Exfoliated graphite materials and composite materials and devices for thermal management

1. A composite material comprising:

a) a flexible graphite material comprising graphite flakes; and

b) a first perforated material comprising:

i. a first major surface;

ii. a second major surface; and

iii. at least one aperture;

said first perforated material embedded in a surface of said flexible graphite material so that said first major surface of said first perforated material is in contact with said surface of said flexible graphite material, and a first portion of said flexible graphite material occupies said at least one aperture in said first perforated material;

wherein a proportion of said graphite flakes in said first portion of said flexible graphite material that are oriented in a through-plane direction is greater than a proportion of said graphite flakes in a remainder of said flexible graphite material that are oriented in a through-plane direction.

2. The composite material of claim 1 wherein said flexible graphite material is a flexible graphite sheet material, said surface of said flexible graphite material is a first major surface of said flexible graphite sheet material, said flexible graphite sheet material having a second major surface opposing said first major surface of said flexible graphite sheet material, and wherein said first perforated material is embedded in said first major surface of said flexible graphite sheet material so that said first major surface of said first perforated material is in contact with said first major surface of said flexible graphite sheet material.

3. The composite material of claim 2 further comprising:

c) a second perforated material comprising:

a. a first major surface;

b. a second major surface; and

c. at least one aperture;

said second perforated material embedded in said second major surface of said flexible graphite sheet material so that said first major surface of said second perforated material is in contact with said second major surface of said flexible graphite sheet material, and a second portion of said flexible graphite sheet material occupies said at least one aperture in said second perforated material;

wherein a proportion of said graphite flakes in said second portion of flexible graphite sheet material that are oriented in a through-plane direction is greater than a proportion of said graphite flakes that are oriented in a through-plane direction in said flexible graphite sheet material that is located between said first major surface of said first perforated material and said first major surface of said second perforated material.

4. The composite material of claim 1 wherein said embedding of said first perforated material in said surface of said flexible graphite material increases the through-plane conductivity of said flexible graphite material.

5. The composite material of claim 1 , wherein said first portion of said flexible graphite material occupies said at least one aperture in said first perforated material so that said flexible graphite material is flush with said second major surface of said first perforated material.

6. The composite material of claim 1 , wherein said first portion of said flexible graphite material occupies said at least one aperture in said first perforated material so that said flexible graphite material protrudes beyond said second major surface of said first perforated material.

7. The composite material of claim 1 wherein said first perforated material is a metal, and said at least one aperture in said first perforated material is a plurality of apertures.

8. The composite material of claim 1 wherein said first perforated material is an adhesive film.

9. A thermal management device comprising a composite material according claim 1 .

10. The thermal management device of claim 9 selected from the group consisting of a thermal pad, a thermal panel, a heat dissipating enclosure for power electronics, a heat sink, and a lid for an electronic device or integrated circuit.

11. The thermal management device of claim 9 in operative contact with a heat source.

12. A method for making a composite material or article, said method comprising:

a) providing a flexible graphite material comprising graphite flakes; and

b) embedding a first perforated material having at least one aperture in a first major surface of said flexible graphite material, so that a first major surface of said first perforated material is in contact with said first major surface of said flexible graphite material and so that a first portion of said flexible graphite material occupies said at least one aperture in said first perforated material;

wherein said flexible graphite material comprises said graphite flakes predominantly oriented in an in-plane direction, and said embedding of said first perforated material in said first major surface of said flexible graphite material re-orients at least a portion of said graphite flakes within said at least one aperture of said first perforated material to be out-of-plane.

13. The method of claim 12 wherein said flexible graphite material is a flexible graphite sheet material, said first major surface of said flexible graphite material is a first major surface of said flexible graphite sheet material, said flexible graphite sheet material having first and a second major surface opposing said first major surface of said flexible graphite sheet material, so that said first major surface of said first perforated material is in contact with said first major surface of said flexible graphite sheet material.

14. The method of claim 13 , wherein said embedding of said first perforated material in said first major surface of said flexible graphite sheet material increases a through-plane thermal conductivity of said flexible graphite sheet material.

15. The method of claim 13 further comprising forming said composite material into a non-planar shape.

16. The method of claim 13 further comprising:

c) embedding a second perforated material having at least one aperture in a second major surface of said flexible graphite sheet material, so that a first major surface of said second perforated material is in contact with said second major surface of said flexible graphite sheet material and so that a second portion of said flexible graphite sheet material occupies said at least one aperture in said second perforated material;

wherein said embedding of said second perforated material in said second major surface of said flexible graphite sheet material re-orients at least a portion of said graphite flakes within said at least one aperture of said second perforated material to be out-of-plane.

17. The method of claim 12 , wherein said first portion of said flexible graphite material occupies said at least one aperture in said first perforated material so that said flexible graphite material is flush with a second major surface of said first perforated material.

18. The method of claim 12 , wherein said first portion of said flexible graphite material occupies said at least one aperture in said first perforated material so that said flexible graphite material protrudes beyond a second major surface of said first perforated material.

19. The method of claim 12 wherein said perforated material is a metal and said at least one aperture is a plurality of apertures.

20. The method of claim 12 wherein said perforated material is an adhesive film.