonia and a first portion of sulfuric acid to water in a process line to form a mixed fluid. The mixed fluid may be cooled and a second portion of sulfuric acid may be added to the mixed fluid to form the base product fluid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x . In the formula, a may be between 1 and 5, b may be between 1 and 5, c may be between 1 and 5, and x may be between 1 and 10.

Claims (47)

1. A chelating compound

having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is between 1 and 5, b is between 1 and 5, c is between 1 and 5, and x is between 1 and 10.

2. The chelating compound of claim 1 , wherein the chelating compound is crystalline.

3. The chelating compound of claim 1 , wherein the chelating compound is hydroscopic.

4. The chelating compound of claim 1 , wherein the chelating compound is capable of chelating a metal salt.

5. The chelating compound of claim 4 , wherein the metal salt comprises a salt of zinc, magnesium, manganese, selenium, molybdenum, iron, boron, cobalt, copper, or combinations thereof.

6. The chelating compound of claim 1 , wherein the chelating compound has a pH below about 2 when mixed with water.

7. The chelating compound of claim 1 , wherein a is 1, b is 1, c is 1, and x is between 1 and 6.

8. The chelating compound of claim 1 , wherein the nitrogen atoms in the chelating compound have an oxidation state of −3.

9. The chelating compound of claim 1 , wherein the sulfur atoms in the chelating compound have an oxidation state of +6.

10. A chelating compound

having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is at least 1, b is at least 1, c is at least 1, and x is between 1 and 10; and

wherein the chelating compound comprises an elemental composition of:

between about 3% and about 6% hydrogen;

between about 10% and about 15% nitrogen;

between about 25% and about 30% sulfur; and

between about 52% and about 60% oxygen.

11. The chelating compound of claim 10 , wherein the chelating compound is crystalline.

12. The chelating compound of claim 10 , wherein a is between 1 and 5, b is between 1 and 5, c is between 1 and 5, and x is between 1 and 10.

13. The chelating compound of claim 10 , wherein the chelating compound is hydroscopic.

14. The chelating compound of claim 10 , wherein the chelating compound is capable of chelating a metal salt.

15. The chelating compound of claim 14 , wherein the metal salt comprises a salt of zinc, magnesium, manganese, selenium, molybdenum, iron, boron, cobalt, copper, or combinations thereof.

16. The chelating compound of claim 10 , wherein the chelating compound has a pH below about 2 when mixed with water.

17. The chelating compound of claim 10 , wherein a is 1, b is 1, c is 1, and x is between 1 and 6.

18. The chelating compound of claim 10 , wherein the nitrogen atoms in the molecule have an oxidation state of −3.

19. The chelating compound of claim 10 , wherein the sulfur atoms in the molecule have an oxidation state of +6.

20. A chelating compound

having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is at least 1, b is at least 1, c is at least 1, and x is between 1 and 10; and

wherein the chelating compound has a pH below about 2 when mixed with water.

21. A chelating fluid, comprising:

a plurality of chelating compounds in a water solution, the chelating compounds having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a varies between 1 and 5 in the plurality of chelating compounds, b varies between 1 and 5 in the plurality of chelating compounds, c varies between 1 and 5 in the plurality of chelating compounds, and x varies between 1 and 10 in the plurality of chelating compounds.

22. The chelating fluid of claim 21 , wherein the chelating compounds are crystalline.

23. The chelating fluid of claim 21 , wherein the chelating compounds are hydroscopic.

24. The chelating fluid of claim 21 , wherein the chelating fluid is capable of chelating metal salts.

25. The chelating fluid of claim 24 , wherein the metal salt comprises a salt of zinc, magnesium, manganese, selenium, molybdenum, iron, boron, cobalt, copper, or combinations thereof.

26. The chelating fluid of claim 21 , wherein the chelating fluid has a pH below about 2.

27. The chelating fluid of claim 21 , wherein a is 1, b is 1, c is 1, and x is between 1 and 6.

28. The chelating fluid of claim 21 , wherein the nitrogen atoms in the chelating compounds have an oxidation state of −3.

29. The chelating fluid of claim 21 , wherein the sulfur atoms in the chelating compounds have an oxidation state of +6.

Assignments (4)
SECURITY INTEREST Recorded Sep 3, 2026
From: SEPRO CORPORATION
To: VARAGON CAPITAL PARTNERS AGENT, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 075890/0044 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2026
From: EARTH SCIENCE LABORATORIES, INC.
To: SEPRO CORPORATION
Reel/Frame 074852/0166 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S NAME INSIDE THE ASSIGNMENT DOCUMENT AND ON THE COVER SHEET PREVIOUSLY RECORDED AT REEL: 44419 FRAME: 725. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 4, 2021
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES, INC.
Reel/Frame 057179/0329 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 18, 2017
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES
Reel/Frame 044419/0725 →
Continuity (2)
Provisional Application 62182191 · Jun 19, 2015
Related Publication 20160368792A1 · Dec 22, 2016