Processes for preparing lithium carbonate
There are provided methods for preparing lithium carbonate. For example, such methods can comprise reacting an aqueous composition comprising lithium hydroxide with CO 2 by sparging the CO 2 the said composition, thereby obtaining a precipitate comprising the lithium carbonate. The methods can also comprise inserting at least a portion of the precipitate into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising the lithium carbonate, separating the solid from the supernatant; and heating the supernatant at a desired temperature so as to at least partially convert the lithium bicarbonate into lithium carbonate.
1. A process for preparing lithium carbonate, said process comprising :
submitting an aqueous composition comprising a lithium compound to an electrodialysis or electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide, wherein during said electrodialysis or electrolysis, said aqueous composition comprising said lithium compound is at least substantially maintained at a pH having a value of about 9.5 to about 12.5; and
converting said lithium hydroxide into lithium carbonate,
wherein during said electrodialysis or electrolysis, said pH is at least substantially maintained at a value of about 10 to about 12,
wherein said lithium compound comprises lithium sulphate, and
wherein during said process electrical current is at least substantially maintained at a density of about 400 to about 600 A/m 2 .
2. The process of claim 1 , wherein said process comprises submitting said aqueous composition comprising said lithium compound to said electrodialysis.
3. The process of claim 1 , wherein said process comprises submitting said aqueous composition comprising said lithium compound to said electrolysis.
4. The process of claim 1 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.0 to about 6.2.
5. The process of claim 1 , wherein during said electrodialysis or electrolysis, said pH is at least substantially maintained at a value of about 11 to about 12.
6. The process of claim 1 , wherein said electrodialysis or said electrolysis is carried out in a three-compartment membrane cell.
7. The process of claim 1 , wherein said electrodialysis or said electrolysis is carried out in a two-compartment membrane cell.
8. A process for preparing lithium carbonate, said process comprising :
leaching an acid roasted lithium-containing material with water so as to obtain an aqueous composition comprising Li + and at least one metal ion;
reacting said aqueous composition comprising Li + and said at least one metal ion with a base so as to obtain a pH of about 4.5 to about 6.5 and thereby at least partially precipitating said at least one metal ion under the form of at least one hydroxide so as to obtain a precipitate comprising said at least one hydroxide and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
optionally reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5, and with optionally at least one metal carbonate, thereby at least partially precipitating at least one metal ion optionally under the form of at least one carbonate so as to obtain a precipitate optionally comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
contacting said aqueous composition comprising Li + and having a reduced content of said at least one metal ion with an ion exchange resin so as to at least partially remove at least one metal ion from said composition, thereby obtaining an aqueous composition comprising a lithium compound;
submitting said aqueous composition comprising said lithium compound to an electrodialysis or an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide; and
converting said lithium hydroxide into lithium carbonate.
9. The process of claim 8 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.0 to about 6.2.
10. The process of claim 8 , wherein said at least one metal ion comprised in said aqueous composition that is reacted with said base so as to obtain a pH of about 4.5 to about 6.5 is chosen from Fe 2+ , Fe 3+ and Al 3+ .
11. The process of claim 8 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 9.5 to about 11.5.
12. The process of claim 8 , wherein said acid roasted lithium-containing material is leached with water so as to obtain said aqueous composition comprising Li + and at least three metal ions chosen from the following metals: iron, aluminum, manganese and magnesium.
13. The process of claim 8 , wherein said aqueous composition comprising Li + and having said reduced content of said at least one metal ion is reacted with said another base over a period of time sufficient for reducing the content of said at least one metal ion in said aqueous composition below a predetermined value.
14. The process of claim 13 , wherein said reaction is carried out over a period of time sufficient for reducing the content of Ca 2+ below about 200 mg/L.
15. The process of claim 8 , wherein said process comprises submitting said aqueous composition comprising said lithium compound to said electrodialysis.
16. The process of claim 8 , wherein said process comprises submitting said aqueous composition comprising said lithium compound to said electrolysis.
17. The process of claim 8 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.0 to about 6.2.
18. The process of claim 8 , wherein during said electrodialysis or electrolysis, said pH is at least substantially maintained at a value of about 11 to about 12.
19. The process of claim 8 , wherein said electrodialysis or said electrolysis is carried out in a three-compartment membrane cell.
20. The process of claim 8 , wherein said electrodialysis or said electrolysis is carried out in a two-compartment membrane cell.
21. The process of claim 8 , wherein during said process electrical current is at least substantially maintained at a density of about 300 to about 6000 A/m 2 .
22. The process of claim 8 , wherein during said process electrical current is at least substantially maintained at a density of about 3500 to about 5500 A/m 2 .
23. The process of claim 8 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 9.5 to about 11.5, and with said at least one metal carbonate, thereby at least partially precipitating at least one metal ion under the form of at least one carbonate so as to obtain a precipitate comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate.