IP Library › Granted Patent US 10,093,563
Granted Patent B2
US 10,093,563 · App. 15/184,531 · Granted Oct 9, 2018

Method for making chelating base product used in water-based systems

Inventors: David Nicholas (Gulf Breeze, FL); Reid Henry Bowman (Fort Collins, CO); Freddie L. Singleton (Fruit Cove, FL)
Assignee: Earth Science Laboratories
C02F1/683C02F1/50C05C3/00C05D5/00C05D9/00C05D9/02C05G3/0064C02F1/505C02F1/68C02F2101/10C02F2103/42C02F2303/02C02F2303/04
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Quick Facts
Patent No.
US 10,093,563
App. No.
15/184,531
Granted
Oct 9, 2018
Kind
B2
Abstract

A base product fluid is produced by adding anhydrous liquid ammonia and a first portion of sulfuric acid to water flowing in a process line to form a mixed fluid. The mixed fluid may be cooled by flowing the mixed fluid through a heat exchanger. A second portion of sulfuric acid may be added to the mixed fluid to form the base product fluid. The second portion of sulfuric acid may be greater, by weight, than the first portion of sulfuric acid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x .

Claims (15)

1. A method for producing a base product fluid, comprising:

flowing water through a process line;

adding and mixing anhydrous liquid ammonia and a first portion of sulfuric acid to water in a process line to form a mixed fluid;

cooling the mixed fluid by flowing the mixed fluid through a heat exchanger; and

adding a second portion of sulfuric acid to the mixed fluid to form the base product fluid, wherein the second portion of sulfuric acid is greater, by weight, than the first portion of sulfuric acid, wherein adding a second portion of sulfuric acid to the mixed fluid forms a chelating compound having the formula of ((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x , and wherein a is between 1 and 5, b is between 1 and 5, c is between 1 and 5, and x is between 1 and 10.

2. The method of claim 1 , wherein the chelating compound is capable of chelating a metal salt.

3. The method of claim 1 , wherein a ratio of the second portion of sulfuric acid to the first portion of sulfuric acid by weight is between about 2:1 and about 7.1.

4. The method of claim 1 , further comprising maintaining the ammonia as a liquid by cooling the ammonia to a temperature below a boiling point of ammonia at a pressure above atmospheric pressure.

5. The method of claim 1 , further comprising maintaining a pressure in the process line between about 40 psig and about 80 psig.

6. The method of claim 1 , further comprising combining the base product fluid with a metal salt and water to form an end product.

7. The method of claim 1 , wherein the chelating compound comprises an elemental composition of:

between about 3% and about 6% hydrogen;

between about 10% and about 15% nitrogen;

between about 25% and about 30% sulfur; and

between about 52% and about 60% oxygen.

Assignments (4)
SECURITY INTEREST Recorded Sep 3, 2026
From: SEPRO CORPORATION
To: VARAGON CAPITAL PARTNERS AGENT, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 075890/0044 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2026
From: EARTH SCIENCE LABORATORIES, INC.
To: SEPRO CORPORATION
Reel/Frame 074852/0166 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S NAME INSIDE THE ASSIGNMENT DOCUMENT AND ON THE COVER SHEET PREVIOUSLY RECORDED AT REEL: 044078 FRAME: 0849. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 4, 2021
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES, INC.
Reel/Frame 057138/0993 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 9, 2017
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES
Reel/Frame 044078/0849 →
Continuity (2)
Provisional Application 62182191 · Jun 19, 2015
Related Publication 20160368793A1 · Dec 22, 2016