IP Library Granted Patent US 11,974,445
Granted Patent B2
US 11,974,445 · App. 15/212,842 · Granted Apr 30, 2024

Light-emitting element, display device, electronic device, and lighting device

Inventors: Satoshi Seo (Kanagawa, JP); Tatsuyoshi Takahashi (Kanagawa, JP); Takeyoshi Watabe (Kanagawa, JP); Satomi Mitsumori (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H10K50/121C07F15/0033C09K11/06H10K50/11H10K50/15H10K50/16H10K59/12H10K59/38H10K59/40C09K2211/1007C09K2211/1011C09K2211/1059C09K2211/185H10K85/342H10K85/615H10K85/633H10K85/636H10K85/654H10K85/657H10K85/6572H10K85/6576H10K2101/10H10K2101/30H10K2101/40H10K2101/80H10K2101/90
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Quick Facts
Patent No.
US 11,974,445
App. No.
15/212,842
Granted
Apr 30, 2024
Kind
B2
Abstract

A light-emitting element with high emission efficiency. The light-emitting element includes a first organic compound, a second organic compound, and a guest material. The LUMO level of the first organic compound is lower than the LUMO level of the second organic compound. The HOMO level of the first organic compound is lower than the HOMO level of the second organic compound. The HOMO level of the guest material is higher than the HOMO level of the second organic compound. The energy difference between the LUMO level of the guest material and the HOMO level of the guest material is larger than the energy difference between the LUMO level of the first organic compound and the HOMO level of the second organic compound. The guest material has a function of converting triplet excitation energy into light emission. The first organic compound and the second organic compound form an exciplex.

Claims (72)

1. A light-emitting element comprising:

a first organic compound;

a second organic compound; and

a guest material,

wherein the first organic compound comprises a triazine skeleton,

wherein the guest material has a lower triplet excitation energy level than each of the first organic compound and the second organic compound,

wherein a lowest unoccupied molecular orbital level of the first organic compound is lower than a lowest unoccupied molecular orbital level of the second organic compound,

wherein a highest occupied molecular orbital level of the first organic compound is lower than a highest occupied molecular orbital level of the second organic compound,

wherein a highest occupied molecular orbital level of the guest material is higher than the highest occupied molecular orbital level of the second organic compound,

wherein an energy difference between a lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than an energy difference between the lowest unoccupied molecular orbital level of the first organic compound and the highest occupied molecular orbital level of the second organic compound,

wherein the guest material converts triplet excitation energy into light emission, and

wherein the first organic compound and the second organic compound form an exciplex.

2. The light-emitting element according to claim 1 , wherein an energy difference between the lowest unoccupied molecular orbital level of the first organic compound and the highest occupied molecular orbital level of the guest material is larger than or equal to light emission energy of the guest material.

3. The light-emitting element according to claim 1 , wherein the energy difference between the lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than transition energy calculated from an absorption edge of an absorption spectrum of the guest material by 0.3 eV or more.

4. The light-emitting element according to claim 1 , wherein the energy difference between the lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than light emission energy of the guest material by 0.3 eV or more.

5. The light-emitting element according to claim 1 , wherein excitation energy of the exciplex is transferred to the guest material.

6. The light-emitting element according to claim 1 , wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side of an absorption spectrum of the guest material.

7. The light-emitting element according to claim 1 , wherein the guest material comprises iridium.

8. The light-emitting element according to claim 7 ,

wherein the guest material comprises a ligand coordinated to the iridium, and

wherein the ligand comprises a cyano group and a nitrogen-containing five-membered heterocyclic skeleton.

9. The light-emitting element according to claim 8 , wherein the ligand comprises the cyano group and a triazole skeleton.

10. The light-emitting element according to claim 1 ,

wherein the first organic compound transports an electron, and

wherein the second organic compound transports a hole.

11. The light-emitting element according to claim 1 ,

wherein the second organic compound comprises at least one of a π-electron rich heteroaromatic ring skeleton and an aromatic amine skeleton.

12. A display device comprising:

the light-emitting element according to claim 1 ; and

at least one of a color filter and a transistor.

13. An electronic device comprising:

the display device according to claim 12 ; and

at least one of a housing and a touch sensor.

14. A lighting device comprising:

the light-emitting element according to claim 1 ; and

at least one of a housing and a touch sensor.

15. A light-emitting element comprising:

a first organic compound;

a second organic compound; and

a guest material,

wherein the first organic compound comprises a triazine skeleton,

wherein the guest material has a lower triplet excitation energy level than each of the first organic compound and the second organic compound,

wherein a lowest unoccupied molecular orbital level of the first organic compound is lower than a lowest unoccupied molecular orbital level of the second organic compound,

wherein a highest occupied molecular orbital level of the first organic compound is lower than a highest occupied molecular orbital level of the second organic compound,

wherein a highest occupied molecular orbital level of the guest material is higher than the highest occupied molecular orbital level of the second organic compound,

wherein an energy difference between a lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than an energy difference between the lowest unoccupied molecular orbital level of the first organic compound and the highest occupied molecular orbital level of the second organic compound,

wherein the guest material converts triplet excitation energy into light emission,

wherein the first organic compound and the second organic compound form an exciplex, and

wherein an energy difference between the lowest unoccupied molecular orbital level of the first organic compound and the highest occupied molecular orbital level of the guest material is larger than or equal to transition energy calculated from an absorption edge of an absorption spectrum of the guest material.

16. The light-emitting element according to claim 15 , wherein the energy difference between the lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than the transition energy calculated from the absorption edge of the absorption spectrum of the guest material by 0.3 eV or more.

17. The light-emitting element according to claim 15 , wherein the energy difference between the lowest unoccupied molecular orbital level of the guest material and the highest occupied molecular orbital level of the guest material is larger than light emission energy of the guest material by 0.3 eV or more.

18. The light-emitting element according to claim 15 , wherein excitation energy of the exciplex is transferred to the guest material.

19. The light-emitting element according to claim 15 , wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side of the absorption spectrum of the guest material.

20. The light-emitting element according to claim 15 , wherein the guest material comprises iridium.

21. The light-emitting element according to claim 20 ,

wherein the guest material comprises a ligand coordinated to the iridium, and

wherein the ligand comprises a cyano group and a nitrogen-containing five-membered heterocyclic skeleton.

22. The light-emitting element according to claim 21 , wherein the ligand comprises the cyano group and a triazole skeleton.

23. The light-emitting element according to claim 15 ,

wherein the first organic compound transports an electron, and

wherein the second organic compound transports a hole.

24. The light-emitting element according to claim 15 ,

wherein the second organic compound comprises at least one of a π-electron rich heteroaromatic ring skeleton and an aromatic amine skeleton.

25. A display device comprising:

the light-emitting element according to claim 15 ; and

at least one of a color filter and a transistor.

26. An electronic device comprising:

the display device according to claim 25 ; and

at least one of a housing and a touch sensor.

27. A lighting device comprising:

the light-emitting element according to claim 15 ; and

at least one of a housing and a touch sensor.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2016
From: SEO, SATOSHI; TAKAHASHI, TATSUYOSHI; WATABE, TAKEYOSHI; MITSUMORI, SATOMI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 039180/0145 →
Priority Claims (3)
JP 2015-145443 · Jul 23, 2015 · national
JP 2015-233299 · Nov 30, 2015 · national
JP 2016-051351 · Mar 15, 2016 · national
Continuity (1)
Related Publication 20170025630A1 · Jan 26, 2017